• Journal of Korean Society for Atmospheric Environment
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• v.24 no.1
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• pp.91-99
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• 2008

A multilayer tower-type photoreactor, in which $TiO_2$-coated glass-tubes were installed, was used to measure the vapor-phase BTEX removal efficiencies by ozone oxidation ($O_3$/UV), photocatalytic oxidation ($TiO_2$/UV) and the combination of ozone and photocatalytic oxidation ($O_3/TiO_2$/UV) process, respectively. The experiments were conducted under various relative humidities, temperatures, ozone concentrations, gas flow rates and BTEX concentrations. As a result, the BTEX removal efficiency and the oxidation rate by $O_3/TiO_2$/UV system were highest, compared to $O_3$/UV and $TiO_2$/UV system. The $O_3/TiO_2$/UV system accelerated the low oxidation rate of low-concentration organic compounds and removed organic compounds to a large extent in a fixed volume of reactor in a short time. Therefore, $O_3/TiO_2$/UV system as a superimposed oxidation technology was developed to efficiently and economically treat refractory VOCs. Also, this study demonstrated feasibility of a technology to scale up a photoreactor from lab-scale to pilot-scale, which uses (i) a separated light-source chamber and a light distribution system, (ii) catalyst fixing to glass-tube media, and (iii) unit connection in series and/or parallel. The experimental results from $O_3/TiO_2$/UV system showed that (i) the highest BTEX removal efficiencies were obtained under relative humidity ranging from 50 to 55% and temperature ranging from 40 to $50^{\circ}C$, and (ii) the removal efficiencies linearly increased with ozone dosage and decreased with gas flow rate. When applying Langmuir-Hinshelwood model to $TiO_2$/UV and $O_3/TiO_2$/UV system, reaction rate constant for $O_3/TiO_2$/UV system was larger than that for $TiO_2$/UV system, however, it was found that adsorption constant for $O_3/TiO_2$/UV system was smaller than that for $TiO_2$/UV system due to competitive adsorption between organics and ozone.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.5
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• pp.642-652
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• 2006

In order to understand the characteristics of surface ozone concentration and high $O_3$ concentration days, regional data from seven air quality monitoring stations which were operated by local governments were analyzed Regional characteristics of $O_3$ concentration were analyzed with the data of $O_3$ concentration and the characteristics of $O_3$ generation and weather conditions by the selection of the days in which the concentration was higher than 80 ppb. In the case of daily variation, the lowest $O_3$ concentration was shown in all regions from 7am to 8am and the highest around at 4 pm. The monthly variation of mean $O_3$ concentration and ${\Delta}O_3$ values revealed a reducing pattern in July and August following the peak in June, and again a gradual increasing trend in September and October. The result shows that the amount of ozone is dependent on photochemical reaction. The days of $O_3$ generated more than 80 ppb in the region of Gwangyang-bay were 544 days(1,760 hrs). The frequency of occurrence in the region revealed a strong pattern with the order of Samil-dong, Jinsang, and Gwangmu-dong stations in the Gwangyang region. However, Tein-dong, which is the nearest station to air pollution material generation source, showed the lowest frequency in the study area. Consequently, the meteorological parameters which can easily generate the high concentration of $O_3$ in the region of Gwangyang-bay are characterized as follows; atmospheric temperature which is higher than $19^{\circ}C$, relative humidity with the range of $60{\sim}85%$, the less average wind velocity than 5 m/s, cloud cover which is less than 5/10, and the more duration of sunshine than 8 hours.

• Journal of the Korean earth science society
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• v.24 no.3
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• pp.216-233
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• 2003

This study delineates the phenomena related with global environmental changes such as global warming, ozone depletion, and El Ni${\tilde{n}}$o/Southern Oscillation (ENSO) noted in the Antarctic. Retreat of ice cliffs, glaciers, and calving of ice shelves indicate the effects of recently aggravated global warming. The ice cliff located at Marian Cove, King George Island, South Shetland Islands off the Antarctic Peninsula has been observed to be retreating faster in the last 7 years than in the previous 38 years since 1956. There are some indications of temperature and precipitation changes associated with ENSO around King Sejong Station. The regression analyses indicate significant trends such as a decrease in the total amount of ozone and an increase in ultraviolet radiation which was seen by a satellite (TOMS-EUV) in September and October which correspond to ozone-hole season over King Sejong Station. Increase of UV radiation due to the ozone depletion in the Antarctic has changed the growth rate of marine organisms. It may also result in changes to the productivity, biomass, and species composition of marine organisms which can affect the whole marine ecosystem. The recent ice-core drilling over Lake Vostok has been reviewed with emphasis on the four cycles of glacial stages over the past 420,000 years. It is time to show more interest in mainland Antarctica through investigations of the coring and vast ice sheet, terrestrial geology, and upper atmospheric sciences in order to understand the past environmental changes and to predict possible changes to the environment in the future.

