• Title/Summary/Keyword: organic dyes

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Dyeing Characteristics and Mechanical Properties of High Tenacity Polyethylene(HTPE) Filament using Solvent Dyes (솔벤트 염료를 이용한 고강도 폴리에틸렌(HTPE) 필라멘트사의 염색성 및 기계적 물성 평가)

  • Lee, Jeong Hoon;Lee, Beom Young;Lee, Seung O;Choi, Kyeong Yong;Ko, Jae Wang;Kim, Jung Su;Kim, Taekyeong;Lee, Seung Geol
    • Textile Coloration and Finishing
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    • v.29 no.3
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    • pp.105-114
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    • 2017
  • High tenacity polyethylene(HTPE) fiber is one of the most important synthetic fibers which possesses outstanding properties such as low density, excellent surface hardness and scratch resistance, superior electrical insulation and low cost. In this study, we dyed high tenacity polyethylene filaments using three different solvent dyes based on log P calculations. We evaluated the dyeing characteristics of dyed high tenacity polyethylene filaments based on dyeing temperature, dyeing time and concentration of solvent dyes. We also analyzed the tensile strength and elongation properties of dyed high tenacity polyethylene filaments with various dyeing temperature and dyeing times. The optimized dyeing condition can be found at $120^{\circ}C$ for dyeing time of 1 hour with 4%(o.w.f.) of solvent dyes.

Research and Development of Functional Colorants Materials (색소기능재료의 개발 및 동향)

  • Jun, Kun;Son, Young-A
    • Korean Chemical Engineering Research
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    • v.52 no.1
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    • pp.1-7
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    • 2014
  • The traditional application of organic dye provides the coloration effects toward various substrates such as textiles, paper, plastic, leather and so on. However, in recent years, these organic dyes, namely colorants, have a great attention in the high technology or high performance industries of electronics and reprographics. In the subsequent discussion of this manuscript, particular emphasis will be given using various examples and explanations on colorant and color chemistry. These high performance uses present interesting challenges to the colorant chemist to design dyes to satisfy the often demanding criteria required. In this context, the following content describes how those researches are being met in the important colorant application to the academic and industrial areas.

White Organic Light-emitting Diodes using red and blue phosphorescent materials (적색과 청색 인광 소재를 이용한 백색 유기 발광 소자에 관한 연구)

  • Park, Jung-Hyun;Choi, Hak-Bum;Kim, Gu-Young;Lee, Seok-Jae;Seo, Ji-Hyun;Seo, Ji-Hoon;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.64-65
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    • 2007
  • High-efficiency white organic light-emitting diodes (WOLEDs) were fabricated with two emissive layers and exciton blocking layer was sandwiched between two phosphorescent dyes which were, bis(3,5-Difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl) iridium III (Flrpic) as blue emission and a newly synthesized red phosphorescent material guest, Bis(5-benzoyl-2-phenylpyridinato-C,N)iridium(III) (acetylacetonate) ((Bzppy)2Ir(III)acac). This exciton blocking layer prevents a triple-triple energy transfer between the two phosphorescent emissive layers with balanced emission of blue and red. The white device showed the Commission Internationale d'Eclairage (CIEx,y) coordinates of (0.34, 0.40) at the maximum luminance of $24100\;cd/m^2$ and maximum luminous efficiency of 22.4 cd/A, respectively.

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Analyses of Harmful Substances in Textile Products according to the European Eco-Label Criteria - I (에코라벨 기준에 의한 국내 섬유제품의 분석-I)

  • 최은경;조영달;박경수;이현경
    • Textile Coloration and Finishing
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    • v.15 no.5
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    • pp.340-347
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    • 2003
  • Present situation of Korean textile products regarding European eco-label criteria was assessed by analyzing harmful substances including pH, PCP & TeCP, formaldehyde, heavy metals, cleavable arylamines, allergenic dyes, pesticides, organic carriers, TBT as well as color fastness as the minimum quality requirement. Fabric specimens were submitted from six typical textile companies for product eco-testing. In six product groups selected, arylamines, allergenic dyes, halogenated organic carriers and color fastness were found to be parameters that failed to meet the criteria. Source elucidation of harmful substances were presented with their instrumental analysis results.

Fabrication of Photoluminescent Dye Embedded PMMA Nanofiber and its Fluorescence Resonance Energy Transfer

  • Lee, Kyung-Jin;Oh, Joon-Hak;Kim, Young-Geun;Jang, Jyong-Sik
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.314-314
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    • 2006
  • The FRET property has been extensively studied from the theoretical view points to the practical applications. In case that the donor and acceptor are confined in nanodimension, the FRET effectively occurs, because of their distant dependent characteristic. However, there are no reports concerning FRET with one dimensional (1D) nanomaterial. We have successfully prepared the PMMA nanotubes using vapor deposition polymerization as the platform of FRET. The dye-PMMA composite nanofiber has also been produced without phase separation and any deterioration of properties of the dyes. The PMMA 1D nanocomposite doped two dyes with great spectral overlap between donor and acceptor displayed FRET property.

