• 제목/요약/키워드: oil energy

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중질유 고부가화를 위한 SDA 개발 기술의 특허 정보 분석 (Patent Analysis of SDA Technology for Heavy Oil Upgrading)

  • 김용헌;이원수;김재호;전상구;나정걸;노남선;이기봉
    • 공업화학
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    • 제21권4호
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    • pp.372-376
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    • 2010
  • 세계적인 자원 확보에 대한 경쟁과 재래에너지의 한계성으로 비재래 에너지가 미래의 에너지원으로 주목받고 있다. 그중에서도, 특히 중질유 및 오일샌드를 경질화하여 부가가치를 높이는 중질유분의 고부가화 공정에 대한 수요가 증가하고 있다. 다양한 형태의 중질 탄화수소로부터 Deasphalted Oil (DAO)를 생산하는 Solvent Deasphalting (SDA) 기술이 기존 정제산업에서 사용되어져 왔고, 비재래 에너지원에서의 사용에도 주목받고 있다. 자원 확보 경쟁에 나선 일부 국가에서는 SDA 기술에 대하여 이미 활발한 연구개발 및 DAO의 상업생산을 시작하고 있다. 본 연구에서는 SDA 기술 개발을 위해 필요한 특허분석을 하였고, SDA특허기술이 출원되기 시작한 1970년대부터 최근까지의 한국, 미국, 일본, 캐나다(캐나다 특허는 1950년도 이후 문헌부터 검색), 유럽, 국제특허를 이용하여, 추출, 회수, 용매 및 기타로 세부기술을 분리한 후, 총 334건을 SDA 기술과 관련된 특허로 추출하여 분석하였다. SDA 기술의 연도별 출원동향을 살펴보면, 대략 10년을 주기로 감소하는 구간이 나타나나 전체적으로는 증가하고 있는 경향을 보이고 있으며, 미국특허가 131건(39%)으로 가장 많으며, 그 다음으로 캐나다특허 83건(25%), 유럽특허 45건(13%), 일본특허 35건(11%)으로 나타났으며, 한국특허는 6건(2%)을 출원하여 가장 낮은 출원건수를 보였다. 다른 나라에 비해 SDA 관련 기술이 취약한 한국은 에너지 자원 기술의 효율적 이용을 위해서 SDA 기술에 대한 연구 개발 및 정부지원이 반드시 필요할 것으로 생각된다.

열펌프를 이용한 온돌 난방 시스템 - 열펌프와 석유보일러의 소요에너지 비교 - (Ondol Heating System Using Heat Pump - Comparison of Energy Consumption between the Heat Pump and the Oil Boiler -)

  • 김현철;송현갑
    • Journal of Biosystems Engineering
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    • 제24권4호
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    • pp.351-358
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    • 1999
  • In these days, we are faced to a couple of difficult problems, the one is the unstable price of the energy due to the shortage of fossil fuel resources and the other is the serious environmental pollution from the excessive consumption of fossil fuel. In order to save the thermal energy for the house heating, in this study the heat pump using the natural thermal energy resources was provided for Ondol heating and the thermal energy consumption of the heat was compared to that of oil boiler. The results could be summarized as follows: 1. In the Ondol room the temperature difference between the Ondol surface and room air was about 5∼$10^{\circ}C$ in accordance with the ambient temperature. 2. The Ondol room heating efficiency of the heat pump with compressor of 2PS was the highest at the water flow rate of 200 l/h. 3. The energy saving rate of the heat pump to the oil boiler for heating the Ondol system was 19.3%. 4. The Ondol heating cost of the heat pump was less 20.6% than that of oil boiler when oil price was 478 won/l.

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Selection of plant oil as a supplemental energy source by monitoring rumen profiles and its dietary application in Thai crossbred beef cattle