• Journal of the Korean Data and Information Science Society
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• v.26 no.6
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• pp.1409-1416
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• 2015

The change of temperature influences on the various aspect, especially human health, plant and animal's growth, economics, industry, and culture of the country. In this article, the autoregressive error (ARE) model has been considered for analyzing the monthly temperature data at the Suwon monitoring site in Korea. In the ARE model, five meteorological variables, four greenhouse gas variables and five pollution variables are used as the explanatory variables for the temperature data set. The five meteorological variables are wind speed, rainfall, radiation, amount of cloud, and relative humidity. The four greenhouse gas variables are carbon dioxide ($CO_2$), methane ($CH_4$), nitrous oxide ($N_2O$), and chlorofluorocarbon ($CFC_{11}$). And the five air pollution explanatory variables are particulate matter ($PM_{10}$), sulfur dioxide ($SO_2$), nitrogen dioxide ($NO_2$), ozone ($O_3$), and carbon monoxide (CO). Among five meteorological variables, radiation, amount of cloud, and wind speed are more influence on the temperature. The radiation influences during spring, summer and fall, whereas wind speed influences for the winter time. Also, among four greenhouse gas variables and five pollution variables, chlorofluorocarbon, methane, and ozone are more influence on the temperature. The monthly ARE model explained about 43-69% for describing the temperature.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.6
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• pp.640-652
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• 2007

The MM5, RAMS and WRF, meteorological models have provided the dynamical parameters as inputs to air quality model. A major content of this study is that significant characteristics of three models for high-ozone occurrence analyze for surface wind and air temperature fields and compare with observation data in Seoul metropolitan area. An analysis of air temperature field revealed that location of core in high temperature of MM5 and WRF differed from that of RAMS. MM5 and WRF indicated high temperature in Seoul but RAMS represented it on the outskirts of Seoul. MM5 and WRF were underestimated maximum temperature during daytime but RAMS simulated similar value with observation data. Surface wind field with three models, it was shown many differences at horizontal distribution of wind direction. RAMS indicated weak wind speed in land and strong sea breeze at coastal areas than MM5 and WRF. However wind speed simulated by three model were overestimated during both daytime and nighttime.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.1276-1281
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• 2004

Nowadays CFCs and HCFCs refrigerants are restricted because it cause depletion of ozone layer. Accordingly, this experiment apply the ammonia gas and not CFCs and HCFCs for refrigerant to study the performance characteristic from the superheat control and improve the energy efficiency from the high performance. The condensing pressure of refrigeration system is increased from 15.0bar to 16bar by 0.5bar and superheat temperature is increased from $0^{\circ}C$ to $10^{\circ}C$ by $1^{\circ}C$ at each condensing pressure. As the result of experiment, when the superheat temperature is $0^{\circ}C$ at each condensing pressure, the refrigeration system has the high performance.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.4
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• pp.334-338
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• 2006

Poly silicon TFT requires high quality dielectric film; conventional method of growing silicon dioxide needs highly hazardous chemicals such as silane. We have grown high quality dielectric film of silicon dioxide using non-hazardous chemical such as TFOS and ozone as reaction gases by APCVD. The films grown were characterized through C-V curves of MOS structures. Conventional APCVD requires high temperature processing where as in the process of current study, we developed a low temperature process. Interface trap density was substantially decreased in the silicon surface coated with the silicon dioxide film after annealing in nitrogen ambient. The interface with such low trap density could be used for poly silicon TFT fabrication with cheaper cost and potentially less hazards.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.8
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• pp.756-761
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• 2004

Since the use of CFC and HCFC refrigerants are to be restricted due to the depletion of ozone layer, this experiment applies the NH$_3$ gas to study the performance characteristics from the superheat control for improving the energy efficiency. The experiments are carried out for the condensing pressure of refrigeration system from 14.5 bar to 16.0 bar by 0.5 bar and for superheat temperature from $0^{\circ}C$ to 1$0^{\circ}C$ by 1$^{\circ}C$ at each condensing pressure. As a result of experiment, when the superheat temperature is 1$^{\circ}C$ at each condensing pressure, the refrigeration system has the highest performance.

• Transactions on Electrical and Electronic Materials
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• v.2 no.4
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• pp.11-14
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• 2001

Phase intergrowth in BSCCO thin films has been Investigated. It turfed out from XRD analyses of these phases that molar fraction of each constituent phase in the intergrowth thin film can be exhibited as a function of substrate temperature and ozone pressure. Super- conducting behavior of the intergrowth thin aim Is also discussed.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.E3
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• pp.121-127
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• 2003

The characteristics of heterogeneous photocatalytic decomposition were investigated at low concentration level of $O_3$on TiO$_2$for various operating parameters such as: loaded catalyst weight (0∼4 mg/$\textrm{cm}^2$), initial concentration of $O_3$(0.06∼10.0 ppm), gas flow rate (1.0 ∼ 2.5ι/min), and relative humidity (0∼80%). This study was conducted using a flow-type reactor at room temperature. Three kinds of pure TiO$_2$(P25, ST -01, and E- 23) were employed as photocatalyts. It was found that $O_3$removal ratio was identical, regardless of the loaded TiO$_2$weight in the range from 0.5 to 4.0 mg/$\textrm{cm}^2$. It was also found that higher initial ozone concentration results in greater oxidation rate of ozone and experimental data show kinetically a good agreement with Langmur-Hinshelwood kinetic model. We also observed that the removal ratio of $O_3$increases linearly with the increasing flow rate and also with the increasing relative humidity for each catalyst.