• 한국물환경학회지
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• 제35권6호
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• pp.459-469
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• 2019

The ozonation of sulfamethoxazole (SMX) was performed at 20℃ using a pilot scale countercurrent bubble column reactor. Ozonation systems were combined with UV irradiation and TiO₂ addition. As the oxidation reaction proceeded in each treatment system, the pH of the sample decreased and in the O₃/UV/TiO₂ system, the pH change was the largest from 4.54 to 2.02. Under these experimental conditions, the scavenger impact of carbonate is negligible. The highest COD and TOC removal rate was observed in the O₃/UV/TiO₂ system due to the UV irradiation and the photocatalytic effect of TiO₂. Also, the highest mineralization ratio(ε) value is 0.2 in the O₃/UV/TiO₂ system, which means theoxidation capacity of the systems. The highest SMX degradation rate constants calculated by COD and TOC values (COD and TOC) were 2.15 × 10^-4 sec^-1 and 1.00 × 10^-4 sec^-1 in the O₃/UV/TiO₂ system, respectively. The activation energy (E_a) of ozone treatment follows the Arrhenius law. It was calculated based on _COD and _TOC. Each activation energy decreased in order of single O₃> O₃/TiO₂> O₃/UV > O₃/UV/TiO₂ system. The result showed that ΔH^≠ is more effective than ΔS^≠ in each SMX ozontaionsystem, that is characteristic of the common oxidation reaction.

• 한국농림기상학회지
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• 제7권3호
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• pp.220-226
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• 2005

오존 노출이 버즘나무의 광합성 특성에 미치는 영향을 조사하기 위하여, 2년생 버즘나무 유묘에 하루에 8시간씩 100 ppb의 오존을 처리하였다. 오존 처리를 진행하는 동안, 3주마다 버즘나무의 엽내 엽록소 함량과 광합성 특성을 측정하였다. 오존에 의한 잎의 가시적 피해는 나타나지 않았으며, 또한 엽내 엽록소 함량은 대조구와 뚜렷한 차이를 보이지 않았다. 그러나 광합성량, 기공전도도, 수분이용효율은 오존 처리 6주 후에 대조구보다 감소하였다. 한편 탄소고정효율과 광화학 효율은 오존 처리 3주와 6주 후에서 감소한 것으로 나타났다. 위의 결과를 토대로 볼 때, 탄소고정효율은 오존 스트레스에 가장 민감한 파라미터로 나타났으며, 이것은 오존 민감성을 평가하기 위한 매우 적당한 지표로 생각되었다.

• 농촌계획
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• 제12권2호
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• pp.49-56
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• 2006

The application of domestic wastewater on rice paddies results in the accumulation of sodium(Na$^+$) to the soil. Excessive concentration of sodium may cause the deterioration of the physical characteristics of the soil, change in the osmosis of the soil, destruction of soil aggregates as well as ion toxicity due to sodium accumulation. Using domestic wastewater as irrigation water should be preceded by measures to prevent or control the soil salinization caused by sodium. Agricultural reuse of domestic wastewater were found not to cause serious problems with food safety due to heavy metals. However, pre-treatment using ultraviolet or ozone is recommended to reduce the number of bacteria and gem and for public health reasons. Using domestic wastewater has shown that reducing the standard application of chemical fertilizers by as much as 50% reduced the harvesting index by only 10%. This study has shown that it is feasible to reuse domestic wastewater on rice paddies. In order to facilitate the application, it is deemed necessary to establish wastewater treatment technologies in the future, to review criteria for recycling domestic wastewater for agricultural purposes such as conditions of soil and cropping system and to resolve conflicts with farmers and public health issues.

