• Title/Summary/Keyword: p-1-r coordinate

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Synthesis and Structural Characterization of Five- and Six-Coordinate Cobalt(Ⅱ) Complexes of Tripodal Liand. Tris-(2-benzimidazolylmethyl)amine

  • 라명수;문무신
    • Bulletin of the Korean Chemical Society
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    • v.18 no.4
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    • pp.406-409
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    • 1997
  • The various cobalt(Ⅱ) complexes were synthesized and characterized using tris-(2-benzimidazolylmethyl)amine (ntb) as a ligand where the ntb plays as a tripodal tetradentate ligand to form complexes with a trigonal pyramidal geometry. The complexes have 5 and 6 coordinate cobalt(Ⅱ) ions depending on the additional ligand used. In each complex the additional ligand, chloride anion, or acetate anion occupies the "open" site trans to the apical tertiary nitrogen atom of ntb ligand. Complex 1, [Co(Ⅱ)(ntb)Cl]Cl has a trigonal bipyramidal geometry. This geometry was easily constructed using ntb as a tetradentate ligand and chloride as a monodentate ligand. The complex is isostructural to the corresponding manganese(Ⅱ) complex. Crystal data are as follows: [Co(Ⅱ)(ntb)Cl]Cl·MeOH, 1. triclinic space group P1; a=13.524(2) Å, b=14.037(2) Å, c=17.275(1) Å; α=78.798(9), β=84.159(8)°, γ=65.504(9)°; V=2929.6(6) Å3; Z=4; R1=0.0715, wR2=0.1461 for reflections of I > 2σ(I). Six coordinate complex 2 [Co(ntb)(OAc)](OAc) was synthesized using ntb as a tetradentate ligand and acetate as a bidentate chelating ligand.

A GORENSTEIN IDEAL OF CODIMENSION 4

  • Shin, Yong-Su
    • Journal of the Korean Mathematical Society
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    • v.34 no.1
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    • pp.135-147
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    • 1997
  • Let k be an infinite field and let $X = {P_1, \cdots, P_s}$ be a set of s-distinct points in $P^n$. We denote by $I(X)$ the defining ideal of $X$ in the polynomial ring $R = k[x_0, \cdots, x_n]$ and by A the homogeneous coordinate ring of $X, A = \sum_{t = 0}^{\infty} A_t$.

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Eliminating the Neutral Current by the Power Compensator without using Energy Storage Elements (에너지저장요소를 사용하지 않는 전력보상기에 의한 중성선 전류의 제거)

  • Kim, Hyo-Seong
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.48 no.6
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    • pp.330-335
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    • 1999
  • This paper proposed the p-q-r coordinate system where the instantaneous active power p, and the two instantaneous reactive powers qq, qr were defined. The three power components are linearly independent, so the compensation for the two instantaneous reactive powers leads to control the two components of the current space vector. With the theory, the neutral current of a three-phase four-wire system can be eliminated by only compensating the instantaneous reactive power using no energy storge element.

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Calculation of NMR Chemical Shift for 5d$^n$ Systems (Ⅰ). Application of the Expansion Method for Spherical Harmonics for Computation of Overlap and Dipole Moment Matrix Elements

  • Ahn, Sang-Woon;Oh, Se-Woung;Park, Eui-Suh
    • Bulletin of the Korean Chemical Society
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    • v.6 no.1
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    • pp.3-7
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    • 1985
  • The general formulas for SCF atomic orbitals |5s > and |6p > have been derived separately by expressing the spherical harmonics part in terms of the coordinate($r_1,\;$r_2$) of the reference point, and by translating the exponential part, $r^4\;exp\;(-{\beta}r)$), in terms of $r_1,\;and\;r_2$ and the modified Bessel functions. Master formulas for overlap and dipole moment matrix elements are derived. The computed values of overlap and dipole moment matrix elements for hypothetical NO molecule are exactly in agreement with those for the previous methods.