  • Matsuba, Keiji;Padlom, Apirada;Khongpradit, Anchalee;Boonsaen, Phoompong;Thirawong, Prayad;Sawanon, Suriya;Suzuki, Yutaka;Koike, Satoshi;Kobayashi, Yasuo
    • Asian-Australasian Journal of Animal Sciences
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    • 제32권10호
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    • pp.1511-1520
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    • 2019
  • Objective: The present study was conducted to select a plant oil without inhibitory effects on rumen fermentation and microbes, and to determine the optimal supplementation level of the selected oil in a series of in vitro studies for dietary application. Then, the selected oil was evaluated in a feeding study using Thai crossbred beef cattle by monitoring growth, carcass, blood and rumen characteristics. Methods: Rumen fluid was incubated with substrates containing one of three different types of plant oil (coconut oil, palm oil, and soybean oil) widely available in Thailand. The effects of each oil on rumen fermentation and microbes were monitored and the oil without a negative influence on rumen parameters was selected. Then, the dose-response of rumen parameters to various levels of the selected palm oil was monitored to determine a suitable supplementation level. Finally, an 8-month feeding experiment with the diet supplemented with palm oil was carried out using 12 Thai crossbred beef cattle to monitor growth, carcass, rumen and blood profiles. Results: Batch culture studies revealed that coconut and soybean oils inhibited the most potent rumen cellulolytic bacterium Fibrobacter succinogenes, while palm oil had no such negative effect on this and on rumen fermentation products at 5% or higher supplementation level. Cattle fed the diet supplemented with 2.5% palm oil showed improved feed conversion ratio (FCR) without any adverse effects on rumen fermentation. Palm oil-supplemented diet increased blood cholesterol levels, suggesting a higher energy status of the experimental cattle. Conclusion: Palm oil had no negative effects on rumen fermentation and microbes when supplemented at levels up to 5% in vitro. Thai crossbred cattle fed the palm oil-supplemented diet showed improved FCR without apparent changes of rumen and carcass characteristics, but with elevated blood cholesterol levels. Therefore, palm oil can be used as a beneficial energy source.

마이크로웨이브와 열전매체유를 이용한 슬러지 건조방법 (Sludge Drying Method Using Microwave Drying Device and Heat Transfer Medium Oil)

  • 김용렬;손민일
    • 한국응용과학기술학회지
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    • 제28권3호
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    • pp.367-373
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    • 2011
  • This research is a basic researching process for producing solid fuel that mixing paper sludge and Heat Transfer Medium Oil. Under the presence of Heat Transfer Medium Oil, paper sludge is heated and dried with home appliance microwave for comparing drying efficiency and energy efficiency of different types of drying method. As a result, Heat Transfer Medium Oil and paper mixing case of drying method, OMD, is the most efficient way to shorten the time for evaporating moisture in the paper sludge. In addition, heat transfer effect and density is increased with adding Heat Transfer Medium Oil by microwave. Future more, OMD's energy cost for evaporating whole moisture is 78% cheaper than MD. Also, OMD process shows the best energy efficiency with comparing other process. Evaporation rate of paper sludge evaporation process with microwave is 11.66% increased by adding Heat Transfer Medium Oil 150g. Preheating Heat Transfer Medium Oil or improving different ways injecting Heat Transfer Medium Oil is a good way to increase a rate of initiative moisture evaporation process.

대용량 보일러의 냉간기동용 액체 연료에 대한 연소 반응성 평가 (Combustion Reactivity Assessments of Oils Used for the Cold Start-Up Operation of Large Scale Boiler)

  • 이장호;박호영
    • 한국수소및신에너지학회논문집
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    • 제33권1호
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    • pp.77-84
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    • 2022
  • The experimental work has been carried out for the study of pyrolysis of oil samples used in industrial and utility boilers in Korea. For five oil samples, the characteristics of pyrolysis have been investigated with a thermogravimetric analyzer (TGA), and their kinetic parameters were obtained and compared each other. The rate order of pyrolysis rate for five oils were as follows: by-product fuel oil, pyrolysis oil, diesel, a heavy oil and refined oil. The pyrolysis of refined oil has been successfully described by the three step, first order reaction model while the single step reaction model has been used for other oils. For the reaction temperature over 550 K, the reactivity of refined oil was very poor compared with other oils.

A Complete, Reductive Depolymerization of Concentrated Sulfuric Acid Hydrolysis Lignin into a High Calorific Bio-oil using Supercritical Ethanol

  • Riaz, Asim;Kim, Jaehoon
    • KEPCO Journal on Electric Power and Energy
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    • 제2권3호
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    • pp.447-452
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    • 2016
  • It is imperative to develop an effective pathway to depolymerize lignin into liquid fuel that can be used as a bioheavy oil. Lignin can be converted into liquid products either by a solvent-free thermal cracking in the absence air, or thermo-chemical degradation in the presence of suitable solvents and chemicals. Here we show that the solvent-assisted liquefaction has produced promising results in the presence of metal-based catalysts. The supercritical ethanol is an efficient liquefaction solvent, which not only provides better solubility to lignin, but also scavenges the intermediate species. The concentrated sulfuric acid hydrolysis lignin (CSAHL) was completely liquefied in the presence of solid catalysts (Ni, Pd and Ru) with no char formation. The effective deoxy-liquefaction nature associated with scEtOH with aid hydrodeoxygenation catalysts, resulted in significant reduction in oxygen-to-carbon (O/C) molar ratio up to 61%. The decrease in oxygen content and increase in carbon and hydrogen contents increased the calorific value bio-oil, with higher heating value (HHV) of $34.6MJ{\cdot}Kg^{-1}$. The overall process is energetically efficient with 129.8% energy recovery (ER) and 70.8% energy efficiency (EE). The GC-TOF/MS analysis of bio-oil shows that the bio-oil mainly consists of monomeric species such as phenols, esters, furans, alcohols, and traces of aliphatic hydrocarbons. The bio-oil produced has better flow properties, low molecular weight, and high aromaticity.

