• Title/Summary/Keyword: ordered nanoporous carbons

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A study on elemental mercury adsorption behaviors of nanoporous carbons with carbon dioxide activation

  • Bae, Kyong-Min;Park, Soo-Jin
    • Carbon letters
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    • v.15 no.4
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    • pp.295-298
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    • 2014
  • In this work, nanoporous carbons (NPCs) were prepared by the self-assembly of polymeric carbon precursors and block copolymer template in the presence of tetraethyl orthosilicate and colloidal silica. The NPCs' pore structures and total pore volumes were analyzed by reference to $N_2$/77 K adsorption isotherms. The porosity and elemental mercury adsorption of NPCs were increased by activation with carbon dioxide. It could be resulted that elemental mercury adsorption ability of NPCs depended on their specific surface area and micropore fraction.

A review: methane capture by nanoporous carbon materials for automobiles

  • Choi, Pil-Seon;Jeong, Ji-Moon;Choi, Yong-Ki;Kim, Myung-Seok;Shin, Gi-Joo;Park, Soo-Jin
    • Carbon letters
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    • v.17 no.1
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    • pp.18-28
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    • 2016
  • Global warming is considered one of the great challenges of the twenty-first century. In order to reduce the ever-increasing amount of methane (CH4) released into the atmosphere, and thus its impact on global climate change, CH4 storage technologies are attracting significant research interest. CH4 storage processes are attracting technological interest, and methane is being applied as an alternative fuel for vehicles. CH4 storage involves many technologies, among which, adsorption processes such as processes using porous adsorbents are regarded as an important green and economic technology. It is very important to develop highly efficient adsorbents to realize techno-economic systems for CH4 adsorption and storage. In this review, we summarize the nanomaterials being used for CH4 adsorption, which are divided into non-carbonaceous (e.g., zeolites, metal-organic frameworks, and porous polymers) and carbonaceous materials (e.g., activated carbons, ordered porous carbons, and activated carbon fibers), with a focus on recent research.

Soft-template Synthesis of Magnetically Separable Mesoporous Carbon (자성에 의해 분리 가능한 메조포러스 카본의 소프트 주형 합성)

  • Park, Sung Soo;Ha, Chang-Sik
    • Journal of Adhesion and Interface
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    • v.18 no.2
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    • pp.75-81
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    • 2017
  • In this study, we synthesized mesoporous carbon (Carbonized Ni-FDU-15) containing nanoporous structures and magnetic nanoparticles. Carbonized Ni-FDU-15 was synthesized via evaporation-induced self-assembly (EISA) and direct carbonization by using a triblock copolymer (F127) as a structure-directing agent, a resol precursor as a carbon-pore wall forming material, and nickel (II) nitrate as a metal ion source. The mesoporous carbon has a well-ordered two-dimensional hexagonal structure. Meanwhile, nickel (Ni) metal and nickel oxide (NiO) were produced in the magnetic nanoparticles in the pore wall. The size of the nanoparticles was about 37 nm. The surface area, pore size and pore volume of Carbonized Ni-FDU-15 were $558m^2g^{-1}$, $22.5{\AA}$ and $0.5cm^3g^{-1}$, respectively. Carbonized Ni-FDU-15 was found to move in the direction of magnetic force when magnetic force was externally applied. The magnetic nanoparticle-bearing mesoporous carbons are expected to have high applicability in a wide variety of applications such as adsorption/separation, magnetic storage media, ferrofluid, magnetic resonance imaging (MRI) and drug targeting, etc.