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Growth and Characterization of ZnS Thin Films by Hot Wall Method (Hot Wall법에 의한 ZnS 박막의 제작과 특성)

  • Lee, Sang-Tae
    • Journal of Navigation and Port Research
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    • v.26 no.1
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    • pp.120-126
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    • 2002
  • ZnS thin films were prepared on glass substrate at various deposition conditions by a HW apparatus and were systematically investigated the growth characteristics, in terms of deposition edges by a double beam spectro- photometer, and structural analysis by a x-ray diffraction rates were increased with incresing the cell temperature and vapor pressure of sulfur, but were decreased with increasing substrate temperature. The optical characteristics of thin films depends on the deposition rates. The band gap energies of 3.46∼3.52eV measured at room temperature are smaller than the theoretical value of 3.54eV, indicating that impurities exist in the crystal. All ZnS thin films are oriented in the (III) principal direction of a zincblende structure. By introducing the S vapor, optical and crystalline properties have been improved.

Fabrication and Characterization of CuO Thin Film/ZnO Nanorods Heterojunction Structure for Efficient Detection of NO Gas (일산화질소 가스 검출을 위한 CuO 박막/ZnO 나노막대 이종접합 구조의 제작 및 특성 평가)

  • Yoo, Hwansu;Kim, Hyojin;Kim, Dojin
    • Korean Journal of Materials Research
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    • v.28 no.1
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    • pp.32-37
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    • 2018
  • We report on the efficient detection of NO gas by an all-oxide semiconductor p-n heterojunction diode structure comprised of n-type zinc oxide (ZnO) nanorods embedded in p-type copper oxide (CuO) thin film. The CuO thin film/ZnO nanorod heterostructure was fabricated by directly sputtering CuO thin film onto a vertically aligned ZnO nanorod array synthesized via a hydrothemal method. The transport behavior and NO gas sensing properties of the fabricated CuO thin film/ZnO nanorod heterostructure were charcterized and revealed that the oxide semiconductor heterojunction exhibited a definite rectifying diode-like behavior at various temperatures ranging from room temperature to $250^{\circ}C$. The NO gas sensing experiment indicated that the CuO thin film/ZnO nanorod heterostructure had a good sensing performance for the efficient detection of NO gas in the range of 2-14 ppm under the conditions of an applied bias of 2 V and a comparatively low operating temperature of $150^{\circ}C$. The NO gas sensing process in the CuO/ZnO p-n heterostructure is discussed in terms of the electronic band structure.

Role of Bevel Angles Influenced on the Fatigue Life of Butt-welded Joints (맞대기 이음 용접의 피로수명에 베벨 각도가 미치는 역할)

  • Park, Jihwan;Han, Changwan;Jung, Seungbin;Park, Seonghun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.2
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    • pp.141-147
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    • 2014
  • This study aims to investigate the influence of bevel angles on the fatigue life of V-groove butt-welded joints with back-plates made by SM490A steel material, generally used for excavators, because changes in the geometry, material and surface properties of welded regions affect the fatigue life of welded structures. Butt type test specimens were prepared by the $CO_2$ welding of rolled steel plates (SM50A steel) with a thickness of 13.5 mm at a welding speed of 30 cm/min and these Butt type test specimens had two different groove angles, which are $40^{\circ}$ (A type) and $30^{\circ}$ (B type). In order to investigate differences in fatigue life between two types, 4-point bending fatigue tests were conducted with a stress ratio of R=0.1 under the cyclic loading environment at a frequency of 5 Hz at room temperature. The fatigue life of A type specimens was approximately 7% higher than that of B type specimens. The stress concentration factors calculated by finite element analysis were 2.16 for A type and 2.25 for B type, whose difference was caused by the influence of the back-plates of butt-welded structures. The current results could provide important guidelines to determine the V-groove angle of butt-welded joints with a satisfactory fatigue life, although under severe operating conditions.

Photocatalytic Decomposition of Gaseous Ozone over $TiO_2$Thin Film

  • Cho, Ki-Chul;Hwang, Kyung-Chul;Yeo, Hyun-Gu;Taizo Sano;Koji Takeuchi;Sadao Matsuzawa
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E3
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    • pp.121-127
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    • 2003
  • The characteristics of heterogeneous photocatalytic decomposition were investigated at low concentration level of $O_3$on TiO$_2$for various operating parameters such as: loaded catalyst weight (0∼4 mg/$\textrm{cm}^2$), initial concentration of $O_3$(0.06∼10.0 ppm), gas flow rate (1.0 ∼ 2.5ι/min), and relative humidity (0∼80%). This study was conducted using a flow-type reactor at room temperature. Three kinds of pure TiO$_2$(P25, ST -01, and E- 23) were employed as photocatalyts. It was found that $O_3$removal ratio was identical, regardless of the loaded TiO$_2$weight in the range from 0.5 to 4.0 mg/$\textrm{cm}^2$. It was also found that higher initial ozone concentration results in greater oxidation rate of ozone and experimental data show kinetically a good agreement with Langmur-Hinshelwood kinetic model. We also observed that the removal ratio of $O_3$increases linearly with the increasing flow rate and also with the increasing relative humidity for each catalyst.