• 한국대기환경학회지
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• 제27권3호
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• pp.337-346
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• 2011

24-hr integrated measurements of water-soluble organic carbon (WSOC) in PM2.5 were made between May 5 and September 25, 2010, on a six-day interval basis, at the Metropolitan Area Air Pollution Monitoring Supersite. A macro-porous XAD7HP resin was used to separate hydrophilic and hydrophobic WSOC. Compounds that penetrate the XAD7HP column are referred to hydrophilic WSOC, while those retained by the column are defined as hydrophobic WSOC. Laboratory calibrations using organic standards suggest that hydrophilic WSOC includes lowmolecular aliphatic dicarboxylic acids and carbonyls with less than 4 or 5 carbons, amines, and saccharides. While the hydrophobic WSOC is composed of compounds of aliphatic dicarboxylic acids with carbon numbers larger than 4~5, phenols, aromatic acids, cyclic acid, and humic-like Suwannee River fulvic acid. Over the entire study period, total WSOC accounted for on average 48% of OC, ranging from 32 to 65%, and hydrophilic WSOC accounted for on average 30.5% (9.3~66.7%) of the total WSOC. Based on the previous results, our measurement result suggests that significant amounts of hydrophobic WSOC during the study period were probably from primary combustion sources. However, on June 9 when 1-hr highest ozone concentration of 130 ppb was observed, WSOC to OC was 0.61, driven by increases in the hydrophilic WSOC. This result also suggests that processes, such as secondary organic aerosol formation, produce significant levels of hydrophilic WSOC compounds that add substantially to the fine particle fraction of the organic aerosol.

• 한국환경과학회지
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• 제18권3호
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• pp.289-298
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• 2009

The blue-green algae which caused odor problem in the tap water are difficult to precipitate in sedimentation basin and clogged the filter void rapidly. The studies of this paper were not only oxidation, coagulation and sedimentation processes for effectively removing blue-green algae but yellow clay and polyamine for verification as coagulants aids. The results of this research are summarized as follows: Higher ozone dose(C) and longer contact time(T) were needed for a high degree of removing blue-green algae efficiency. the removal rate of blue-green algae was proportional to the $C\times T$ value. The removal percent of chlorophyll-a by sedimentation and filter without pre-ozonation was about 75% but 1 mg/L pre-ozonation could increase the removal percent of chlorophyll-a to 99% and more pre-ozonation could remove completely. Though the removal efficiency of turbidity could increased by high dose of chlorination, the dissolved organic carbon was increased. More chlorine dose from 4 to 10 mg/L dissolved organic carbon was decreased. Using yellow clay as coagulant aids increased density of floc so the settling velocity of floc become rising but polyamine could not increase settling velocity of floc though it could formated large floc.

• 청정기술
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• 제9권1호
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• pp.9-21
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• 2003

CFC-113, 1,1,1-TCE는 오존파괴물질로 선진국에서는 이미 사용이 전면 규제되고 있고 MC, TCE는 유해성 또는 발암성물질로 판명되어 일부사업장에서 제한적으로 사용되고 있다. 그러므로 세정성이 좋고 환경/안전성이 우수한 대체세정제를 개발하여 사용하거나 기존 개발된 세정제 중에서 우수한 세정제를 선정하여 사용하는 것이 필요한 실정이다. 대체세정제로는 수계세정제가 환경성과 경제적면에서 유망한 것으로 평가받고 있어 많은 사업장에서 사용될 전망이다. 본 연구에서는 환경친화적인 수계세정제를 개발하기 위하여 수계세정제의 주요성분인 여러 형태의 계면활성제를 선정하여 이들의 물성, 거품성, 오염물 종류에 따른 세정성, 유수분리성을 평가하여 비교하였다.

• 상하수도학회지
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• 제25권6호
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• pp.885-892
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• 2011

In this study, LCA(Life Cycle Assessment) on 'Saemangum CSO Project' was carried out to evaluate environmental impact which occurred during the construction and operation periods and the potential environmental impact reduction was analyzed by comparing production and reduction level of pollution loads. LCA was conducted out according to the procedure of ISO14040 which suggested Goal and Scope Definition, Life Cycle Inventory Analysis, Life Cycle Impact Assessment and Interpretation. In the Goal and Scope Definition, the functional unit was 1 m3 of CSO, the system boundary was construction and operation phases, and the operation period was 20 years. For the data collection and inventory analysis, input energies and materials from civil, architecture, mechanical and electric fields are collected from design sheet but the landscape architecture field is excepted. LCIA(Life Cycle Impact Assessment) was performed following the procedure of Eco-Labelling Type III under 6 categories which were resource depletion, eutrophication, global warming, ozone-layer destruction, and photochemical oxide formation. In the result of LCA, 83.4% of environmental impact occurred in the construction phase and 16.6% in the operation phase. Especially 78% of environmental impact occurred in civil works. The Global warming category showed the highest contribution level in the environmental impact categories. For the analysis on potential environmental impact reduction, the reduction and increased of environmental impact which occurred on construction and operation phases were compared. In the case of considering only the operation phase, the result of the comparison showed that 78% of environmental impact is reduced. On the other hand, when considering both the construction and operation phases, 50% of environmental impact is increase. Therefore, this study showed that eco-friendly material and construction method should be used for reduction of environmental impact during life cycle, and it is strongly necessary to develop technology and skills to reduce environmental impact such as renewable energies.

