• 제목/요약/키워드: oxidative induction time

검색결과 58건 처리시간 0.019초

소맥배아유의 산화안정성 (Oxidative stability of crude wheat germ oil)

  • 표영희
    • 대한가정학회지
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    • 제29권4호
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    • pp.37-43
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    • 1991
  • Oxidative stability of crude wheat germ oil (WGO) was determined by the active oxygen method(Rancimat, hrs at 98$^{\circ}C$). The induction time of crude WGO was 7.6hrs as compared to 23.7hrs of crude soybean oil. However, the induction time of WGO could be extended by 2-3 times with 300ppm of mixed tocopherols and 200ppm of organic acids. The antioxidant effect of organic acids increased in the order of L-ascorbic acid > tartaric acid > citric acid > malic acid. Especially, the induction time of WGO could be extended by ca. 38hrs with 500ppm of L-ascorbic acid. This antioxiative effect of 500ppm L-ascorbic acid with mixed tocopherol(100, 200, 300 or 500ppm). It seems that the synergistic effect of L-ascorbic acid was due to the high content of tocopherols(0.4%) in WGO.

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Thermal Oxidative Stability of Various Vegetable Oils used for the Preparation of the Seasoned Laver Pyropia spp.

  • Kim, Jiyoung;Shin, Eui-Cheol;Lim, Ho-Jeong;Yoon, Minseok;Yang, Hyejin;Park, Joodong;Park, Eun-Jeong;Yoo, Hyunil;Baek, Jeamin;Cho, Suengmok
    • Fisheries and Aquatic Sciences
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    • 제18권1호
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    • pp.21-26
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    • 2015
  • Seasoned laver Pyropia spp. is a traditional Korean seafood that has gained popularity worldwide because of its unique taste, texture, and health benefits. It is prepared by roasting a sheet of dried laver, to which vegetable oils have been applied, at an ultra-high temperature (UHT) of $300^{\circ}C$. Therefore, the oxidative stability of the oils is the most important factor in determining the shelf life of seasoned laver products. In this study, we investigated changes in the thermal oxidative stability of six major vegetable oils (sesame, perilla, sunflower, rice bran, canola, and olive) during the seasoned laver processing. The oxidation induction time of each oil from the seasoned laver products was decreased compared with the fresh oil. These results indicate that the UHT treatment ($300^{\circ}C$, 10 s) induced thermal oxidation of the oils. Among the six seasoned laver oils, the induction times of olive (OL, 8.02 h) and sesame (SE, 5.31 h) oils were significantly higher than the other oils. The acid values (AVs) of OL and SE oils from the seasoned laver were 0.49 and 0.79, respectively. On the other hand, perilla oil had the overall worst thermal oxidative properties (induction time: 0.35 h, AV: 2.82). Our results provide useful information about seasoned laver products for researchers or manufactures.

Long-Term Performance of Geomembranes by Oxidative Induction Time

  • 정한용;김홍관;금재호;장용채;류원석;김한도
    • 한국지반신소재학회논문집
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    • 제2권3호
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    • pp.19-24
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    • 2003
  • 폐기물 매립지 바닥층 및 사면에 적용되는 평편 형 및 텍스츄어드 형 고밀도 폴리에틸렌 지오멤브레인의 장기성능이 검토되었다. 특수 설계된 스크래치 장치를 이용하여 인위적으로 지오멤브레인 표면에 결함을 부여하였다. 결함 및 미결함 지오멤브레인의 역학적 및 마찰특성, 화학저항성 및 자외선 저항성 그리고 산화유도시간 등이 검토되었다. 텍스츄어드 형 지오멤브레인의 마찰특성이 평편 형 지오멤브레인 보다 우수함을 알 수 있었다. 끝으로 화학저항성, 자외선 저항성 그리고 산화유도시간 측정결과로부터 결함이 없는 지오멤브레인과 텍스츄어드 형 지오멤브레인의 장기성능이 결함이 있는 지오멤브레인보다 우수함을 알 수 있었다.

