• Title/Summary/Keyword: pH effects

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Numerical Simulation on Buffering Effects of Ultrathin p-${\mu}c$-Si:H Inserted at the p-a-SiC:H/i-a-Si:H Interface of Amorphous Silicon Solar Cells (비정질 실리콘 태양전지의 p-a-SiC:H/i-a-Si:H 계면에 삽입된 P형 미세 결정 실리콘의 완충층 효과에 대한 수치 해석)

  • Lee, Chang-Hyun;Lim, Koeng-Su
    • Solar Energy
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    • v.20 no.1
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    • pp.11-20
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    • 2000
  • To get more insight into the buffering effects of the p-${\mu}c$-Si:H Inserted at the p-a-SiC:H/i-a-Si:H interface, we present a systematic numerical simulation using Gummel-Schafetter method. The reduced recombination loss at the p/i interface due to a constant bandgap buffer is analysed in terms of the variation of the p/i Interface region with a short lifetime and the characterisitics of the buffer such as mobility bandgap, acceptor concentration, and D-state density. The numerical modeling on the constant bandgap buffer demonstrates clearly that the buffering effects of the thin p-${\mu}c$-Si:H originate from the shrinkage of highly defective region with a short lifetime in the vicinity of the p/i interface.

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Kinetic Study of pH Effects on Biological Hydrogen Production by a Mixed Culture

  • Jun, Yoon-Sun;Yu, Seung-Ho;Ryu, Keun-Garp;Lee, Tae-Jin
    • Journal of Microbiology and Biotechnology
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    • v.18 no.6
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    • pp.1130-1135
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    • 2008
  • The effect of pH on anaerobic hydrogen production was investigated under various pH conditions ranging from pH 3 to 10. When the modified Gompertz equation was applied to the statistical analysis of the experimental data, the hydrogen production potential and specific hydrogen production rate at pH 5 were 1,182 ml and 112.5 ml/g biomass-h, respectively. In this experiment, the maximum theoretical hydrogen conversion ratio was 22.56%. The Haldane equation model was used to find the optimum pH for hydrogen production and the maximum specific hydrogen production rate. The optimum pH predicted by this model is 5.5 and the maximum specific hydrogen production rate is 119.6 ml/g VSS-h. These data fit well with the experimented data($r^2=0.98$).

The Effects of Initial pH on the Crystallization of Zeolitic ETS-Series (초기 pH가 제올라이트성 ETS-계열의 결정화반응에 미치는 영향)

  • Kim, Wha Jung;Kim, Youn Sang
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.33-37
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    • 1998
  • The effects of initial pH on the synthesis of new microporus zeolitic materials, ETS-4 and ETS-10 were investigated with the initial pH from 10.4 to 11.5. The results showed that initial pH significantly affect the type of ETS-series materials to be crystallized ; that is, pure ETS-10 at 10.4 of pH, mixture of ETS-10 and ETS-4 at intermediate pH, and pure ETS-4 at pH. Micrographs show that the morphology of final solid product changes from the shape contacting the bottom sides of two truncated pyramids to the plane-like shape as initial pH increases.

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Effects of pH Early Postmortem on Meat Quality in Beef Longissimus

  • Hwang, I.H.;Tompson, J.M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.8
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    • pp.1218-1223
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    • 2003
  • The effects of type (high and low voltages) and time (3, 40 and 60 min postmortem) of stimulation on drip loss and meat color at 24 h post-mortem were determined on M. longissimus dorsi of 38 crossbred steers and heifers. In addition, the effect of pH early postmortem (70 min postmortem) on the rate and extend of meat tenderization was examined. Either high or low voltage stimulation at 3 min showed a tendency for faster pH decline (p=0.052) and higher drip loss (p=0.08), and improved the color dimensions of L*, a* and b* (p<0.01), compared to stimulation at 40 min. This was equivalent to approximately one unit of an AUSMEAT color chip. On the other hand, although there were significant differences in pH decline between high voltage stimulation at 40 and 60 min, and between low voltage stimulation at 40 min and control sides, drip loss and meat color did not differ significantly (p>0.05). The results suggested that early application of stimulation, regardless of type of stimulation, improved overall meat color at 24 h postmortem through its effect on faster glycolysing rate. However, if the pH decline was moderate, the benefit of electrical stimulation on meat color was not apparent. An intermediate pH decline resulted in the lowest shear force. Due to differential ageing rates the optimum pH at 70 min postmortem increased with ageing time from 5.96, 6.07, 6.12 and 6.14 for 1, 3, 7 and 14 days postmortem, respectively. This implied that a small difference in the rate of pH decline was important, especially carcasses stimulated for very early postmortem, and the optimum rate of pH decline varied with intended ageing period. The study suggests that the beneficial or adverse effects of electrical stimulation on drip loss, meat color and tenderness is determined by the rate of pH decline, rather than by stimulation treatment and time of application per se.

