• 제목/요약/키워드: pH paper

검색결과 2,274건 처리시간 0.031초

검정동부 종피에서의 색소 추출과 추출색소의 저장 안정성 연구 (Research on the Colorants Extraction from Black Cowpea Seed Coats and their Storage Stability)

  • 정양숙;최경진;강항원;배도규
    • 한국자원식물학회지
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    • 제24권5호
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    • pp.499-506
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    • 2011
  • 본 연구에서는 검정 동부 종피에 함유된 천연색소에 대한 연구의 일환으로, 추출방법에 따른 색소 추출 효율과 저장안정제 첨가에 따른 저장 안정성과 특성을 검토하여 다음과 같은 결과를 얻었다. 1) 용액 추출 시 온도가 높을수록, 시간이 경과될수록 색소 추출 효율이 높게 나타났으며, pH 조건에서는 pH 4가 가장 효율적이었다. 2) 착액 추출 시, 단시간 전처리에서는 pH 4가 pH 5에서보다 색소 추출량이 많았지만, 15시간 이상의 장시간 전처리에서는 오히려 pH 5에서 많게 나타났다. 3) 검정동부 색소용액의 pH 변화에 따른 색도는, orange-red색(pH 3.0), orange색(pH 4.0~6.0), blue색(pH 7.0) 그리고 greenish-blue색(pH 9.0~11.0)으로 Antocyanin과 유사한 거동을 보였다. 4) 저장 안정제로 Methionine을 첨가한 결과에서는 첨가에 따른 검정 동부 색소의 안정화 효과에서 저장 기간 18일까지는 변색 지연 효과를 보였으며, Methionine 10 mmol 첨가>20 mmol 첨가>무첨가 순으로 안정효과가 크게 나타났다. 5) 검정 동부 종피로부터 착액 추출한 색소 분말을 paper chromatography한 결과, 하나의 긴 띠 모양으로 전개되었으며 Rf 값은 각각 0.68(BAW), 0.53(30% acetic acid)으로 나타났다. 6) Chromatograph paper상에서 전개속도에 따라 3분획으로 구분하여 취한 색소의 spectrum 분석에서는 552 nm의 shoulder의 존재 유무를 근거로 적어도 2가지 이상의 색소 성분이 혼합되어 있는 것을 명확히 알 수 있었다.

pH 적정공정의 모델링 및 자기동조 제어기 설계 (Modelling of a pH titration process and design of a self-tuning pH controller)

  • 김우태;이혁희;최태호;이지태
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1988년도 한국자동제어학술회의논문집(국내학술편); 한국전력공사연수원, 서울; 21-22 Oct. 1988
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    • pp.476-481
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    • 1988
  • In this paper a pH process of a weak acid with a strong base is modeled into a bilinear form, and a self-tuning pH control algorithm which is robust against initial values of solution and disturbances is presented. The control algorithm employs the recursive least square method for the parameter estimation and the generalised minimum variance criterion as the objective function. The computer simulation shows that the tracking of desired pH values is obtained in satisfactory manner regardless of the initial values chosen for the process.

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Benzaldehyde와 Semicarbazide의 결합에 미치는 pH치의 영향 (The Effect of pH on the Condensation Reaction of Benzaldehyde and Semicarbazide)

  • 이길상;김인자
    • 약학회지
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    • 제6권1호
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    • pp.5-7
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    • 1962
  • Like the condensation reaction of general aldehyde, that of benzaldehyde with semicarbazide also depends upon the concentration of carbonium ion that is produced by hydrogen ion. The lower pH value is the facility of the formation of carbonium ion in the condensation reaction, while the reactivity of semicarbazide as a reactant is reduced. In this paper, therefore we want to find out the optimum pH value in the condensation reaction of benzaldehyde with semicarbazide. This optimum pH value was determined by using the simple paper-chromatographic method. According to the result of this experiment, the condensation reaction between benzaldehyde and semicarbazide reacts with its highest point at 3.5pH value. It seems clear that at this point the benzaldehyde acquires the most suitable amount of carbonium ion for the condensation reaction with semicarbazide, and the semicarbazide also has the optimum reactivity.

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종이의 보존을 위한 이산화황 가스(SO2)의 영향 평가 (Evaluation of the Effects of Sulfur Dioxide(SO2) on Conservation of Paper)

  • 임보아;김명남;이선명
    • 펄프종이기술
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    • 제44권6호
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    • pp.15-20
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    • 2012
  • The effects of sulfur dioxide on paper were investigated since these sulfur compounds could cause damages on cellulose and organic materials in papers. For the reason, exposure ageing tests were performed on traditional Korean paper (Hanji) and two different types of modern paper (acid-free and acid paper) to determine the damage with regard to the optical as well as physicochemical properties according to the varying $SO_2$ concentration. As a result, optical properties were not changed while physical and chemical peoperties were remarkably changed with the exposure period. In the case of pH, $SO_2$ had little impact on the pH of the Hanji and acid-free paper while the pH of acid paper was remarkably decreased. The decrease of the folding endurance of the Hanji was relatively smaller than those of the acid-free and acid paper. The results prove Hanji was more resistant to $SO_2$ than the modern paper in terms of optical, physical and chemical properties. In addition, it was also suggested that $SO_2$ concentration should be kept below 0.01 ppm for the preservation of paper objects.

