• 제목/요약/키워드: oxide electrode

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AZO anode 전극을 갖는 OLED의 전기적, 광학적 특성 (Electrical and Optical Properties of OLED with AZO Anode Electrode)

  • 진은미;신은철;송민종;박춘배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.91-92
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    • 2006
  • Aluminum-doped zinc oxide (AZO) films are attractive materials as transparent conductive electrode because they are inexpensive, nontoxic and abundant element compared with indium tin oxide (ITO). AZO films have been deposited on glass (corning 1737) substrates by RF magnetron sputtering system. The electrical resistivity of AZO films was $1.81{\times}10^{-2}{\Omega}cm$ and the average transmittance in the visible range 400-800 nm was more than 76% Organic light-emitting diodes (OLEDs) with AZO/TPD/$Alq_3$/Al configuration were fabricated. The current density-voltage properties of devices were studied and compared with ITO devices fabricated under the same conditions.

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고온에서 Pd 전극의 형태가 수소 센서의 감도에 미치는 영향 (Effect on the Sensitivity of a Hydrogen Sensor by Pd Electrode Patterns at High Temperature)

  • 김성진
    • 전기전자학회논문지
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    • 제22권2호
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    • pp.356-361
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    • 2018
  • 고온에서 이용 가능한 수소 센서에 관해 연구하였다. 센서는 $Pd/Ta_2O_5/SiC$으로 구성된 MOS 구조로 제작되었으며, $Ta_2O_5$ 박막은 급속 열 산화법(RTO)법으로 형성하였다. 본 연구에서는 3가지 다른 패턴의 팔라듐(Pd) 전극으로 만든 센서를 제작하여, Pd 전극의 형태가 응답 특성에 미치는 영향을 고찰하였다. 그 결과, 센서는 Pd 전극의 채워진 면적이 클수록, 정전용량의 응답특성이 개선됨을 확인하였다.

Effects of Sealing Time of Anodic Aluminum Oxide (AAO) for Upper Electrode of Etcher

  • 송제범;신재수;신용현;강상우;김진태;윤주영
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.115-115
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    • 2012
  • 반도체/디스플레이 산업분야의 발전으로 진공 공정 기술력 또한 증진되고 있다. 반도체소자의 초미세화, 진공부품의 대면적화가 진행 되면서 진공 공정 중에 발생하는 오염입자를 제어하는 것이 이슈가 되고 있다. 오염입자는 플라즈마의 물리적인 부식과 활성이 높은 화학반응에 의해 진공부품에서 부식이 진행되어 발생하며, 이는 반도체 및 디스플레이 부품의 신뢰성측면과 수율저하 등 life time의 근본적인 문제점으로 대두되고 있다. 본 연구에서는 반도체/디스플레이 장비용 코팅부품으로 많이 사용되고 있는 Al2O3 코팅막을 이용하였으며, sealing time에 따른 Anodic Aluminum Oxide (AAO) electrode의 물성특성평가 및 진공평가기술을 이용하여 life time을 예측하는 연구를 수행하였다.

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The Effect of Surface Modification with La-M-O (M = Ni, Li) on Electrochemical Performances of Li[Ni0.8Co0.15Al0.05]O2 Cathode

  • Ryu, Jea-Hyeok;Kim, Seuk-Buom;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • 제30권3호
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    • pp.657-660
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    • 2009
  • The surface of $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ cathode particle was modified by lanthanum based oxide to improve electrochemical property and thermal stability. The XRD pattern of surface layer was indexed with that of $La_4NiLiO_8$. The discharge capacity of modified electrode was higher than that of pristine sample, specially at fast charge-discharge rate and high cut-off voltage. In the DSC profile of the charged sample, the generation of heat by exothermic reaction was decreased by surface modification. Such enhancement may by attributed to the presence of stable lanthanum based oxide, which effectively suppressd the reaction between electrode and electrolyte on the surface of $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ electrode.

Copper Oxide-Modified Polymeric Composite Elecrodes for Amperometric Detection of Carbohydrates in LCEC Analysis

  • 정혜경;박종만
    • Bulletin of the Korean Chemical Society
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    • 제18권9호
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    • pp.952-957
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    • 1997
  • Modified polymeric composite electrodes having highly dispersed CuO particles through the electrode matrix were prepared for LCEC or flow injection analysis of carbohydrates. The composite electrodes were prepared by incorporating carbon black and highly dispersed copper oxide particles in polystyrene matrix cross-linked with divinylbenzene. The analytical characteristics of the electrodes for LCEC and flow injection analysis of carbohydrates were evaluated. Improved performance in LCEC and flow injection analysis of carbohydrates is demonstrated in terms of sensitivity, reproducibility, stability and surface renewability. It was possible to get improved performance of the electrodes as well as adaptability of the electrodes for practical applications by employing highly dispersed catalyst particles through the electrode matrix and robust polymeric electrode matrix.

산화물기반 박막트랜지스터 전극용 ITO박막의 제작시 투입 산소 분압 의존성 (Dependency of Oxygen Partial Pressure of ITO Films for Electrode of Oxide-based Thin-Film Transistor)

  • 김경환
    • 반도체디스플레이기술학회지
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    • 제20권2호
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    • pp.82-86
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    • 2021
  • In this study, we investigated the oxygen partial pressure effect of ITO films for electrodes of oxide-based Thin-Film Transistor (TFT). Firstly, we deposited single ITO films on the glass substrate at room temperature. ITO films were prepared at the various partial pressures of oxygen gas 0-7.4% (O2/(Ar+O2)). As increasing oxygen on the process of film deposition, electrical properties were improved and optical transmittance increased in the visible light range (300-800 nm). For the electrode of TFT, we fabricated a TFT device (W/L=1000/200 ㎛) with ITO films as the source and drain electrode on the silicon wafer. Except for the TFT device combined with ITO film prepared at the oxygen partial pressure ratio of 7.4%, We confirmed that TFT devices with ITO films via FTS system operated as a driving device at threshold voltage (Vth) of 4V.