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Synthesis of Novel Quinacridone Dyes and Their Photovoltaic Performances in Organic Dye-sensitized Solar Cells

  • SaKong, Chun;Kim, Se-Hun;Yuk, Sim-Bum;Kim, Jeong-Yun;Park, Se-Woong;Ko, Min-Jae;Kim, Jae-Pil
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2553-2559
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    • 2011
  • Two novel quinacridone (QNC) dyes with thiophene or benzene-conjugated bridge and cyanoacrylic acid acceptor were first designed and synthesized for use in dye-sensitized solar cells (DSSCs). The absorption spectra, electrochemical and photovoltaic properties of these dyes were investigated. Under simulated AM 1.5G irradiation conditions, the solar cell based on the quinacridone dye containing thiophene as a bridge unit had a short-circuit photocurrent density of 8.51 $mA{\cdot}cm^{-2}$, an open-circuit voltage of 643.6 mV, and a fill factor of 0.70, corresponding to an overall conversion efficiency of 3.86%.

Photodecomposition of Different Organic Dyes Using Fe-CNT/TiO2 Composites under UV and Visible Light

  • Zhang, Kan;Meng, Ze-Da;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.169-176
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    • 2010
  • The Fe-treated CNT/$TiO_2$ photocatalysts mixed with anatase and rutile phase have been developed for the decomposition of non-biodegradable different organic dyes like methylene blue (MB), rhodamine B (Rh.B), and methyl orange (MO) in two conditions as ultraviolet and visible light respectively. The results indicate that all the Fe-CNT/$TiO_2$ composites proved to be more efficient photocatalysts since degradation of MB at higher reaction rates, tthe decomposition rate of different dyes increases with an increase of $Fe^{3+}$ concentration in composites the highest rate of decomposition of different dyes was noted under UV irradiation. These results can indicate that the large CNT network is facilitate the electron transfer and strongly adsorb dye molecules on the texted photocatalysts, iron is reactive in the photo-Fenton process resulting in high production of OH radicals and also high activity of the photocatalyst. And Fe particles can generate more photoinduced electrons to conduction band of $TiO_2$ under visible light irradiation. The composites of Fe-CNT/$TiO_2$ photocatalysts synthesized by a sol-gel method were characterized by BET, TEM, SEM, XRD and EDX.

Synthesis of SnO2-Mn-C60 Nanocomposites and Their Photocatalytic Activity for Degradation of Organic Dyes

  • Li, Jiulong;Ko, Jeong Won;Ko, Weon Bae
    • Elastomers and Composites
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    • v.52 no.4
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    • pp.287-294
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    • 2017
  • Nanocomposites based on $SnO_2-Mn$ were synthesized by the reaction of tin (II) chloride dihydrate and manganese (II) chloride tetrahydrate at a molar ratio of 10:1 in the presence of ammonium hydroxide at $80^{\circ}C$. The $SnO_2-Mn$ nanocomposites were stirred with fullerene [$C_{60}$] in a mass ratio of 2:1 in tetrahydrofuran to prepare $SnO_2-Mn-C_{60}$ nanocomposites; these nanocomposites were obtained upon heating the mixture of $SnO_2-Mn$ nanocomposites and fullerene [$C_{60}$] in an electric furnace at $700^{\circ}C$ for 2 h. The synthesized $SnO_2-Mn-C_{60}$ nanocomposites were confirmed through various characterization methods such as X-ray diffraction and scanning electron microscopy. The photocatalytic activities of the $SnO_2-Mn-C_{60}$ nanocomposites were demonstrated by the degradation of the organic dyes BG, MB, MO, and RhB under 254 nm irradiation and evaluated using UV-Vis spectrophotometry.

Sonochemical Synthesis of $PbMoO_4$ Nanoparticles and Evaluation of its Photocatalytic Activity

  • Uresti, Diana B. Hernandez;De la Cruz, Azael Martinez;Martinez, Leticia M. Torres;Lee, Soo-Wohn
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.49.2-49.2
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    • 2011
  • $PbMoO_4$ nanoparticles were successfully obtained in the presence of ethylene glycol (EG) with the assistance of a prolonged sonication process. The nanoparticles were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), diffuse reflectance spectroscopy (DRS) and adsorption-desorption $N_2$ isotherms (BET). The catalyst prepared sonochemically showed higher photocatalytic activity than $PbMoO_4$ prepared by solid-state reaction in the degradation reactions of rhodamine B (rhB), indigo carmine (IC), orange G (OG), and methyl orange (MO) under UV-Vis light radiation. In order to elucidate aspects of the degradation mechanism of the organic dyes, some experimental variables were modified such as pH, $O_2$ level in solution, and radiation source. In general, the photocatalytic activity for the degradation of organic dyes followed the sequence IC>OG>rhB>MO.

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