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살리실산이 오이 잎의 산화적 스트레스와 UV-B 내성에 미치는 영향 (Effects of Salicylic Acid on Oxidative Stress and UV-B Tolerance in Cucumber Leaves)

  • 홍정희;김태윤
    • 한국환경과학회지
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    • 제16권12호
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    • pp.1345-1353
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    • 2007
  • The effect of salicylic acid(SA) on antioxidant system and protective mechanisms against UV-B induced oxidative stress was investigated in cucumber(Cucumis sativus L.) leaves. UV-B radiation and SA were applied separately or in combination to first leaves of cucumber seedlings, and dry matter accumulation, lipid peroxidation and activities of antioxidant enzymes were measured in both dose and time-dependant manner. UV-B exposure showed reduced levels of fresh weight and dry matter production, whereas SA treatment significantly increased them. SA noticeably recovered the UV-B induced inhibition of biomass production. UV-B stress also affected lipid peroxidation and antioxidant enzyme defense system. Malondialdehyde(MDA), a product of lipid peroxidation, was greatly increased under UV-B stress, showing a significant enhancement of a secondary metabolites, which may have antioxidative properties in cucumber leaves exposed to UV-B radiation. Combined application of UV-B and SA caused a moderate increase in lipid peroxidation. These results suggest that SA may mediate protection against oxidative stress. UV-B exposure significantly increased SOD, APX, and GR activity compared with untreated control plants. Those plants treated with 1.0 mM SA showed a similar pattern of changes in activities of antioxidant enzymes. SA-mediated induction of antioxidant enzyme activity may involve a protective accumulation of $H_2O_2$ against UV-B stress. Moreover, their activities were stimulated with a greater increase by UV-B+SA treatment. The UV-B+SA plants always presented higher values than UV-B and SA plants, considering the adverse effects of UV-B on the antioxidant cell system. ABA and JA, second messengers in signaling in response to stresses, showed similar mode of action in UV-B stress, supporting that they may be important in acquired stress tolerance. Based on these results, it can be suggested that SA may participates in the induction of protective mechanisms involved in tolerance to UV-B induced oxidative stress.

$^{60}Co\;{\gamma}$-선 조사에 따른 클로프렌 고무의 열적 특성 (Thermal Properties of Chloroprene Rubber with $^{60}Co\;{\gamma}$-ray Irradiation)

  • 김기엽;이청;류부형
    • 한국안전학회지
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    • 제18권4호
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    • pp.64-70
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    • 2003
  • The thermal properties of chloroprene rubber (CR) with $^{60}Co\;{\gamma}$-ray irradiation has been investigated. The prepared CR was irradiated up to 1000kGy radiation dose by $^{60}Co\;{\gamma}$-ray and the radiation degradation of CR was investigated by thermogravimetric analysis and differential acanning calorimetry. Dynamic mechanical properties measurement and FT-IR observation are carried out as well. From these analyses results, the glass transition temperature($T_g$), decomposition onset temperature(DOT), oxidative induction time(OIT), the peak temperature of loss modulus and mechanical tan ${\delta}$ values were compared for the radiation degradation level of CR. The tendency between $T_g$ and peak temperature of loss modulus and mechanical tan ${\delta}$ agreed well with radiation doses. Decomposition temperature, OIT and DOT showed the same tendencies as increasing radiation doses. It was verified that these analyses are available to estimate the degradation level of CR.

매설강관용 폴리에틸렌 피복재의 내구성 (A Study on the Durability of the Polyethylene Coatings for Underground Pipeline)

  • 류근창;이성민;고영태
    • 한국가스학회지
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    • 제6권4호
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    • pp.40-46
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    • 2002
  • 천연가스 수송배관은 매설환경에서의 방식 및 외부충격 등에 대비하여 배관을 보호할 목적으로 폴리에틸렌(polyethylene)으로 피복(coating)되어 있다. 국내 천연가스의 보급과 함께 배관피복 기술도 초기 사용하던 폴리에틸렌 테이프에서, 분말용착식의 1층(one-layer), 압출식의 2층 피복으로 발전되어 현재는 에폭시 층이 도입된 3층 피복 시스템을 적용한 배관들이 전국에 매설되고 있다. 그러나 강관에 적용된 폴리에틸렌 피복이 경우에 따라 장기간사용에 따른 자연균열이 발생하여 피복의 안정성에 문제를 일으키기도 하므로, 상업적인 배관 피복재들의 내구 물성의 분포를 확인하여 천연가스 수송용 배관의 신뢰성 확보에 기여하고자 하였다. 이를 위하여 선진외국에서 폴리에틸렌 배관의 내구성과 장기사용안정성 평가를 위해 오래 전부터 활용되고 있는 저속균열저항성(slow crack growth resistance: SCGR)과 배관 피복층의 산화유도시간(oxidative induction time: OIT)을 측정하여 국내 배관 피복재들의 내구성을 평가하고 이를 근거로 하여 적합한 폴리에틸렌 물성치의 목표값을 제안하였다.

