• Title/Summary/Keyword: optimum mixture

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Optimum Reaction Condition of Enzymatic Hydrolysis for Production of Reducing Sugar from Enteromorpha intestinalis (창자파래로부터 환원당 생산을 위한 효소가수분해의 최적 반응조건)

  • Kim, A-Ram;Kim, Dong-Hyun;Jeong, Gwi-Taek
    • KSBB Journal
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    • v.30 no.2
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    • pp.53-57
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    • 2015
  • In this study, the production of total reducing sugar from macro green-algae Enteromorpha intestinalis by enzymatic hydrolysis was investigated. As a result of enzymatic hydrolysis using 13 kind commercial enzymes, the highest yield of 8.75% was obtained from Viscozyme L, which is multi-enzyme complex such as cellulase, arabanase, beta-glucanase, hemicellulase and xylanase. As a control, only 0.33% and 0.27% yield were obtained from 1% sulfuric acid and 0.05 M citrate buffer (pH 4.8), respectively. In the case of enzyme mixture, the mixture of $Viscozyme^{(R)}$ L and $Cellic^{(R)}$ CTec2 (1:1) was presented the highest yield of 10.67%. Finally, the 14.99% yield was obtained at 36 hr under the condition of 10% biomass and 30% enzyme mixture.

Study on the Optimization of Cationic Ring Opening Polymerization of Silicone-Based Epoxy Monomers for Holographic Photopolymers

  • Kim, Dae-Heum;Chung, Dae-Won
    • Macromolecular Research
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    • v.17 no.9
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    • pp.651-657
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    • 2009
  • This study examined the optimum compositions of binder, photo-acid generator (PAG) and sensitizer for the cationic ring opening polymerization of 1,3-bis[2-(3-{7-oxabicyclo-[4.1.0]heptyl})]-tetramethyldisiloxane in the presence of polydimethylsiloxane with four epoxide moieties as a co-monomer. When diffractive efficiency (DE) values were compared quantitatively to analyze the effect of the binder on holographic photopolymerization, DE was affected by the viscosity of the binders and miscibility with the monomer mixture. Extremely low DE values were observed when the immiscible dimethyl silicone was used as a binder. Therefore, methylphenyl silicone, which is miscible with the monomer mixture, was used as the binder for further studies. The optimal conditions were a binder viscosity between 250 to 390 cP, and contents of the binder, PAG, and sensitizer were 75-125 wt%, > 6 wt% and 0.05 wt% to the total monomer mixture, respectively.

Performance Characteristics of Propane/isobutane Mixtures in a Small Refrigeration System (프로판-이소부탄 혼합냉매를 적용한 소형 냉동시스템의 성능 특성에 관한 연구)

  • 윤원재;김용찬
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.1
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    • pp.73-82
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    • 2002
  • A small refrigeration system used in a water purifier was tested by employing propane/isobutane (R-290/R-6OOa) mixtures as an alternative refrigerant of R-12. The drop-in tests were performed by varying mass fraction of propane at 0.25, 0.5 and 0.75 with a change of both refrigerant charge amount and capillary tube length in order to find an optimum composition in aspect of performance and reliability of the system. As a result, the mixture of 50% propane-50% isobutane showed the best performance and reliability among them in a small refrigeration system. During steady state operations, both the COP and refrigeration capacity increased by 4% and 9%, respectively, as compared to the baseline R-12 system. In addition, the propane/isobutane (50/50) mixture system yielded advantages in the minimization of modification and redesigning of system components due to very similar saturation tempera- ture and pressure characteristics with R-12.

Study on the Boriding of Steel in Ferroboron and NaBF4 Powder Mixture (훼로보론과 NaBF4 에 의한 강재의 침 경화처리에 관하여)

  • 김문일;여운관
    • Journal of the Korean institute of surface engineering
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    • v.8 no.3
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    • pp.5-11
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    • 1975
  • The boronizing method using ferroborn and NaBF4 powder mixture was studied for surface hardening of medium carbon steel. This boride layer was compared with a boride layer that was formed in ferroboron and KBF4 powder mixture. The frequency factor and activation energy were discussed in this paper. The main results obtained can be summerized as follow. 1) The optimum range of NaBF4 content is 10 to 15% of weight to obtain a thick and dense boride layer. 2) The depth of the boride layer was approximately expressed by the following equation : {{{{d=100 exp (-18,000/RT) SQRT { t} }} 3) The oxidating resistance of boronized steel proved to be good at 800$^{\circ}C$ but almost unacceptable near at 900 $^{\circ}C$. 4) The NaBF4 effect was the same as that reported for KBF4.

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Parametric Study of DF-$CO_2$ Transfer Chemical Laser by the Numerical Model Simulation

  • Kim, Sung-Ho;Cho, Ung-In
    • Bulletin of the Korean Chemical Society
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    • v.11 no.6
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    • pp.527-530
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    • 1990
  • The effects of the concentration and the pressure of reactants on laser output were reported in the previous study. The present study is made of the following main parameters on laser characteristics; the initial temperature of the reaction mixture, inert gas (He) added in the reaction mixture, and the level of initiation as a function of time. As the initial temperature of reaction mixture decreases, both the output energy and the duration time increase. Especially, the output energy is linearly proportional to the inverse of the initial temperature. In order to obtain a proper lasing for a given condition, a sufficient amount of He must be added: The optimum ratio of [He] to $[D_2\;+\;F_2\;+\;CO_2]$ is found to be greater than 2. In addition, the time dependence of level of initiation (TDLI) shows no significant difference in total output energy from that of the premixed model, but only the power profile.

