Transactions of the Korean hydrogen and new energy society (한국수소및신에너지학회논문집)

The Korean Hydrogen and New Energy Society (한국수소및신에너지학회)
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Combustion Reactivity Assessments of Oils Used for the Cold Start-Up Operation of Large Scale Boiler

대용량 보일러의 냉간기동용 액체 연료에 대한 연소 반응성 평가

  • Received : 2022.01.25
  • Accepted : 2022.02.18
  • Published : 2022.02.28
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Abstract

The experimental work has been carried out for the study of pyrolysis of oil samples used in industrial and utility boilers in Korea. For five oil samples, the characteristics of pyrolysis have been investigated with a thermogravimetric analyzer (TGA), and their kinetic parameters were obtained and compared each other. The rate order of pyrolysis rate for five oils were as follows: by-product fuel oil, pyrolysis oil, diesel, a heavy oil and refined oil. The pyrolysis of refined oil has been successfully described by the three step, first order reaction model while the single step reaction model has been used for other oils. For the reaction temperature over 550 K, the reactivity of refined oil was very poor compared with other oils.

Keywords

Acknowledgement

본 연구는 (주)한국중부발전의 지원을 받아 수행한 기술지원(2021-M-16-1)의 일환으로 수행되었다

References

  1. K. B. Lee, M. C. Kim, and H. K. Park, "A study on the application of marine emulsion fuel for tier 3 regulation", KSEE, Vol. 34, No. 10, 2012, pp. 671-667, doi: https://doi.org/10.4491/KSEE.2012.34.10.671.
  2. J. K. Cho, S. J. Park, and S. H. Song, "A effects of natural gas-diesel/hi-sene dual fuel operation on performance of a heavy-duty diesel engine for power generation", Journal of Energy Engineering, Vol. 25, No.1, 2016, pp. 122-130, doi: https://doi.org/10.5855/ENERGY.2015.25.1.122.
  3. K. R. Kwon and K. H. Jeong, "A study on the usefulness of energy-added light oil and blend oil in domestic oil boiler", KSPSE, 2002, pp. 188-196, Retrieved from http://oak.jejunu.ac.kr/bitstream/2020.oak/2975/2/%EA%B0%80%EC%A0%95%EC%9A%A9%EB%B3%B4%EC%9D%BC%EB%9F%AC%EC%97%90%EC%84%9C%20%EC%B4%88%EC%9D%8C%ED%8C%8C%EC%97%90%EB%84%88%EC%A7%80%EB%A5%BC%20%EB%B6%80%EA%B0%80%ED%95%9C%20%EA%B2%BD%EC%9C%A0%20%EB%B0%8F%20%ED%98%BC%ED%95%A9%EC%97%B0%EB%A3%8C%EC%9D%98%20%EC%9C%A0%EC%9A%A9%EC%84%B1%EC%97%90%20%EA%B4%80%ED%95%9C%20%EC%97%B0%EA%B5%AC.pdf.
  4. J. J. Seo, W. K. Wang, and S. A. Kim, "An experimental study on characteristics of exhaust emissions with fuel properties changes in a diesel engine for small-sized fishing vessel", KSFOT, Vol. 46, No. 4, 2010, pp. 487-494, doi: https://doi.org/10.3796/KSFT.2010.46.4.487.
  5. Sung Kwang Industrial Co.,"Heavy oil combustion technology", 2010, pp. 13.
  6. H. K. Song and J. G. Kim, "Estimation of the economic coal feeding temperature at the time of fuel change to russian bituminous coal during starting up for CFB power plant", Plant Journal, Vol. 11, No.3, 2015, pp. 46-52.
  7. Taean thermal power complex division, "Practical business affairs for #1-4 thermal power plant", Korea Western Power Company, 2012, pp. 3-8.
  8. I. P. Fernandez, J. C. L. Garcia, and D. P. Gutierrez, "Improvements in light oil combustion by adding small quantities of alcohol. Possible application in cold starts up, in thermal power stations", Fuel Process Technology, Vol. 60, No. 1, 1999, pp. 15-27, doi: https://doi.org/10.1016/S0378-3820(99)00020-X.
