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http://dx.doi.org/10.17702/jai.2017.18.2.75

Soft-template Synthesis of Magnetically Separable Mesoporous Carbon  

Park, Sung Soo (Department of Polymer Science and Enhineering, Pusan National University)
Ha, Chang-Sik (Department of Polymer Science and Enhineering, Pusan National University)
Publication Information
Journal of Adhesion and Interface / v.18, no.2, 2017 , pp. 75-81 More about this Journal
Abstract
In this study, we synthesized mesoporous carbon (Carbonized Ni-FDU-15) containing nanoporous structures and magnetic nanoparticles. Carbonized Ni-FDU-15 was synthesized via evaporation-induced self-assembly (EISA) and direct carbonization by using a triblock copolymer (F127) as a structure-directing agent, a resol precursor as a carbon-pore wall forming material, and nickel (II) nitrate as a metal ion source. The mesoporous carbon has a well-ordered two-dimensional hexagonal structure. Meanwhile, nickel (Ni) metal and nickel oxide (NiO) were produced in the magnetic nanoparticles in the pore wall. The size of the nanoparticles was about 37 nm. The surface area, pore size and pore volume of Carbonized Ni-FDU-15 were $558m^2g^{-1}$, $22.5{\AA}$ and $0.5cm^3g^{-1}$, respectively. Carbonized Ni-FDU-15 was found to move in the direction of magnetic force when magnetic force was externally applied. The magnetic nanoparticle-bearing mesoporous carbons are expected to have high applicability in a wide variety of applications such as adsorption/separation, magnetic storage media, ferrofluid, magnetic resonance imaging (MRI) and drug targeting, etc.
Keywords
Soft-template synthesis; Mesoporous carbon; Magnetic nanoparticle; Ni/NiO nanoparticle;
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