Nitrite Scavenging Effect of Maillard Reaction Products Derived from Glucose-Amino Acids (Glucose-아미노산계 Maillard 반응생성물의 아질산염 소거작용)

  • Kim, Seon-Bong;Lee, Dong-Ho;Yeum, Dong-Min;Park, Jin-Woo;Do, Jung-Roung;Park, Yeung-Ho
    • Korean Journal of Food Science and Technology
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    • v.20 no.3
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    • pp.453-458
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    • 1988
  • This research was carried out to investigate the effects of Maillard reaction products and nondialyzable melanoidins on the nitrite-scavenging. Nitrite-scavenging reactions were done at the different pH conditions(pH 1.2, 4.2 and 6.0). Maillard reaction products and nondialyzable melanoidins, produced from the glucose-amino acids(lys., gly., arg., his.)model systems, had a great of nitrite-scavenging effects. Nitrite-scavenging effects of Maillard reaction products and nondialyzable melanoidins were also pH dependent, being higher at pH 1.2 and lower at pH 6.0. By the treatment of Maillard reaction products and nondialyzable melanoidins with sodium borohydride, nitrite-scavenging effects were remarkably decreased at pH 1.2.

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Effects of Heating, pH, Salts and Organic Acids on Color Changes of Ground Garlic (가열 및 pH, 유기산, 염류가 마쇄마늘 변색에 미치는 영향)

  • Cho, Jin-Sook;Ku, Kyung-Hyung;Kim, Woo-Jung
    • Korean Journal of Food Science and Technology
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    • v.31 no.2
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    • pp.399-403
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    • 1999
  • Effects of heating, pH, organic acids and some salts on color changes of ground garlic, expressed by Hunter color values, were investigated during storage. The organic acids, such as acetic, citric and lactic acids rather enhanced greening, while NaCl affected little. As the pH decreased to 4.0, greening was significantly reduced. Among the several phosphates tested, $Na_{2}HPO_{4}\;and\;Na_{3}PO_{4}$ showed some positive effects and other chemicals, such as BHA, BHT, propyl gallate and glutathione showed little or negative effects on both greening and browning of ground garlic. Heating at $80^{\circ}C$ for up to 10 mins at pH range of $3.0{\sim}5.0$ caused a severe greening mostly, while heating at $90\;and\;100^{\circ}C$ for 30 mins or longer resulted in a decrease in greening and an increase in yellow color of ground garlic.

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Effects of Different Potassium Sources on the Ammonia Volatilization from Soils under Flooded Condition (가리(加里)의 시용(施用)이 담수토양(湛水土壤)에서 암모니아의 휘산(揮散)에 미치는 영향(影響))

  • Oh, Wang-Keun;Kim, Seong-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.14 no.1
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    • pp.17-23
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    • 1981
  • The effects of potassium chloride and potassium sulphate on the volatilization of ammonia from acidic clayloam and tidal sandy clay loam soils applied with urea under flooded conditions were studied in a laboratory experiment. Results obtained were as follows; 1. The application of potassium to the acidic soil promoted the volatilization of ammonia through increasing soil pH. 2. The application of potassium to urea treated on the tidal soil which lead pH over 8.0 under flooded reduced conditions decreased the wet soil pH and reduced the volatilization of ammonia from the soil. These effects of potassium were more pronounced in the potassium sulphate treatment than in the potassium chloride. 3. More ammonia was volatilized from the acidic soil applied with potassium sulphate, however, the effects of potassium fertilizers applied to the high pH tidal soil seemed to be masked by high salt content of the soil. 4. Urea brought up soil pH significantly. Potassium sulphate was more effective than potassium chloride in raising pH of the acidic soil, though the reverse could be true in the tidal soil with high pH. The reduction of sulphate might be a major cause for the pH change.