Gender Reassignment Surgery in Human Immunodeficiency Virus-Positive Patients: A Report of Two Cases

  • Kim, Seok-Kwun;Choi, Ji-An;Kim, Myung-Hoon;Kim, Min-Su;Lee, Keun-Cheol
    • Archives of Plastic Surgery
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    • v.42 no.6
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    • pp.776-782
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    • 2015
  • It is believed that surgery on human immunodeficiency virus (HIV)-positive patients is dangerous and should be avoided due to the possibility of postoperative infection of the patients or HIV occupational transmission to the medical staff. We discuss here the preparations and measures needed to conduct surgery safely on HIV-positive patients, based on our experience. We performed sex reassignment surgery on two HIV-positive patients from January 2013 to January 2015. Both of them were receiving highly active antiretroviral therapy and were asymptomatic, with a normal CD4 count ($>500cells/{\mu}L$). The HIV-RNA was undetectable within the bloodstream. All the staff wore protective clothing, glasses, and three pairs of protective gloves in the operating room because of the possibility of transmission. Prophylactic antibiotics were administered to the patients, and antiviral therapy was performed during their perioperative course. Neither of the patients had postoperative complications, and none of the medical staff experienced accidental exposure. Both patients had satisfactory surgery outcomes without complications. HIV-positive patients can undergo surgery safely without increased risk of postoperative complications or HIV transmission to the staff through the proper use of antibiotics, active antiretroviral therapy, and supplemental protective measures with post-exposure prophylaxis for the staff in case of HIV exposure.

Closed Reduction of Zygomatic Arch Fracture with Intraoperative Mobile Computed Tomography Scan (관골궁 골절의 정복 시 술중 이동식 CT의 유용성)

  • Kim, Myung-Good;Noh, Yong-Joon;Lee, Hoon-Young;Kim, Min-Ho;Lee, Sin-Chul
    • Archives of Plastic Surgery
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    • v.37 no.1
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    • pp.91-94
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    • 2010
  • Purpose: The purpose of this study is to describe the usefulness of intraoperative mobile CT scans in the reduction of zygomatic arch fracture. Method: Two patients with zygomatic arch fractures were selected who were indications of closed reduction by Gilles' approach. After the reduction was done in the operating room with zygomatic arch elevator, intraoperative CT scan was done to check the extent of reduction. Additional reduction was performed according to the obtained images from the intraoperative mobile CT scan. Examination of the preoperative CT, intraoperative CT after the reduction, and postoperative plain X-ray films were done for documentation and analysis. Results: Reduction was carried out successfully to the patients without any complications. Both patients were satisfied with the postoperative cosmetic and functional outcome. Revisional surgery was not necessary during the 6 months follow up. Conclusion: The advantage of this method is that it is easier to obtain three dimensional relationships of the fracture site. Furthermore, the operator is less exposed to radiation hazards compared to other methods that obtain intraoperative images such as the C-arm. In conclusion, intraoperative mobile CT scan can be a useful surgical aid in the reduction of zygomatic arch fractures.

Experience with Operating a Trauma Team at a Local Private University Hospital (일개 지방사립대학병원에서의 중증외상팀 운영경험)

  • Kim, Yong Hwan;Yang, Young Mo;Lee, Jang Young;Lee, Won Suk;Sung, Won Young;Bark, Koung Nam
    • Journal of Trauma and Injury
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    • v.26 no.3
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    • pp.99-103
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    • 2013
  • Purpose: This hospital has operated a trauma system of the inclusive trauma system under the sponsorship of this hospital and with financial support from the government from 2011, and it has been designated as a specialized trauma center (candidate) since November 2008. Therefore, this emergency medical center evaluated the influence of the inclusive trauma system on the course of healing and on the results for trauma patients within the region. Methods: The medical records of all patients who were registered as trauma patients from among those who visited the emergency medical center of this hospital from April 2009 to May 2012 were retrospectively reviewed. The monthly and the annual averages of important indices, such as the time in the emergency room and preventable mortalities, were calculated, and patterns of change were sought. The preventable mortality rate was calculated by using the Trauma Injury Severity Score (TRISS) for each patient. Results: The total number of patients registered from April 2009 to May 2012 was 601, and male patients accounted for a larger proportion(432 males(71.88%) vs. 169 females(28.12%)). Their average age was 46.2 years, the average Revised Trauma Score (RTS) was 5.74 points, and the average Injury Severity Score (ISS) was 26.99 points. The preventable mortality rate during the entire period, which was calculated using the TRISS, appeared lower than the preventable mortality rates reported in past studies in the Republic of Korea. Conclusion: These results for the operation of a new trauma system are limited in that they are only for a local private university hospital. However, results show greater changes and developments in and out of the hospital due to multilateral endeavors by the trauma team and the hospital. These endeavors include increased communications among the departments and development of a complementary patient registration system.

