Structural and Dielectric Properties of $(1-x)Pb(Fe_{1/2}Nb_{1/2})O_3-xPbTiO_3$ Prepared by Precalcination Method

전하소법으로 합성한 $(1-x)Pb(Fe_{1/2}Nb_{1/2})O_3-xPbTiO_3$의 구조와 유전성질에 대한 연구

  • 홍영식 (고려대학교 이과대학 화학과) ;
  • 박휴범 (고려대학교 이과대학 화학과) ;
  • 김정 (서남대학교 화학과) ;
  • 김건 (고려대학교 이과대학 화학과) ;
  • 김시중 (고려대학교 이과대학 화학과)
  • Published : 1993.11.01

Abstract

Pb(Fe1/2Nb1/2)O3 and (1-x)Pb(Fe1/2Nb1/2)O3-xPbTiO3 ceramics were prepared by the precalcination method. Their structural and dielectric properties were investigated. The amount of perovsikte phase was increased by the precalcination and the dielectric properties of ceramics were improved. Additions of PbTiO3 were found to increase the tetragonality (c/a) of crystal lattice and Tc. In the middle region of (1-x)Pb(Fe1/2Nb1/2)O3-xPbTiO3, duffuse phase transitions (DPT) were observed.

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References

  1. Am. Ceram. Soc. Bull. v.62 no.1375 Low-Firing Multilayer Capacitor Materials M. Yonezawa
  2. Sov. Phys. Solid State v.1 no.1429 Dielectric Polarization of a Number of Complex Compounds G.A. Smolenskii;A.I. Agranovskaya
  3. Piezoelectric Ceramics B. Jaffe;W.R. Cook;H. Jaffe
  4. J. Am. Ceram. Soc. v.47 no.484 Resistivity Anormaly in Doped Barium Titanate W. Heywang
  5. J. Kor. Ceram. Soc. v.22 no.71 Studies on Fabrication of Translucent Electro-Optic Ceramics J.Y. Kim
  6. J. Phys. Soc. Japan v.27 no.262 Ferroelectric Properties in the System Pb(Zn⅓Nb⅔)O₃-PbTiO₃ S. Nomura;T. Takahashi;Y. Yokomizo
  7. Am. Ceram. Soc. Bull. v.65 no.1601 Preparation of Perovskite PZN-PT Ceramic Powder Near the Morphotropic Phase Boundary T.R. Gururaja;A. Safari;A. Halliyal
  8. Ferroelectrics v.100 no.29 Dielectric and Pyroelectric Properties in the Pb(Mg⅓Nb⅔)O₃-PbTiO₃ System S.W. Choi;T.R. Shrout;S.J. Tang;A.S. Bhalla
  9. Am. Ceram. Soc. Bull. v.63 no.808 Dielectric Properties in the Pb(Fe½Nb½)O₃-Pb(Ni⅓Nb⅔)O₃ Solid Solution System T.R. Shrout;S.L. Swartz;M.J. Haun
  10. J. Mat. Sci. v.23 no.3258 Fabrication of Perovskite Pb(Fe⅔Nb⅓)(Fe½Nb½)[sub 0.9-x]Ti[sub 0.1]O₃by Double Calcmation Process G.F. Chen;S.L. Fu
  11. Jpn. J. Appl. Phys. v.15 no.1059 Ferroelectric and Piezoelectric Properties of xPb[sub 1-y]K[sub y](Zn⅓Nb⅔)O[sub 3-y/2-](1-x)PbTiO₃ Solid Solution L. Hanh;S. Nomura
  12. Mater. Res. Bull. v.17 no.1245 Fabrication of Perovskite PMN S.L. Swartz;T.R. Shrout
  13. Acta. Cryst. v.17 no.1476 On the High Pressure Form of FeVO₄ F. Laves
  14. Am. Ceram. Soc. Bull. v.66 no.671 Stabilization of the Perovskite Phase and Dielecric Properties of Ceramics in the Pb(Zn⅓Nb⅔)O₃-PbTiO₃ System A. Halliyal;U. Kumar;R.E. Newnham;L.E. Cross
  15. J. Solid State Chem. v.6 no.513 Electronic and Vibrational Spectra of Ordered Perovskite G. Blasse;A.F. Corsmit
  16. Acta Cryst. v.9 no.131 X-ray and Neutron Diffraction Study of Ferroelectric PbTiO₃ G. Shirane;R. Pepinsky;B.C. Frazer
  17. J. Mater. Sci. v.23 no.2517 Curie Point of Perovskite-type Oxides Containing Bivalent Ions of the 4th Period in the B-site K. Igrashi;K. Koumato;H. Yanagida;M. Shirasaki