DOI QR코드

DOI QR Code

Dyeing Characteristics and Mechanical Properties of High Tenacity Polyethylene(HTPE) Filament using Solvent Dyes

솔벤트 염료를 이용한 고강도 폴리에틸렌(HTPE) 필라멘트사의 염색성 및 기계적 물성 평가

  • Lee, Jeong Hoon (Department of Organic Material Science and Engineering, Pusan National University) ;
  • Lee, Beom Young (Department of Organic Material Science and Engineering, Pusan National University) ;
  • Lee, Seung O (Dongmyung Technology) ;
  • Choi, Kyeong Yong (Kyungeun Textile Industrial Co., Ltd.) ;
  • Ko, Jae Wang (Korea Institute of Footwear and Leather Technology) ;
  • Kim, Jung Su (Korea Institute of Footwear and Leather Technology) ;
  • Kim, Taekyeong (Department of Textile System Engineering, Kyungpook National University) ;
  • Lee, Seung Geol (Department of Organic Material Science and Engineering, Pusan National University)
  • 이정훈 (부산대학교 유기소재시스템공학과) ;
  • 이범영 (부산대학교 유기소재시스템공학과) ;
  • 이승오 (동명기술(주)) ;
  • 최경용 (경은산업(주)) ;
  • 고재왕 (한국신발피혁연구원) ;
  • 김정수 (한국신발피혁연구원) ;
  • 김태경 (경북대학교 섬유시스템공학과) ;
  • 이승걸 (부산대학교 유기소재시스템공학과)
  • Received : 2017.07.07
  • Accepted : 2017.08.08
  • Published : 2017.09.27

Abstract

High tenacity polyethylene(HTPE) fiber is one of the most important synthetic fibers which possesses outstanding properties such as low density, excellent surface hardness and scratch resistance, superior electrical insulation and low cost. In this study, we dyed high tenacity polyethylene filaments using three different solvent dyes based on log P calculations. We evaluated the dyeing characteristics of dyed high tenacity polyethylene filaments based on dyeing temperature, dyeing time and concentration of solvent dyes. We also analyzed the tensile strength and elongation properties of dyed high tenacity polyethylene filaments with various dyeing temperature and dyeing times. The optimized dyeing condition can be found at $120^{\circ}C$ for dyeing time of 1 hour with 4%(o.w.f.) of solvent dyes.