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The Effects of pH and Dosages According to Qualities of Raw Waters and Basicity of Coagulants (원수 수질특성과 응집제 염기도에 따른 응집 pH 및 주입량의 영향)

  • Park, Noh-Back;Lee, Bum;Tian, Dong-Jie;Lee, Young-Ju;Jun, Hang-Bae
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.5
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    • pp.581-593
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    • 2010
  • The objectives of this study were to investigate the effects of raw water pH and basicity of coagulants on turbidity removal with several raw waters having different level of turbidity, alkalinity and pH. Raw waters were sampled from M, S and B water treatment plants(WTP) located at Miryang, Nakdong, Han river, respectively. Six coagulants which have different levels of basicity and aluminum contents were used for this evaluation. High basicity of the coagulant helped to properly control coagulation processes for treating turbid and low alkali raw water. It was difficult for operators to determine optimum coagulant dose for high basicity coagulants, since residual turbidity tended to decrease continuously as coagulant dose increased. Turbidity removal efficiencies with high basicity coagulants(E and F) were higher than the other coagulants at ambient pH for the M WTP. Turbidity removal efficiencies, however, at adjusted pH 7.0 showed similar among six coagulants. Residual turbidity kept low at excess dosages with high basicity coagulants. Optimum coagulant dosages at adjusted pH 7.0 showed higher than those at ambient pH in M WTP. On the contrary in B WTP, optimum coagulant dosage at ambient pH were higher than that at adjusted pH 7.0.

Effects of Acute Acid Stress on Hatching and Mortality of Hermaphroditic Teleost, Rivulus marmoratus(Cyprinodontiformes; Rivulidae)

  • Kim, Ae-Ri;Lee, Meoung-Sook;Park, Eun-Ho
    • Animal cells and systems
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    • v.7 no.4
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    • pp.345-348
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    • 2003
  • The effects of acute acid stress on hatching success and hatching period of laboratory-reared hermaphroditic fish Rivulus marmoratus were examined. The effects of acute acid toxicity on mortality was also determined in three life stages of this fish. There was a significant negative effect of acid stress on hatching performance in the R. marmoratus embryos. The hatching success was only 5% at pH 3.5 compared to over 78% at pH higher than 4.0. The hatching period was also delayed by low pH treatments. The larval and juvenile stages were more sensitive to acid toxicity on mortality than the adult stage, but larvae and juveniles showed similar sensitivity. The 96-h LC50 value was pH 3.8 in larval and juvenile stages and pH 3.3 in adult stage.

Effects of Precipitation pH of Black Liquor on Characteristics of Precipitated and Acetone-Fractionated Kraft Lignin

  • Ega Cyntia WATUMLAWAR;Byung-Dae PARK
    • Journal of the Korean Wood Science and Technology
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    • v.51 no.1
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    • pp.38-48
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    • 2023
  • Two important steps in utilizing technical kraft lignin (KL) from black liquor to synthesize lignin-phenol-formaldehyde (LPF) resin are its extraction via precipitation and fractionation. However, the effects of precipitation pH and acetone fractionation on the characteristics of hardwood KL have not been studied for LPF resins. Therefore, this paper reports the effects of the precipitation pH of black liquor and acetone fractionation on the characteristics of KL from mixed hardwood species for LPF resins. The precipitation was conducted at various pH levels from 3 to 9 of black liquor to obtain crude KL (C-KL), which was used in acetone fractionation to produce acetone-soluble KL (AS-KL) and acetone-insoluble KL (AI-KL). Precipitation at pH 3 and 9 produced the highest and lowest yields of C-KL, respectively. As expected, the C-KL infrared spectra were similar regardless of the precipitation pH levels. As the pH increased, the molecular weight of C-KL increased. However, the molecular weight of AS-KL and AI-KL after acetone fractionation increased to a maximum of 4,170 and 47,190 g/mol at pH 7, then decreased to 3,210 and 19,970 g/mol at pH 9, respectively. The smallest molecular weights of AS-KL and AI-KL were 3,210 and 15,480 g/mol and were found at pH 9 and 3, respectively. These results suggest that both AS-KL at pH 9 and AI-KL at pH 3 have good potential as starting lignins for synthesizing LPF resins that require cross-linking for polymerization.