• 제목/요약/키워드: particulate size distribution

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유성볼밀공정으로 제조된 Fe-TiC 복합재료 분말 (Fe-TiC Composite Powders Fabricated by Planetary Ball Mill Processing)

  • 이병훈;안기봉;배상원;배선우;;김병기;김지순
    • 한국분말재료학회지
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    • 제22권3호
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    • pp.208-215
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    • 2015
  • Fe-TiC composite powders were fabricated by planetary ball mill processing. Two kinds of powder mixtures were prepared from the starting materials of (a) (Fe, TiC) powders and (b) (Fe, $TiH_2$, Carbon) powders, respectively. Milling speed (300, 500 and 700 rpm) and time (1, 2, and 3 h) were varied. For (Fe, $TiH_2$, Carbon) powders, an in situ reaction synthesis of TiC after the planetary ball mill processing was added to obtain a homogeneous distribution of ultrafine TiC particulates in Fe matrix. Powder characteristics such as particle size, size distribution, shape, and mixing homogeneity were investigated.

상수도관망에서 입자성 물질의 특성분석 및 영향조사 (Characteristic Analysis and Effect of Particulate Material in Drinking Water Distribution Networks)

  • 김도환;이두진;황진수;최두용
    • 대한환경공학회지
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    • 제35권5호
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    • pp.312-320
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    • 2013
  • 상수도관망에서의 입자성 물질들은 대부분 금속관로의 내부부식 및 퇴적물에 의한 영향으로 이를 해결할 수 있는 방법은 제한적이라 할 수 있다. 수중의 입자성 물질들은 입자크기, 화합물 성분 및 성상들이 다르며, 이들 특성은 시설별 종류, 관 상태, 외부적 요인 및 공급과정 등에 의해서 차이가 발생하게 된다. 본 연구에서는 상수도관망의 수질조사를 수행하면서 수중의 입자성 물질들에 대한 조사를 실시하고자 하였으며, 정수를 공급하는 각 계통들의 배수지 및 관말지역을 대상으로 실시하였다. 각 조사지점에서 입자성 물질을 포집하기 위해 $47{\phi}$ 의 유리섬유여지(GF/C)를 이용하여 여과를 수행하였다. 수중의 탁도에 영향을 미치는 물질들이 입자성 부유물질과 무기물질들에 의한 것으로 관말지역으로 갈수록 입자성 물질이 증가하는 것으로 조사되었다. XRD를 이용한 입자성 물질의 화합물 성분분석결과 상수도관망의 관말지역에서 가장 많은 화합물은 Goethite (${\alpha}$-FeOOH), Magnetite ($Fe_3O_4$) 등이고 정수와 각 배수지 유출수에서는 Quartz ($SiO_2$)와 Yeelimite ($Ca_4Al_6O_{12}SO_4$) 등도 있는 것으로 조사되어 각 상수도 시설별 용출되거나 잔존하고 있는 화합물 성분이 다르며, 침적물들에도 차이가 있었다.

Diurnal Changes in the Distribution of Ruminal Bacteria Attached to Feed Particles in Sheep Fed Hay Once Daily

  • Pan, J.;Suzuki, T.;Ueda, K.;Tanaka, K.;Okubo, M.
    • Asian-Australasian Journal of Animal Sciences
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    • 제13권12호
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    • pp.1708-1716
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    • 2000
  • A study was made of diurnal changes in the ruminal bacteria associated with feed particles, i.e., non-associated (NAB), loosely associated (LAB), and tightly associated with particles (TAB), and the TAB concentration in different particle sizes from sheep fed orchardgrass (OG) or alfalfa (ALF) hay. Diaminopimelic acid (DAPA) was used to determine the TAB mass. Results showed that the bacterial masses in NAB and LAB were small, but comprised over 90% in TAB. The TAB mass in the ALF group sharply increased within 2 h after feeding and decreased afterward. The TAB mass showed the same trend in the OG group, increasing from 0 h to 2 h, but remained at the same level up to 14 h after feeding. The peak bacterial mass was, however, lower in the OG than the ALF group. The TAB concentration reflected the changes in total particulate tightly associated bacterial masses in both groups of hay fed sheep. Number of bacterial colonies per particle increased as the particulate size decreased in both groups. This difference, however, tended to decline as the postprandial period was prolonged. DAPA, however, tended to overestimate the TAB mass in the reticulo-rumen digesta of the hay fed sheep.