Keywords

References

  1. E. P. Kim, Dyeing Method of Ultra High Molecular Weight Polyethylene Fiber and Work Glovesmade from Dyed Ultra High Molecular Weight Polyethylene Fiber using This, KR101287041B1(2013).
  2. T. K. Kim, Dyeing Method of Ultra-High Molecular Weight Polyethylene, KR10-1172860-0000(2012).
  3. Y. A. Son and J. Y. Hwang, DyeingMethod of Polyolefine Based Fiber, KO10-1590732-0000(2016).
  4. S. U. Kim, "Steel Fiber Floating in Water, Ultra High Molecular Weight Polyethylene", DYETEC, Daegu, pp.1-19, 2012.
  5. P. Smith and P. J. Lemstra, Ultra-High-Strength Polyethylene Filaments by Solution Spinning-Drawing, J. of Materials Science, 15(2), 505(1980). https://doi.org/10.1007/BF02396802
  6. T. K. Kim and C. W. Lee, Synthesis of a Super Hydrophobic Violet Dye for Pure Polyolefin(PP/UHMWPE) Fibers, Textile Coloration and Finishing, 25(3), 165 (2013). https://doi.org/10.5764/TCF.2013.25.3.165
  7. T. K. Kim and M. H. Ryu, Synthesis of Super Hydrophobic Orange Dyes having Maximum Absorption at 450-500nm for Pure Polyolefin Fibers, Textile Coloration and Finishing, 26(3), 165(2014). https://doi.org/10.5764/TCF.2014.26.3.165
  8. N. Jo, J. Lee, and T. K. Kim, Synthesis of Bluish-green Dyes for Pure Polyolefin Fibers, Textile Coloration and Finishing, 28(3), 156(2016). https://doi.org/10.5764/TCF.2016.28.3.156
  9. T. K. Kim, M. H. Ryu, andY. J. Jang, Synthesis of Super Hydrophobic Disazo Red Dyes using Alkylanilines as Diazo Components, Textile Coloration and Finishing, 27(1), 27(2015). https://doi.org/10.5764/TCF.2015.27.1.27
  10. R. Mannhold, G. I. Poda, C. Ostermann, and I. V. Tetko, Calculation of Molecular Lipophilicity: State-of-the-art and Comparison of Log P Methods on More than 96,000 Compounds, J. of Pharmaceutical Sciences, 98, 861(2009). https://doi.org/10.1002/jps.21494
  11. T. K. Kim, K. J. Jang, and S. H. Jeon, Calculation and Analysis of Hydrophobicity of the Dyes Synthesized for Unmodified Polypropylene Fibers using Molecular Descriptors, Textile Coloration and Finishing, 21(5), 21(2009). https://doi.org/10.5764/TCF.2009.21.5.021
  12. T. K. Kim, J. S. Jung, S. Son, S. H. Yoon, M. K. Kim, and J. S. Bae, Synthesis and Application of Alkyl-Substituted Disazo Yellow Dyes for Unmodified Polypropylene Fiber, Fibers and Polymers, 10(2), 148(2009). https://doi.org/10.1007/s12221-009-0148-z
  13. J. H. Park, J. S. Koh, J. S. Bae, and S. D. Kim, Synthesis and Dyeing Properties of Red Disperse Dyes Derived from Diaminopyridines, Textile Coloration and Finishing, 17, 1(2005).
  14. Tongyi Middle Special Type Xianwei Technolofy Department Limited Company, Sinotex Investment and Development Co, Ltd, An Ultra-High Molecular Weight Polyethylene Fiber Dyeing Method, CN2013-10744307 (2013).
  15. T. Kim, J. Jung, S. Yoon, M. Kim, and Y. Son, The Coloration Properties of Alkyl-Substituted Anthraquinoid Dyes for Pure Polypropylene Fiber, Textile Coloration and Finishing, 19(6), 28(2007).
  16. T. K. Kim, K. J. Jang, and S. H. Jeon, Synthesis and Application of Alkyl-Substituted Red Dyes for Unmodified Polypropylene Fibers, Fibers and Polymers, 12, 174(2011). https://doi.org/10.1007/s12221-011-0174-5
  17. A. K. Ghose, V. N. Viswanadhan, and J. J. Wendoloski, Prediction of Hydrophobic(Lipophilic) Properties of Small Organic Molecules using Fragmental Methods: An Analysis of ALOGP and CLOGP Methods, The J. of Physical Chemistry A, 102, 3762(1998). https://doi.org/10.1021/jp980230o
  18. K. R. Cousins, Computer Review of Chem Draw Ultra 12.0, J. of American Chemical Society, 133, 8388(2011). https://doi.org/10.1021/ja204075s
  19. I. V. Tetko and V. Y. Tanchunk, ALOGPS(HTTP: //WWW. VCCLAB. ORG) is a Free on-Line Program to Predict Lipophilicity and Aqueous Solubility of Chemical Compounds, Abstracts of Papers of the American Chemical Society, pp.U608-U608, 2016.
  20. X. Y. Wang and R. Salovey, Melting of Ultrahigh Molecular Weight Polyethylene, J. of Applied Polymer Science, 34, 593(1987). https://doi.org/10.1002/app.1987.070340214
  21. E. W. Lee, A Study on the Structure and Mechanical Properties of Isothermally Annealed After Elevated Heating of Drawn PP Filaments, J. of The Korean Society of Industrial Application, 5(4), 361(2002).
  22. S. H. Yoon, T. K. Kim, Y. J. Lim, and K. M. Cho, The Interpretation of Dyeing Behavior of Poly(Trimethylene Terephthalate) Fiber with a Disperse Dye, Textile Coloration and Finishing, 13(4), 249(2001).
  23. K. S. Ko, B. T. Kim, and K. H. Kang, Strength Tests of Imported NYLON 6 and its Variation After Dying, The Korean Society of Fisheries Technology, 6(1), 14(1970).
  24. E. W. Lee, A Study on the Structure and Mechanical Properties of Isothermally Annealed After Elevated Heating of PET Filaments, J. of the Korean Society of Industrial Application, 6(4), 387(2003).
  25. I. Jung, S. Lee, G. Lim, and J. Ryu, Supercritical Fluid Dyeing of Polyester Fiberwith Two Different Dispersion Dyes, Clean Technology, 17, 110(2011).
  26. D. J. Han, Disperse Dyes: A Dye Chemists Perspectives, Aatcc Review, 3(1), 17(2003).