Electrophilic Attack of the Phenyl Isocyanate Carbon at the Bridging Imido Nitogen: Preparation and Structure of$ Mo_2({\mu-N(CONPh)Ph})({\mu-NPh)(NPh)_2(S_2CNEt_2)_2$

  • 김경;Lee, Soon W.
    • Bulletin of the Korean Chemical Society
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    • v.19 no.11
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    • pp.1211-1216
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    • 1998
  • Bis(diethyldithiocarbamato)ioxomolybdenum(VI), cis-MoO2(S2CNEt2)2, 1, reacted with chlorotrimethylsilane (Me33SiCl) to give a seven-coordinate, pentagonal bipyramidal complex MoOC12(S2CN]Et2)2, 3, in which the oxo ligand is trans to the chloride ligand and the two chloride ligands are mutually cis. The monooxo molybdenum complex bis(diethyidithiocarbamato)oxomolybdenum(IV), MoO(S2CNEt2)2, 2, reacted with phenyl isocyanate (PhNCO) to give an Mo dimer MO2{μ-N(CONPh)Ph}(μ-NPh)(NPh)2(S2CNEt2)2, 4, which contains an Mo-Mo bond, two diethyldithiocarbamato ligands, two terminal imido (NPh) ligands, and two bridging hnido (NPh) ligands. One of the two bridging NPh ligands seemed to have been attacked by the electrophilic phenyl isocyanate carbon, which suggests that the bridging imido NPh ligand is more nucleophilic than the terminal one. Crystallographic data for 3: monoclinic space group P21/c, a=8.908(l) Å, b=17.509(3) Å, c=12.683(2) Å, β=110.15(1)°, Z=4, R(wR2)=0.0611(0.1385). Crystallographic data for 4-THF: orthorhombic space group P212121, a=17.932(4) Å, b=22.715(5) Å, c=11.802(3) Å, Z=4, R(wR2)=0.0585(0.1286).

ON THE MINIMAL FREE RESOLUTION OF CURVES OF MAXIMAL REGULARITY

  • Lee, Wanseok;Park, Euisung
    • Bulletin of the Korean Mathematical Society
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    • v.53 no.6
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    • pp.1707-1714
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    • 2016
  • Let $C{\subset}{\mathbb{P}}^r$ be a nondegenerate projective curve of degree d > r + 1 and of maximal regularity. Such curves are always contained in the threefold scroll S(0, 0, r - 2). Also some of such curves are even contained in a rational normal surface scroll. In this paper we study the minimal free resolution of the homogeneous coordinate ring of C in the case where $d{\leq}2r-2$ and C is contained in a rational normal surface scroll. Our main result provides all the graded Betti numbers of C explicitly.

Development of Plantar Pressure Measurement System and Personal Classification Study based on Plantar Pressure Image

  • Ho, Jong Gab;Kim, Dae Gyeom;Kim, Young;Jang, Seung-wan;Min, Se Dong
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.15 no.11
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    • pp.3875-3891
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    • 2021
  • In this study, a Velostat pressure sensor was manufactured to develop a plantar pressure measurement system and a C#-based application was developed to monitor and collect plantar pressure data in real time. In order to evaluate the characteristics of the proposed plantar pressure measurement system, the accuracy of plantar pressure index and personal classification was verified by comparing with MatScan, a commercial plantar pressure measurement system. As a result, the output characteristics according to the weight of the Velostat pressure sensor were evaluated and a trend line with the reliability of r2 = 0.98 was detected. The Root Mean Square Error(RMSE) of the weighted area was 11.315 cm2, the RMSE of the x coordinate of Center of Pressure(CoPx) was 1.036 cm and the RMSE of the y coordinate of Center of Pressure(CoPy) was 0.936 cm. Finally, inaccuracy of personal classification, the proposed system was 99.47% and MatScan was 96.86%. Based on the advantage of being simple to implement and capable of manufacturing at low cost, it is considered that it can be applied to various fields of measuring vital signs such as sitting posture and breathing in addition to the plantar pressure measurement system.

THE ARTINIAN POINT STAR CONFIGURATION QUOTIENT AND THE STRONG LEFSCHETZ PROPERTY

  • Kim, Young-Rock;Shin, Yong-Su
    • Journal of the Korean Mathematical Society
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    • v.56 no.3
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    • pp.645-667
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    • 2019
  • It has been little known when an Artinian point quotient has the strong Lefschetz property. In this paper, we find the Artinian point star configuration quotient having the strong Lefschetz property. We prove that if ${\mathbb{X}}$ is a star configuration in ${\mathbb{P}}^2$ of type s defined by forms (a-quadratic forms and (s - a)-linear forms) and ${\mathbb{Y}}$ is a star configuration in ${\mathbb{P}}^2$ of type t defined by forms (b-quadratic forms and (t - b)-linear forms) for $b=deg({\mathbb{X}})$ or $deg({\mathbb{X}})-1$, then the Artinian ring $R/(I{\mathbb_{X}}+I{\mathbb_{Y}})$ has the strong Lefschetz property. We also show that if ${\mathbb{X}}$ is a set of (n+ 1)-general points in ${\mathbb{P}}^n$, then the Artinian quotient A of a coordinate ring of ${\mathbb{X}}$ has the strong Lefschetz property.