산화촉매를 장착한 대형 CNG 엔진의 나노입자 배출특성 (Nanoparticles Emission Characteristics of Heavy-Duty CNG Engine with Oxidation Catalyst)

  • 김태준;김화남;최병철
    • 동력기계공학회지
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    • 제12권5호
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    • pp.27-33
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    • 2008
  • Natural gas has been considered one of the most promising alternative fuels for transportation because of its abundance as well as its ability to reduce regulated pollutants. We measured emission characteristics of nanoparticles from lean burn H/D(Heavy-Duty) CNG (Compressed Natural Gas) engine equipped with oxidation catalysts. The experiments were carried out to measure the emission and engine performance according to the ESC test cycle. The CO and THC conversion efficiencies on the best catalyst in the ESC test cycle achieved about 91 % and 83 %, respectively. From the measurement by the SMPS, the number of nanoparticles emitted from H/D CNG engine is reduced by about 99 % which is more than that of 2.5 L diesel engine. The particle number concentrations of H/D CNG engine were almost nanoparticles. Nanoparticles smaller than 30 nm emitted from the H/D CNG engine and diesel engine equipped with a CDPF(Catalyzed Diesel Particulate Filter) were quite similar. However, the particles bigger than 30nm from the CNG engine were smaller than the particles from diesel engine equipped with a CDPF. The higher the CNG engine load, the lower the particle number from engine-out, but it increased slightly at full load.

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용탕교반법에 의한 SiC 입자강화 Mg기 복합재료의 기계적 특성 (Mechanical Properties of SiC Particulate Reinforced Mg Matrix Composites Fabricated by Melt Stirring Method)

  • 임석원;장융랑;박용진
    • 한국주조공학회지
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    • 제13권5호
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    • pp.441-449
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    • 1993
  • SiC particulate reinforced magnesium matrix composites were fabricated by melt stirring method. The effet of several factors on mechanical properties and the efficiency of melt stirring method from the viewpoint of these properties were investigated. The tensile strength increased and the elongation decreased with decrease of the particle size or the increase of the paticulate volume fraction for pure magnesium matrix and Mg-5%Zn alloy matrix composites. A longer stirring time improved the tensile strength of these composites. The tensile strength of Mg-5%Ca alloy matrix composites which shows no uniform paticulate distribution was a little lower than that of matrix alloy. Rapid solidification rate is preferred for the improved tensile strength of these composites. The pure magnesium matrix and Mg-5%Zn alloy matrix composites have tensile strength of about 400MPa. This value agrees with the tensile strength of some magnesium matrix composites fabricated by liquid infiltration method or powder metallurgy method at the same volume fraction of reinforcements of whisker or particle. Therefore, the melt stirring method which has the advantages of simple process is considered to be efficient in fabricating magnesium matrix composites.

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가솔린 직접 분사식 엔진에서 연료 분사 압력 증가에 따른 연소 및 배기 배출물 특성 (The Combustion and Emission Characteristics with Increased Fuel Injection Pressure in a Gasoline Direct Injection Engine)

  • 이준순;이용규
    • 한국분무공학회지
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    • 제22권1호
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    • pp.1-7
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    • 2017
  • Recently, Performance and fuel efficiency of gasoline engines have been improved by adopting direct injection (DI) system instead of port fuel injection (PFI) system. However, injecting gasoline fuel directly into the cylinder significantly reduces the time available for mixing and evaporation. Consequently, particulate matters(PM) emissions increase. Moreover, as the emission regulations are getting more stringent, not only the mass but also the total number of PM should be reduced to satisfy the Euro VI regulations. Increasing the fuel injection pressure is one of the methods to meet this challenge. In this study, the effects of increased fuel injection pressures on combustion and emission characteristics were experimentally examined at several part load conditions in a 1.6 liter commercial gasoline direct injection engine. The main combustion durations decreased about $2{\sim}3^{\circ}$ in crank angle base by increasing the fuel injection pressure due to enhanced air-fuel mixing characteristics. The exhaust emissions and number concentration distributions of PM with particle sizes were also compared. Due to enhanced combustion characteristics, THC emissions decreased, whereas NOx emissions increased. Also, the number concentrations of PM, larger than 10 nm, also significantly decreased.

배경지역 대기경계층 미세먼지의 화학조성 특성: 2012년 가을 측정 (Chemical Composition Characteristics of Fine Particulate Matter at Atmospheric Boundary Layer of Background Area in Fall, 2012)

  • 고희정;이윤상;김원형;송정민;강창희
    • 대한화학회지
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    • 제58권3호
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    • pp.267-276
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    • 2014
  • 국내 배경지역인 제주도 한라산 1100 고지에서 2012년 가을철에 $PM_{10}$, $PM_{2.5}$ 미세먼지를 채취하여 이온 및 원소 성분을 분석한 결과로부터 대기경계층(ABL) 미세먼지의 화학조성과 입자크기별 분포 특성을 조사하였다. $PM_{2.5}$ 미세입자($d_p$ < $2.5{\mu}m$)에서는 2차 오염물질인 nss-$SO{_4}^{2-}$, $NH_4{^+}$, $NO_3{^-}$ 농도가 각각 4.84, 1.98, $1.27{\mu}g/m^3$로 상대적으로 높고, 전체 질량의 58.2%를 차지하였다. 반면에 $PM_{10-2.5}$ 조대입자($2.5{\mu}m$ < $d_p$ < $10{\mu}m$)에서는 이들 세 성분의 농도가 각각 0.63, 0.21, $1.10{\mu}g/m^3$로 전체 질량의 22.8%를 차지하였다. 또 수용성 이온성분들 중 $NH_4{^+}$, nss-$SO{_4}^{2-}$, $K^+$, $CH_3COO^-$은 주로 미세입자에 분포하고, $NO_3{^-}$은 미세입자와 조대입자에 고르게 분포하나, $Na^+$, $Cl^-$, $Mg^{2+}$, nss-$Ca^{2+}$은 조대입자에 더 많이 분포하는 특징을 나타내었다.