• Journal of Korean Society for Atmospheric Environment
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• 제22권E1호
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• pp.19-26
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• 2006

The decomposition of gaseous $CH_3CHO$ was investigated by metal loaded $TiO_2$ (pure $TiO_2,\;Pt/TiO_2,\;Pd/TiO_2,\;Mn/TiO_2\;and\;Ag/TiO_2$) with $UV/TiO_2$ process and $UV/TiO_2/O_3$ process at room temperature and atmospheric pressure. Metal loaded $TiO_2$ was prepared by photodeposition. Decomposition of $CH_3CHO$ was carried out in a flow-type photochemical reaction system using three 10W black light lamps ($300{\sim}400nm$) as a light source. The experimental results showed that the degradation rate of $CH_3CHO$ was increased with Pt and Ag on $TiO_2$ compared to pure $TiO_2$, but decreased with depositing Pd and Mn on pure $TiO_2$. The considerable increase in the degradation efficiency of the $CH_3CHO$ was found by a combination of photocatalysis and ozonation as compared to only by ozonation or photocatalysis. Loading of Pt on $TiO_2$ promoted conversion of gaseous ozone. The degradation rate of gaseous $CH_3CHO$ decreased with an increase of water vapor in the feed stream for the both $UV/TiO_2\;and\;UV/TiO_2/O_3$ processes. The pure $TiO_2$ was more affected by the water vapor than Pt loaded $TiO_2$.

• 한국수산과학회지
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• 제51권4호
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• pp.389-396
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• 2018

Marine pathogenic bacteria, such as Streptococcus parauberis, Edwardsiella tarda and Vibrio harveyi, can cause lethal infections in farmed fish, ozone and antibiotics, are employed to sterilize waters used for rearing fish to mitigate this threat. The most widely used method is treatment with sodium hypochlorite solution. However, the maintenance of a constant concentration of chlorine in rearing waters can be difficult. We investigated the potential of a mixed oxidant (MO) solution generated by electrolysis of sea water to improve water quality. We measured the survival rates of fish pathogenic bacteria exposed to different concentrations of MO (0.5, 1.0, 1.5 and 2.0 MO) and sodium hypochlorite (0.5, 1.0, 1.5 and 2.0 ppm) for various lengths of time (0, 5, 10, 15, 20, 25 and 30 min). We found a time-dependent decrease in the survival rates of the tested pathogenic microorganisms. The sterilization effect of the MO solution on pathogenic organisms was greater than that of sodium hypochlorite for gram-negative and gram-positive bacteria. We conclude that MO solution produced by electrolysis could be used to maintain a constant chlorine concentration in aquaculture systems.

• 대한환경공학회지
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• 제32권8호
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• pp.767-773
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• 2010

최근, 가솔린 첨가물인 Methyl tert-butyl ether (MTBE)가 음용수로 사용되는 대수층으로 방출되는 것에 대해 상당한 관심이 되고 있다. MTBE는 친수성이고, 가솔린 유출과 새고 있는 저장탱크 누출에 의해 환경에 노출되어 물과 쉽게 섞이게 된다. 본 논문에서는 실험실 규모 반응기내에서 MTBE 용액의 탈기 및 오존산화반응을 연구하였다. 계산한 질량 전달율(N)은 $1.24{\times}10^{-6}\;mol{\cdot}sec^{-1}$으로 나타났다. MTBE의 오존산화반응 실험결과 COD와 TOC는 각각 8.3%와 6.5% 감소하였고 BOD/COD는 0.03으로 큰 변화가 나타나지 않았다. 유사 1차 반응속도 상수는 $3.75{\times}10^{-5}\;sec^{-1}$으로 나타났다. 활성화 에너지는 4.80 kcal.mol-1로 나타났다.