Repair of Complex Cardiac Anomaly Associated with Congenital Tracheal Stenosis -1 Case Report- (선천성 기관 협착증을 동반한 복잡 심기형의 완전 교정술 -1예 보고-)

  • Park, Jeong-Jun;Kim, Woong-Han
    • Journal of Chest Surgery
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    • v.30 no.1
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    • pp.88-91
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    • 1997
  • Congenital long-segment tracheal stenosis with complex cardiac anomaly has generally been regarded as a fatal disease This report described the successful concomitant repair of unexpected congenital tracheal stenosis and complex cardiac anomaly with the use of edrdiopulmonary bypass. The patient was a 3-month-old girl with coarctation of aorta, V D, and PDA. The presence of tracheal stenosis was not discovered until when difficulty with endotracheal intubation was encountered at operating room. Thus, we decided concomitant repair of both lesions and performed anterior pericardial tracheoplasty combined with one stage repair of coarctation of aorta, VSD, and PDA under the cardiopulmonary bypass. The patient is doing well without any signs of complication at present, 2 years and 1 month after the operation.

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Cracked-Healing and Bending Strength of Si3N4 Ceramics (Si3N4 세라믹스의 균열 치유와 굽힘 강도 특성)

  • Nam, Ki-Woo;Park, Seung-Won;Do, Jae-Youn;Ahn, Seok-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.11
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    • pp.957-962
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    • 2008
  • Crack-healing behavior of $Si_3N_4$ composite ceramics has been studied as functions of heat-treatment temperature and amount of additive $SiO_2$ colloidal. Results showed that optimum amount of additive $SiO_2$ colloidal and coating of $SiO_2$ colloidal on crack could significantly increase the bending strength. The heat-treatment temperature has a profound influence on the extent of crack healing and the degree of strength recovery. The optimum heat-treatment temperature depends on the amount of additive $SiO_2$ colloidal. Crack healing strength was far the better cracked specimen with $SiO_2$ colloidal coating on crack surface. After heat treatment at the temperature 1,273 K in air, the crack morphology almost entirely disappeared by scanning prob microscope. At optimum healing temperature 1,273 K, the bending strength with additive $SiO_2$ colloidal 0.0 wt.% without $SiO_2$ colloidal coating recovered to the value of the smooth specimens at room temperature for the investigated crack sizes $100\;{\mu}m$. But that with $SiO_2$ colloidal coating increase up to 140 %. The amount of optimum additive $SiO_2$ colloidal was 1.3 wt.% and crack healed bending strength with $SiO_2$ colloidal coating increase up to 160 % to smooth specimen of additive $SiO_2$ colloidal 0.0 wt.%. Crack closure and rebonding of the crack due to oxidation of cracked surfaces were suggested as a dominant healing mechanism operating in $Si_3N_4$ composite ceramics.

Fatigue Characteristics and Compressive Residual Stress of Shot Peened Alloy 600 Under High Temperature (쇼트피닝 가공된 Alloy 600 재료의 고온환경하에서의 잔류응력 및 피로특성)

  • Kim, Jong Cheon;Cho, Hong Seok;Cheong, Seong Kyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.3
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    • pp.333-338
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    • 2013
  • The compressive residual stress and fatigue behavior of shot peened alloy 600 under a high-temperature environment is investigated in this study. Alloy 600 is used in the main parts of nuclear power plants, and the compressive residual stress induced by the shot peening process is considered to prevent SCC (stress corrosion cracking). To obtain practical results, the fatigue characteristics and compressive residual stress are evaluated under the actual operating temperature of a domestic nuclear power plant, as well as a high-temperature environment. The experimental results show that the peening effects are valid at a high temperature lower than approximately $538^{\circ}C$, which is the threshold temperature. The fatigue life was maintained at temperatures lower than $538^{\circ}C$, and the compressive residual stress at $538^{\circ}C$ was 68.2% of that at room temperature. The present results are expected to be used to obtain basic safety and reliability data.