Chemical Characterization of Water-Soluble Organic Acids in Size-Segregated Particles at a Suburban Site in Saitama, Japan

  • Bao, Linfa;Sakamoto, Kazuhiko
    • Asian Journal of Atmospheric Environment
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    • 제3권1호
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    • pp.42-51
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    • 2009
  • Saturated n-dicarboxylic acids ($C_2-C_7$, $C_9$), unsaturated dicarboxylic acids (maleic, fumaric, phthalic acid), ketocarboxylic acids (pyruvic, glyoxylic acid), and dicarbonyls (glyoxal, methylglyoxal) were determined in size-segregated samples with a high-volume Andersen air sampler at a suburban site in Saitama, Japan, May 12-17 and July 24-27, 2007 and January 22-31, 2008. The seasonal average concentrations of these detected organic acids were 670 $ng/m^3$, accounting for about 4.4-5.7% (C/C) of water-soluble organic carbon (WSOC) and 2.3-3.6% (C/C) of organic carbon (OC). The most abundant species of dicarboxylic acids was oxalic acid, followed by malonic, phthalic, or succinic acids. Glyoxylic acid and methyglyoxal were most abundant ketocarboxylic acid and dicarbonyl, respectively. Seasonal differences, size-segregated concentrations, and the correlations of these acids with ambient temperatures, oxidants, elemental carbon (EC), OC, WSOC, and ionic components were also discussed in terms of their corresponding sources and possible secondary formation pathways. The results suggested that photochemical reactions contributed more to the formation of particulate organic acids in Saitama suburban areas than did direct emissions from anthropogenic and natural sources. However, direct emissions of vehicles were also important sources of several organic acids in particles, such as phthalic and adipic acids, especially in winter.

X선 위상차 가시화 기법을 이용한 GDI 인젝터 노즐 근방의 분무 간 상호간섭 해석 (Analyzing the Spray-to-spray Interaction of GDI Injector Nozzle in the Near-field Using X-ray Phase-Contrast Imaging)

  • 배규한;문석수
    • 한국분무공학회지
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    • 제25권2호
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    • pp.60-67
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    • 2020
  • Despite its benefit in engine thermal efficiency, gasoline-direct-injection (GDI) engines generate substantial particulate matter (PM) emissions compared to conventional port-fuel-injection (PFI) engines. One of the reasons for this is that the spray collapse caused by the spray-to-spray interaction forms the locally rich fuel-air mixture and increases the fuel wall film. Previous studies have investigated the spray collapse phenomenon through the macroscopic observation of spray behavior using laser optical techniques, but it is somewhat difficult to understand the interaction between sprays that is initiated in the near-nozzle region within 10 mm from the nozzle exit. In this study, the spray structure, droplet size and velocity data were obtained using an X-ray imaging technique from the near-nozzle to the downstream of the spray to investigate the spray-to-spray interaction and discuss the effects of spray collapse on local droplet size and velocity distribution. It was found that as the ambient density increases, the spray collapse was promoted due to the intensified spray-to-spray interaction, thereby increasing the local droplet size and velocity from the near-nozzle region as a result of droplet collision/coalescence.

High resolution size characterization of particulate contaminants for radioactive metal waste treatment

  • Lee, Min-Ho;Yang, Wonseok;Chae, Nakkyu;Choi, Sungyeol
    • Nuclear Engineering and Technology
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    • 제53권7호
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    • pp.2277-2288
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    • 2021
  • To regulate the safety protocols in nuclear facilities, radioactive aerosols have been extensively researched to understand their health impacts. However, most measured particle-size distributions remain at low resolutions, with the particle sizes ranging from nanometer to micrometer. This study combines the high-resolution detection of 500 size classes, ranging from 6 nm to 10 ㎛, for aerodynamic diameter distributions, with a regional lung deposition calculation. We applied the new approach to characterize particle-size distributions of aerosols generated during the plasma arc cutting of simulated non-radioactive steel alloy wastes. The high-resolution measured data were used to calculate the deposition ratios of the aerosols in different lung regions. The deposition ratios in the alveolar sacs contained the dominant particle sizes ranging from 0.01 to 0.1 ㎛. We determined the distribution of various metals using different vapor pressures of the alloying components and analyzed the uncertainties of lung deposition calculations using the low-resolution aerodynamic diameter data simultaneously. In high-resolution data, the changes in aerosols that can penetrate the blood system were better captured, correcting their potential risks by a maximum of 42%. The combined calculations can aid the enhancement of high-resolution measuring equipment to effectively manage radiation safety in nuclear facilities.