글루코스-글리신 혼합용액의 갈색화 패턴 및 색소 (Browning Pattern and Pigment of Glucose/Glycine Model Systems)

  • 남상숙;이미순
    • 한국식품과학회지
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    • 제16권2호
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    • pp.218-222
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    • 1984
  • 조정된 조건하에서 glucose-glycine 혼합수용액을 사용하여 browning을 발달시켰다. Browning pattern은 medium의 pH및 반응물질의 농도에 특히 영향을 받았다. Glucose- glycine수용액을 희석시켜 filter paper disks를 담갔다가 기름으로 튀겼다. 반응물질의 농도는 튀긴 filter Paper dists의 browning pattern에만 영향하고 pH영향은 고온에서 불명확하게 되였다. Glucose-glycine system의 pH 2에서는 무결정형의 갈색 침전물이 생성되었다. 본 model system에서 생성된 갈색 색소를 규명하기 위하여 기기분석을 시도하였다.

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Micro pH Sensor Using Patterned Hydrogel with pH Indicators

  • Jang, Ji-Sung;Kwon, Sung-Hoon
    • 센서학회지
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    • 제20권4호
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    • pp.234-237
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    • 2011
  • This paper presents a study into pH Indicator-Embedded hydrogel micro-particles which are encoded various shapes according to the captured indicator. We incorporate various pH indicators into a photo-curable hydrogel, PEG-DA(Poly(ethylene glycol) diacrylate). Using the latest fluidic lithography techniques, we can easily fabricate variously patterned hydrogel particles based on in-situ photopolymerization of the PEG-DA in a micro-fluidic channel. The shape of the particle is related to the pH indicator inside the particle. We demonstrate that the micro pH sensors change their colors according to the pH levels. The micro pH sensors have various characteristics that are related to the curing time, particle size, etc. By changing these conditions, we can adjust the long term stability and reaction time of the hybrid micro pH sensors.

정수처리에서 pH 저감에 의한 응집효율향상에 관한 연구 (Improving Coagulation Performance with pH Preadjustment in Drinking Water Treatment)

  • 이환;이철효;정창규;이윤진
    • 한국환경보건학회지
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    • 제29권2호
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    • pp.1-6
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    • 2003
  • This paper reports on a pilot scale comparison of PACS coagulation with and without pH preadjustment. The pH of the water was adjusted with carbon dioxide and sulfuric acid. Process performance was assessed on the basis of total organic carbon(TOC), UV absorbance, turbidity and disinfection by-product(DBP) precursors. Coagulation pH appeared to be a determining factor for maximum NOM removal. The optimum coagulation pH in order to decrease TOC and turbidity were pH 7. Preadjustment of pH 7 increased TOC removal to as much as 43, 47 percent with sulfuric acid and carbon dioxide. Moreover, coagulation at pH 7 caused a reduction in UV$_{254}$, THMFP and HAAFP compared to the baseline coagulation. For preadjustment of pH 7 with carbon dioxide, the percentage of TOC, UV$_{254}$, THMFP and HAAFP shows the reduction rate of 3.8, 0.5, 4.8, 9.4% comparing to the coagulation rendition using sulfuric acid. Acid addition to depress pH during coagulation decrease Langelier Saturation Index(LSI), potentially causing increase corrosion in water distribution systems. LSI for carbon dioxide and sulfuric acid at pH 6 was -2.3, -3.3. Therefore, carbon dioxide was more effective at controlling corrosion than sulfuric acid.

백색 점착성 이물질을 측정하기 위한 새로운 시험법 - pH와 칼슘경도의 영향 - (A New Test Method to Evaluate Potential White Pitch Deposit - Influence of pH and calcium hardness -)

  • 신은주;최태호;송봉근;조병욱;류정용
    • 펄프종이기술
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    • 제41권2호
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    • pp.26-33
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    • 2009
  • A new testing method to evaluate the deposition potential of white pitch was developed. The new method involves depositing the potential white pitch particles on the air bubble covered plastic film in the pitch deposit tester (PDT) developed by KRICT and analysing the deposited area of white pitch using an image analyzer. In addition, the effect of two important factors (pH and calcium hardness) on white pitch deposition potential was elucidated. When pH of the coated broke stock was increased from neutral to alkali or the calcium hardness of the stock was decreased, the pitch deposit area was decreased, implying that these two factors have to be controlled during the evaluation of pitch deposition potential. It was found that hydrophobicity of the surface of latex binding films repulped is a key factor influencing white pitch deposition.

고분자전해질의 LbL multilayering 시 pH와 염 농도 조건에 따른 섬유의 전기화학적 특성 (Electrochemical Properties of Pulp Fiber with LbL Multilayering by Polyelectrolyte at the Different pH and Salt Concentration)

  • 류재호;이성린;진성민;윤혜정
    • 펄프종이기술
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    • 제40권4호
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    • pp.59-65
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    • 2008
  • Electrochemical properties of pulp fiber could be modified by LbL(Layer-by-Layer) multilayering. Salt concentration and pH affect the conformation and ionization degree of polyelectrolyte. In this study, therefore, we intended to evaluate the effect of pH and salt concentration in polyelectrolyte multilayering on the electrochemical properties of pulp fiber. The pH of the stock was varied to 4, 7, and 10. Salt concentration was controlled at 0.001, 0.003, and 0.005 M of NaCl. Higher zeta potential was obtained when pulp fibers were multilayered at the condition of higher pH and higher salt concentration. The final zeta potential of pulp fiber after multilayering was dependent on the adsorption ratio of polyelectrolyte and the initial zeta potential of fibers.