Electrochemical behavior of dissolved hydrogen at Pt electrode surface in a high temperature LiOH-H3BO3 solution: Effect of chloride ion on the transient current of the dissolved hydrogen

  • Myung-Hee Yun;Jei-Won Yeon
    • Nuclear Engineering and Technology
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    • 제55권10호
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    • pp.3659-3664
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    • 2023
  • The electrochemical behavior of dissolved hydrogen (H2) was investigated at a Pt electrode in a high temperature LiOH-H3BO3 solution. The diffusion current of the H2 oxidation was proportional to the concentration of the dissolved H2 as well as the reciprocal of the temperature. In the polarization curve, a potential region in which the oxidation current decreases despite an increase in the applied potential between the H2 oxidation and the water oxidation regions was observed. This potential region was interpreted as being caused by the formation of a Pt oxide layer. Using the properties of the Cl- ion that reduces the growth rate of the Pt oxide layer, it was confirmed that there is a correlation between the Cl- ion concentration and the transient current of the H2 oxidation.

Simultaneous Voltammetric Determination of Mefenamic Acid and Paracetamol using Graphene Nanosheets/Nickel Oxide Nanoparticles Modified Carbon Paste Electrode

  • Naeemy, Ali;Gholam-Shahbazi, Rozhina;Mohammadi, Ali
    • Journal of Electrochemical Science and Technology
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    • 제8권4호
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    • pp.282-293
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    • 2017
  • A new modified carbon paste electrode (CPE) was constructed based on nickel oxide nanoparticles (NiONPs) and graphene nanosheets (Gr) for simultaneous determination of paracetamol (PCM) and mefenamic acid (MFA) in aqueous media and pharmaceutical dosage forms. NiONPs were synthesized via a simple and inexpensive technique and characterized using X-ray diffraction method. Scanning electron microscopy was used for the characterization of the morphology of modified carbon paste electrode (NiONPs/Gr/CPE). Voltammetric studies suggest that the NiONPs and Gr provide a synergistic augmentation that can increase current responses by improvement of electron transfers of these compounds on the NiONPs/Gr/CPE surface. Using cyclic voltammetry, the NiONPs/Gr/CPE showed good sensitivity and selectivity for the determination of PCM and MFA in individually or mixture standard samples in the linear range of $0.1-30{\mu}g\;mL^{-1}$. The resulted limit of detection and limit of quantification were 20 and $60ng\;mL^{-1}$ for PCM, 24 and $72ng\;mL^{-1}$ for MFA, respectively. The analytical performance of the NiONPs/Gr/CPE was evaluated for the determination of PCM and MFA in pharmaceutical dosage forms with satisfactory results.

Sol-gel 법을 이용한 이성분 금속산화물 ($IrO_2-RuO_2$) pH 센서 (Binary Metal Oxide ($IrO_2-RuO_2$) pH Sensor Prepared by Sol-gel Method)

  • 이정란;오세림;한원식;홍태기
    • 한국응용과학기술학회지
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    • 제31권2호
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    • pp.190-196
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    • 2014
  • The sol-gel method was used to prepare binary metal oxide ($IrO_2-RuO_2$) pH sensor. The electrodes that mole percent compositions (mol%) of $IrO_2$ and RuO2 were 70:30 and 30:70 were selected. The characterizations of Nernstian response over pH range, response rate, interference on alkaline metals and reproducibility were investigated. Also the electroanalytical properties of these electrodes were evaluated in comparison with a commercial glass pH electrode. The composition of $IrO_2:RuO_2$ 70:30 mol% was chosen as better electrode formulation. The electrode was not susceptible to the action of interfering ions such as $Li^+$, $Na^+$ and $K^+$.

Preparation and application of reduced graphene oxide as the conductive material for capacitive deionization

  • Nugrahenny, Ayu Tyas Utami;Kim, Jiyoung;Kim, Sang-Kyung;Peck, Dong-Hyun;Yoon, Seong-Ho;Jung, Doo-Hwan
    • Carbon letters
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    • 제15권1호
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    • pp.38-44
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    • 2014
  • This paper reports the effect of adding reduced graphene oxide (RGO) as a conductive material to the composition of an electrode for capacitive deionization (CDI), a process to remove salt from water using ionic adsorption and desorption driven by external applied voltage. RGO can be synthesized in an inexpensive way by the reduction and exfoliation of GO, and removing the oxygen-containing groups and recovering a conjugated structure. GO powder can be obtained from the modification of Hummers method and reduced into RGO using a thermal method. The physical and electrochemical characteristics of RGO material were evaluated and its desalination performance was tested with a CDI unit cell with a potentiostat and conductivity meter, by varying the applied voltage and feed rate of the salt solution. The performance of RGO was compared to graphite as a conductive material in a CDI electrode. The result showed RGO can increase the capacitance, reduce the equivalent series resistance, and improve the electrosorption capacity of CDI electrode.