스크류 프레스의 대두유(大豆油) 착유(搾油) 성능(性能)과 착유유(搾油油)의 연료(燃料) 성질(性質) (Performance of a Screw Press to Extract Soybean Oil and Quality of the Oil as a Fuel)

  • 서상룡;에프 디 해리스
    • Journal of Biosystems Engineering
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    • 제10권2호
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    • pp.47-54
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    • 1985
  • Performance of a screw press was investigated experimentally with soybeans of various temperatures in order to find out a proper temperature of soybean to extract the oil by the mechanical method. Crude oil extracted by the screw press was chemically analyzed to determine a level of processing the oil for the oil to be used as a fuel for a compression ignition engine. The crude oil was degummed and dried by a plant type laboratory experimental setup to decide whether the processes are effective to improve quality of the oil as a fuel. The degummed oil and the degummed and dried oil were also chemically analyzed and were compared with the crude oil and the commercially degummed and dried soybean oil. The results are as follows: 1. In extraction of soybean oil by a screw press, heating soybeans is effective to increase oil production and to decrease energy consumption of the press. A proper temperature of soybean to extract the oil by the press was determined as about $50^{\circ}C$. 2. Soybean oil production and electric energy consumption of the press are about 83 ml and 58 Wh per 1 kg of soybeans heated to about $50^{\circ}C$, respectively. 3. The quality of crude oil produced by the press is similar to that of the commercially degummed and dried oil. The crude oil does not need to be degummed or dried for use as an engine fuel.

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나노다이아몬드가 분산된 엔진오일의 마찰공학 특성 (Tribology Properties of Nanodiamond Dispersed Engine Oil)

  • 전수형;엄영랑;이창규
    • 한국분말재료학회지
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    • 제18권5호
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    • pp.417-422
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    • 2011
  • Hydrophobic nanodiamond (ND) were dispersed in engine oil (Helix Oil, Shell co.) as an additives to improve tribology properties. In this study, nanodiamond prepared by an explosive method was used. Tribology properties of both pure Helix oil and engine oil containing ND additive were evaluated. The rotating disks were made of Gray Cast Iron (240 Hv) and SKD11 (710 Hv). Surface topographies of the disks' wear tracks and friction coefficient were compared. The results show that nanodiamond-dispersed lubricants are capable of reducing these metals' wear loss. The friction coefficient is strongly affected to the hardness of wear track.

Simulation of Gravity Feed Oil for Aeroplane

  • Lu, Yaguo;Huang, Shengqin;Liu, Zhenxia
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2008년 영문 학술대회
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    • pp.732-736
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    • 2008
  • The traditional method to calculate the gravity feed is to assume that only one tank in fuel system supplies the needed fuel to the engine, and then calculated for the single branch. Actually, all fuel tanks compete for supplying oil. Our method takes into consideration all fuel tanks and therefore, we believe, our method is intrinsically superior to traditional methods and is closer to understanding the real seriousness of the oil supply situation. Firstly, the thesis gives the mathematical model for fuel flow pipe, pump, check valve and the simulation model for fuel tank. On the basis of flow network theory and time difference method, we established a new calculation method for gravity feed oil of aeroplane fuel system, secondly. This model can solve the multiple-branch and transient process simulation of gravity feed oil. Finally, we give a numerical example for a certain type of aircraft, achieved the variations of oil level and flow mass per second of each oil tanks. In addition, we also obtained the variations of the oil pressure of the engine inlet, and predicted the maximum time that the aeroplane could fly safely under gravity feed. These variations show that our proposed method of calculations is satisfactory.

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국내 에너지자원 자급률 향상을 위한 기술개발 전략 (Strategies of Technology Development for Improvement of National Energy Resources Supply)

  • 임종세
    • 에너지공학
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    • 제19권2호
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    • pp.57-61
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    • 2010
  • 국내 에너지자원 자급률을 높이기 위해서는 적극적인 해외유전개발투자를 통한 생산 유 가스전 매입, M&A, 기존 생산광구 증산 등을 추진해야할 것이다. 이를 위해서는 생산 유 가스전 평가, 설계, 운영 등과 관련된 핵심 전략 기술에 대한 확보가 필수적이라고 할 수 있다. 향후 지속적인 연구개발 지원을 통한 생산광구평가와 생산 최적 설계.운영 기술 축적으로 해외 매입 가능한 유 가스전의 증가와 기존 유 가스전의 생산량 증대, 효율적인 광구 운영을 통한 석유 가스 자주개발률 제고를 기대할 수 있을 것이다.