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Effects of Oxidative Stress on the Expression of Aldose Reductase in Vascular Smooth Muscle Cells

  • Kim, Hyo-Jung;Chang, Ki-Churl;Seo, Han-Geuk
    • The Korean Journal of Physiology and Pharmacology
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    • 제5권3호
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    • pp.271-278
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    • 2001
  • Oxidative stress and methylglyoxal (MG), a reactive dicarbonyl metabolites produced by enzymatic and non-enzymatic reaction of normal metabolism, induced aldose reductase (AR) expression in rat aortic smooth muscle cells (SMC). AR expression was induced in a time-dependent manner and reached at a maximum of 4.5-fold in 12 h of MG treatment. This effect of MG was completely abolished by cyclohemide and actinomycin D treatment suggesting AR was synthesized by de novo pathway. Pretreatment of the SMC with N-acetyl-L-cysteine significantly down-regulated the MG-induced AR mRNA. Furthermore, DL-Buthionine-(S,R)-sulfoximine, a reagent which depletes intracellular glutathione levels, increased the levels of MG-induced AR mRNA. These results indicated that MG induces AR mRNA by increasing the intracellular peroxide levels. Aminoguanidine, a scanvenger of dicarbonyl, significantly down-regulated the MG-induced AR mRNA. In addition, the inhibition of AR activities with statil, an AR inhibitor, enhanced the cytotoxic effect of MG on SMC under normal glucose, suggesting a protective role of AR against MG-induced cell damages. These results imply that the induction of AR by MG may contribute to an important cellular detoxification of reactive aldehyde compounds generated under oxidative stress in extrahepatic tissues.

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지오멤브레인의 장기성능 평가(1) - 열노화 및 자외선 처리 후 산화유도시간 (Assessments of Long Term Performance of Geomembranes(1) - Oxidative Induction Time with Thermal Ageing and UV treatment)

  • 전한용;김홍관;최준동;금재호
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2002년도 봄 학술발표회 논문집
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    • pp.329-332
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    • 2002
  • 고밀도 폴리에틸렌(HDPE, High Density Polyethylene) 지오멤브레인은 독성 폐기물 처리시설에서 차수재로 광범위하게 이용되고 있으며, 열이나, 자외선, 그리고 산소와 화학약품에 노출되었을 때의 내구성이 장기성능에 커다란 영향을 미친다 어떤 원인에 의해서 지오멤브레인이 산화될 경우에는 지오멤브레인의 파괴가 가속화되어 구조 시스템의 안정성을 저하시키는 심각한 현상이 발생하게 된다. (중략)

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목단피가 세포고사의 억제에 미치는 영향에 관한 연구 (Studies on the Anti-apoptotic Effect of the Mudanpi)

  • 권덕윤;배영춘;이상민;유관석;주종천;김경요
    • 동의생리병리학회지
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    • 제18권4호
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    • pp.1071-1077
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    • 2004
  • Mudanpi (Cortex Moutan Radicis; the root cortex of Paeonia suffruticosa Andrews) is an important Chinese crude drug used in many oriental prescriptions. 1,2,3,4,6-Penta-O-galloyl-beta-D-glucose (PGG), a major component of this crude drug, has been shown to possess potent antioxidant, anti-mutagenic and anti-proliferative effects. In this study, I examined whether PGG could protect Neuro 2A cells, a kind of neuronal cell lines, from oxidative damage through the induction of HO-1 expression and HO activity. Exposure of Neuro 2A cells to PGG (10-50μM) resulted in a concentration- and time-dependent induction of HO-1 mRNA, and protein expressions and heme oxygenase activity. PGG protected the cells from hydrogen peroxide-induced cell death. The protective effect of PGG on hydrogen peroxide-induced cell death was abrogated by zinc protoporphyrin IX (ZnPP IX), a HO inhibitor. These results indicate that PGG is a potent inducer of HO-1 and HO-1 induction is responsible for the PGG-mediated cytoprotection against oxidative damage.