Determination of Mixing Ratio of Mixed Refrigerants and Performance Analysis of Natural Gas Liquefaction Processes (혼합냉매 혼합비에 따른 천연가스 액화공정 성능 비교)

  • Kim, Min Jin;Yi, Gyeong Beom;Liu, Jay
    • Korean Chemical Engineering Research
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    • v.51 no.6
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    • pp.677-684
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    • 2013
  • A mixed refrigerant cycle (MRC) has been widely used in liquefaction of natural gas because it is simple and easily operable with reasonable equipment costs. One of the important techniques in MRC is selection of a refrigerant mixture and decision of its optimum mixing ratio. In this work, it is examined whether mixture components (refrigerants) and their mixing ratio influence performance of general MRC processes. In doing this, mixture design and response surface method, which are well-known statistical techniques, are used to find optimal mixture refrigerants and their optimal mixing ratio that minimize total energy consumption of the entire liquefaction process. A MRC process using several refrigerants and various mixing ratios is simulated by Aspen HYSYS and mixture design and response surface method are implemented using Minitab. According to the results, methane ($C_1$), ethane ($C_2$), propane ($C_3$) and nitrogen ($N_2$) are selected as best mixture refrigerants and the determined mixture ratio (mole ration) can reduce total energy consumption by up to 50%.

Tensile Strength Variation of Binary Tablets Produced by Planetary Ball Milling (유성볼밀링으로 제조한 2성분 정제의 인장강도 변화)

  • Sim, Chol-Ho
    • Journal of Pharmaceutical Investigation
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    • v.38 no.1
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    • pp.1-8
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    • 2008
  • Planetary ball mill was used to decrease and control the particle size of excipients. The effects of the weight of sample and the revolution number of mill, and grinding time on the particle size of the ground sample were analyzed by response surface methodology. The optimum conditions for the milling of microcrystalline cellulose were 38.82 g of the weight of sample and 259 rpm of the revolution number of mill, and 45 minutes of grinding time. The predicted value of the particle size at the these conditions was $19.02{\mu}m$, of which the experimental value at the similar conditions was $18.68{\mu}m$. The tensile strength of tablets of single-component powders, such as microcrystalline cellulose, hydroxypropylmethyl cellulose and starch, binary mixtures and ground binary mixtures of these powder were measured at various relative densities. It was found that the logarithm of the tensile strength of the tablets was proportional to the relative density. A simple model, based upon Ryshkewitch-Duckworth equation that was originally proposed for porous materials, has been developed in order to predict the relationship between the tensile strength and relative density of ground binary tablets based on the properties of the constituent single-component powders. The validity of the model has been verified with experimental results for ground binary mixtures. It has demonstrated that this model can well predict the tensile strength of ground binary mixtures based upon the properties of single-component powders, such as true density, and the compositions. When the tensile strength of the mixture of microcrystalline cellulose hydroxypropylmethyl cellulose (90:10) and the ground mixture of them were compared, the tensile strength of the ground mixture decreased widely from 45.3 to 5.6% compared to the mixture in case the relative density of tablets was in the range of $0.7{\sim}0.9$. When the tensile strength of the mixture of microcrystalline cellulose starch (80:20) and the ground mixture of them were compared, the tensile strength of the ground mixture decreased widely from 31.0 to 11.6% compared to the mixture in case the relative density of tablets was in the range of $0.7{\sim}0.9$.

Preparation and Characterization of Silk and Mulberry/Silk Papers

  • Lee, Ki-Hoon;Kang, Gyung-Don;Oh, Han-Jin;Ki, Chang-Seok;Kim, Jong-Wook;Park, Young-Hwan
    • International Journal of Industrial Entomology and Biomaterials
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    • v.13 no.1
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    • pp.45-50
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    • 2006
  • Papers were prepared from cut cocoons and mulberry branches, which are byproducts from sericulture industry. The long filament of silk should be cut into appropriate length in order to prepare paper and this was achieved by chemical method. By a mixture of sodium hydroxide and sodium carbonate solution, the silk filaments were cut into short fibers (less than 1 mm in length). Since the short silk fibers (sSf) could not bind each other by itself, starch and poly(ethylene oxide)(PEO) were added as a bonding agent. When starch and PEO were used in a ratio of 3:7, the silk papers had optimum mechanical properties for paper. Fibers from the skin of mulberry branches (MBF) were added to sSf to enhance the mechanical properties of pure silk paper. Bleaching of MBF was performed with a mixture of hydrogen peroxide and sodium silicate. The mechanical properties were greatly enhanced and the optimum blend ratio of MBF and sSf were 7:3. The mulberry/silk paper has good absorption property against formaldehyde, and therefore, the paper could be applied as a wall paper for preventing the sick house syndrome.

Etching Reaction of $UO_2\;with\;CF_4/O_2$ Mixture Gas Plasma

  • Kim, Yongsoo;Jinyoung Min;Kikwang Bae;Myungseung Yang
    • Nuclear Engineering and Technology
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    • v.31 no.2
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    • pp.133-138
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    • 1999
  • Research on the etching reaction of UO$_2$ with CF$_4$/O$_2$gas mixture plasma is carried out. The reaction rates are investigated as a function of CF$_4$/O$_2$ ratio, plasma power, and substrate temperature. It is found that there exists an optimum CF$_4$/O$_2$ ratio around 4:1 at all temperatures up to 37$0^{\circ}C$ and surface analysis using XPS X-ray Photoelectron Spectroscopy) confirms the result. Peak rate at the optimum gas composition increases with increasing temperature. Highest rate obtained in this study leaches 1050 monolayers/min. at 37$0^{\circ}C$ under r. f. power of 150 W, which is equivalent to about 0.5${\mu}{\textrm}{m}$/min. The rate also increases with increasing r. f. power, thus, higher power and higher substrate temperature will undoubtedly raise the etching reaction rate much further. This reaction seems to be an activated process, whose activation energy will be derived in the following experiments.

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