  9. Hanwha Total, "Fuel oil", Retrieved from https://www.hanwha-total.com/product/product_energy?depth2Cd=CCAA.
  10. H. H. Kim, Y. H. Park, K. Han. J. H. Jang, H. Y. Park, H. Y. Han, K. Kim, H. H. Park, S. B. Jang, and J. Y. Seo, "Combustion and emission characteristic of a reprocessed used lubricanting oil as a renewable fuel for boiler cold start-up operation", Energy, Vol. 222, 2021, pp. 119784, doi: https://doi.org/10.1016/j.energy.2021.119784.
  11. I. H. Choe, "High heating and clean energy(Hi-sene) 'Samsung total'", KOREAN POULTRY JOURNAL, Vol. 46, No. 9, 2014, pp. 120-123, Retrieved from https://www.koreascience.or.kr/article/JAKO201443358900733.pdf.
  12. Korea Association of Refined Oil Industries, "Refined oil", Retrieved from http://karoi.or.kr.
  13. Korea Lubricating Oil Industries Association, "State of recovery and refining of waste lubricating oils", KLOIA, Retrieved from http://www.kloia.or.kr/trend/trend_sub04_1.php.
  14. J. Doe, T. Lim, J. Lee and H. Kang, "Study on characteristics of change of physical/chemical property of refined fuel oil (reduced-pressure) by mixing with by-product fuel oil(No. 2)", Journal of Oil & Applied Science, Vol. 35, No. 4, 2018, pp. 1349-1358, doi: https://doi.org/10.12925/jkocs.2018.35.4.1349.
  15. D. S. Lee, G. S. Lee, S. O. Kim, S. C. Oh, S. R. Kim and U. T. Kwon, "The study for manufacturing technology of industrial fuel from mixed waste plastics", KSNRE, 2005, pp. 403-413.
  16. C. Phae, Y. Kim, and C. Jo, "Assessment of practical use of recycling oil from the pyrolysis of mixed waste plastics", Journal of energy engineering, Vol. 14, No.2, 2005, pp. 159-166.
  17. T. Eom, "Improvement of process and efficiency of waste-plastic emulsion process", Korean society for environmental technology, Vol. 13, No. 4, 2012, pp. 371-378. Retrieved from https://www.dbpia.co.kr/Journal/articleDetail?nodeId=NODE10837619.
  18. P. Jeeban, D. W. Lim, J. S. Kim, and C. Oh, "A study on the fuel feasibility of pyrolytic oil from waste plastics", The Korean society for new and renewable energy, 2014, pp. 140. Retrieved from https://www.dbpia.co.kr/Journal/articleDetail?nodeId=NODE06204857.
  19. K. T. Lee, "Power companies who accelerate the recycling industry", Ajudaily, 2021, Retrieved from https://www.ajunews.com/view/20210218134006965#PL2.
  20. J. K. Park, S. Park, M. Kim, C. Ryu, S. H. Baek, Y. J. Kim, H. H. Kim, and H. Y. Park, "CFD analysis of combustion characteristics for fuel switching to bioliquid in a oil-fired power plant", Fuel, Vol. 159, 2015, pp. 324-333, doi: https://doi.org/10.1016/j.fuel.2015.06.079.
  21. S. K. Kim, "Controversy over defective refined oil ②", New daily bussiness, 2014, Retrieved from https://biz.newdaily.co.kr/svc/article_print.html?no=2014051110003.
  22. S. Badzioch and P. G. W. Hawksley, "Kinetics of thermal decomposition of pulverised coal particles", Ind. Eng. Chem. Proc. Des. Dev., Vol. 9, No. 4, 1970, pp. 521-530, doi: https://doi.org/10.1021/i260036a005.
  23. H. Y. Park, K. Han, H. H. Kim, S. B. Park, J. H. Jang, G. S. Yu, and J. H. Ko, "Comparisons of combustion characteristics between bioliquid and heavy fuel oil combustion in a 0.7 MWth pilot furnace and a 75 MWe utility boiler", Energy, Vol. 192, 2020, pp. 116557, doi: https://doi.org/10.1016/j.energy.2019.116557.