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http://dx.doi.org/10.5012/bkcs.2011.32.8.2553

Synthesis of Novel Quinacridone Dyes and Their Photovoltaic Performances in Organic Dye-sensitized Solar Cells  

SaKong, Chun (Department of Materials Science and Engineering, Seoul National University)
Kim, Se-Hun (Department of Materials Science and Engineering, Seoul National University)
Yuk, Sim-Bum (Department of Materials Science and Engineering, Seoul National University)
Kim, Jeong-Yun (Department of Materials Science and Engineering, Seoul National University)
Park, Se-Woong (Solar Cell Research Center, Materials Science and Technology Division, Korea Institute of Science and Technology (KIST))
Ko, Min-Jae (Solar Cell Research Center, Materials Science and Technology Division, Korea Institute of Science and Technology (KIST))
Kim, Jae-Pil (Department of Materials Science and Engineering, Seoul National University)
Publication Information
Bulletin of the Korean Chemical Society / v.32, no.8, 2011 , pp. 2553-2559 More about this Journal
Abstract
Two novel quinacridone (QNC) dyes with thiophene or benzene-conjugated bridge and cyanoacrylic acid acceptor were first designed and synthesized for use in dye-sensitized solar cells (DSSCs). The absorption spectra, electrochemical and photovoltaic properties of these dyes were investigated. Under simulated AM 1.5G irradiation conditions, the solar cell based on the quinacridone dye containing thiophene as a bridge unit had a short-circuit photocurrent density of 8.51 $mA{\cdot}cm^{-2}$, an open-circuit voltage of 643.6 mV, and a fill factor of 0.70, corresponding to an overall conversion efficiency of 3.86%.
Keywords
Quinacridone chromophore; Organic dyes; Dye-sensitized solar cell; Intramolecular charge transfer; Thiophene; Benzene;
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