A Study on the Correlation between Visual Perception Ability and Balance Ability in the Health Elderly (노인의 시지각 능력과 균형능력과의 상관관계에 관한 연구)

  • Jang, Yong-Su;Park, Chang-Sik;Lee, Hyoung-Soo
    • Journal of Korean Physical Therapy Science
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    • v.18 no.2
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    • pp.73-80
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    • 2011
  • Purpose: The purpose of this study was to investigate the correlation between the visual perception ability and the static dynamic balance ability in health elderly. Method: The Motor Free Visual Perception Test-Row Score(MVPT-RS) and MVPT-Process Time(MVPT-PT) were used for evaluating the visual perception abilities. Assessment of the balance ability was taken by using Good Balance System. In the assessment using Good Balance System, X, Y coordinate speed, anterior-posterior direction, medial-lateral direction and Velocity Movement(VM) in standing posture when eye open were measured as static balance abilities. Thirty-seven healthy elderly who live in Gwangyang participated in the experiment for 2 months, from October to November 2010. Results: 1. There were statistically significant differences of MVPT-RS, MVPT-PT, NSB-X, NSB-Y, NSB-VM, OLB-X, and OLB-VM based on the gender(p<0.05). 2. The negative correlations of MVPT-RS:NSB-Y(r=-0.354), MVPT-RS:OLB-X(r=-0.4), MVPT-RS: OLB-Y(r=-0.371), but positive correlations of MVPT-PT:DTB-T showed a statistical significance(r=0.45, p<0.05). 3. The positive correlations of NSB-X:NSB-Y(r=0.54), NSB-X: NSB-VM(r=0.848), NSB-Y:NSB-VM(r=0.531), OLB-X:OLB-Y(r=0.876), OLB-X:OLB-VM(r=0.872), and OLB-Y:OLB-VM(r=0.787) showed statistical significances(p<0.05). Conclusion: These results showed that the visual perception ability was correlated with some balance ability in health elderly. Especially the perception test process time(MVPT-PT) has closely related with the DTB-T. The visual perception ability is considered as a factor on the balance ability in health elderly. Further study will focus on the development of improving program of visual perception ability as an improving method of balancing ability in health elderly.

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Preparation and Structure of Re$({\equiv}NC_6H_5)(PPh_3)(PR_3)Cl_3,\;PR_3=PMe_3,\;P(OMe)_3$

  • Kim, Young-woong;Jung, June-ho;Park, Hee-sook;Lee, Soon W.
    • Bulletin of the Korean Chemical Society
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    • v.15 no.10
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    • pp.891-896
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    • 1994
  • Reactions of mer, trans-$Re({\equiv}NC_6H_5)(PPh_3)_2Cl_3$, I, with $PMe_3$ and $P(OMe)_34 at room temperature, led to mer, trans-$Re({\equiv}NC_6H_5)(PPh_3)(PMe_3)Cl_3$, II, and fac-$Re({\equiv}NC_6H_5)(PPh_3)(P(OMe)_3)Cl_34, III, respectively. The crystal structures of II and III were determined through X-ray diffraction. Ⅱ crystallizes in the orthorhombic system, space group $Pna2_1$ with cell parameters a=19.379(4) ${\AA}$, b=11.867(2) ${\AA}$, c = 12.676(3) ${\AA}$, and Z = 4. Least-squares refinement of the structure led to a $R(wR_2)$ factor of 0.0251 (0.0621) for 2203 unique reflections of $I>2{\sigma}(I)$ and for 306 variables. III crystallizes in the monoclinic system, space group $P2_1/n$ with cell parameters a=11.399(3) ${\AA}$, b=14.718(4) ${\AA}$, c=17.558(5) ${\AA}$, ${\beta}=97.79(2){\circ}$, and Z=4. Least-squares refinement of the structure led to a $R(wR_2)$ factor of 0.0571 (0.1384) for 3739 unique reflections of $I>2{\sigma}(I)$ and for 344 variables. Structural studies showed that the relative orientations of the two phosphines in both complexes are different, probably due to the differences in the coordinating abilities between $PMe_3$ and $P(OMe)_3$ to the 5-coordinate fluxional intermediate.