• 한국연소학회:학술대회논문집
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• 2005.10a
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• pp.141-147
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• 2005

LNG combustion characteristics of oxygen carrier particles were investigated in a batch type bubbling fluidized bed reactor. Three particles, NiO/bentonite, $NiO/NiAl_2O_4$, $CO_xO_y/CoAl_2O_4$, were used as oxygen carrier particles and LNG and air were used as reactants for reduction and oxidation, respectively. In the reducer, high gas conversion and high $CO_2$ selectivity were achieved for all three particles. In the oxidizer, NOx was not detected. The results of exhaust gas analysis showed that inherent $CO_2$ separation and NOx-free combustion are possible in the LNG fueled chemical-looping combustion system with NiO/bentonite, $NiO/NiAl_2O_4$ and $Ca_xO_y/CoAl_2O_4$ particles.

• Bulletin of the Korean Chemical Society
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• v.21 no.12
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• pp.1233-1238
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• 2000

$Mo/{\gamma}-Al_2O_3catalysts$ modified with Fe, Co, and Ni were prepared by impregnation method and catalytic activity for water gas shift reaction was examined. The optimum amount of Mo loaded for the reaction was 10 wt% $MoO_3$ to ${\gamma}-Al_2O_3.$ The catalytic activity of $MoO_3/{\gamma}-Al_2O_3was$ increased by modifying with Fe, Co, and Ni in the order of Co${\thickapprox}$ Ni > Fe. The optimum amounts of Co and Ni added were 3 wt% based on CoO and NiO to 10 wt% $MoO_3/{\gamma}-Al_2O_3$, restectively. The TPR (temperature-programmed reduction) analysis revealed that the addition of Co and Ni enganced the reducibility of the catalysts. The results of both catalytic activity and TPR experiments strongly suggest that the redox property of the catalyst is an important factor in water gas shift reaction on the sulfided Mo catalysts, which could be an evidence of oxy-sulfide redox mechanism.

• Korean Journal of Materials Research
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• v.18 no.12
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• pp.678-682
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• 2008

This study investigates $Bi_2O_3$-$B_2O_3$-BaO-ZnO glass with variations of the $Co_3O_4$ content (0.25, 0.5, 1, and 2 wt%) and the interaction between transparent dielectric and Ag electrodes heat-treated at $500-560^{\circ}C$ for 30 min. The glass transition temperature, softening temperature and thermal expansion coefficient were $432^{\circ}C$, $460^{\circ}C$ and $81.4{\times}10^{-7}/^{\circ}C$, respectively. The transmittance of 0.25 wt% $Co_3O_4$ to which dielectric was added was highest and was decreased due to coloration with the addition of more than 0.25 wt%. However, without $Co_3O_4$, the transmittance of the transparent layer was decreased due to the formation of $Ba_5Bi_3$; however, the occurrence of the crystal phase decreased as a result of the addition of $Co_3O_4$. The amount of $Co^{2+}$ ions increased as the $Co_3O_4$ increased. With a maximum of $Co^{3+}$ ions, the highest transmittance was observed.

• Journal of Korean Ophthalmic Optics Society
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• v.3 no.1
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• pp.223-228
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• 1998

Glass films of $SiO_2-TiO_2-M_xO_y$ (M = Co, Cr or Cu) have been prepared on soda-lime-silica slide glasses by the chemical solution method using a spin-coating technique. Commercially available tetraethyl orthosilicate, titanium trichloride, and cobalt-, chromium- and copper-nitrates were used as starting materials. No crystalline segregations of $Co_3O_4$, $Cr_2O_3$ and CuO were observed by X-ray diffraction ${\theta}-2{\theta}$ scans. From the optical transmission analysis, cobalt existed as $ Co^{2+}$ in tetrahedral coordination, chromium as $Cr^{6+}$ in tetrahedral symmetry and copper as $Cu^{2+}$ in octahedral coordination. Films with a crack-free and no texture exhibited homogeneous interfaces between the films and the substrates along the cross-section.

• Korean Journal of Materials Research
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• v.13 no.11
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• pp.737-741
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• 2003

Polycrystalline $Ti_{l-x}$ $Co_{x}$ $O_2$thin films on $SiO_2$ (200 nm)/Si (100) substrates were prepared using liquid-delivery metalorganic chemical vapor deposition. Microstructures and ferromagnetic properties were investigated as a function of doped Co concentration. Ferromagnetic behaviors of polycrystalline films were observed at room temperature, and the magnetic and structural properties strongly depended on the Co distribution, which varied widely with doped Co concentration. The annealed $Ti_{l-x}$ $Co_{x}$ $O_2$thin films with $x\leq$0.05 showed a homogeneous structure without any clusters, and pure ferromagnetic properties of thin films are only attributed to the X$l-x_{l-x}$ $Co_{x}$X$O_2$phases. On the other hand, in case of thin films above x = 0.05, Co-rich clusters formed in a homogeneous $Ti_{l-x}$ $Co_{x}$ $O_2$phase, and the overall ferromagnetic (FM) properties depended on both FMTCO and FMCo. Co-rich clusters with about 10-150 nm size decreased the value of Mr (the remanent magnetization) and increased the saturation magnetic field.

• Journal of Korean Ophthalmic Optics Society
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• v.5 no.1
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• pp.49-53
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• 2000

Sodium borate silicate glass of composition $10Na_2O-39B_2O_3-50SiO_2-CoO$ and $20Na_2O-14B_2O_3-65SiO_2-CoO$ were prepared by melting oxide mixtures in alumina crucible at $1210^{\circ}C$ in an electric furance in air for 2h, and then quenching in air. The dielectric behavior of the quenched glasses are the subject of the present work. Properties such as dielectric constant and resistivity as a function frequency and temperature are reported. From the dielectric spectra, the glass phase transition temperature has been found to decrease at a rate $Na_2O$ 20 mol% and the dielectric constants increase with increasing $Na_2O$ content. The frequency dependent resistivity response of glass exhibits a non-Debye type relaxation.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.24 no.5
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• pp.183-189
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• 2014

This study was conducted to study the influence of Co and Fe on the color of glaze and diopside crystals in the diopside crystal glaze empirically produced and used by ceramic artists, in case of adding $Co_3O_4$ and $Fe_2O_3$. As a result, the color of glaze was blue when $Co_3O_4$ was added to the diopside crystal glaze and the diopside crystals appeared pastel violet with Co included. When $Fe_2O_3$ was added to the diopside crystal glaze, the color of glaze appeared brown and the color of diopside crystals was goldenrod with Fe included. The crystals precipitated on the surface of diopside consisted of diopside crystals and diopside precursors. With longer retention time, the amount of diopside precursors decreased and the amount of diopside crystals increased. Also, Co was more easily included by the diopside crystals than Fe was and crystallizability of dispside was improved in case of including Co. Including Fe lowered peak intensity of properties and partially dissolved the diopside crystals.

• Applied Chemistry for Engineering
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• v.29 no.6
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• pp.657-662
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• 2018

In this study, the effect of $Pt/TiO_2$ catalysts on the CO oxidation reaction at room temperature was investigated using various $TiO_2$ supports with different physical properties to compare and evaluate $Pt/TiO_2$ catalysts. Physicochemical properties of the catalyst were alanyzed using XPS, CO-chemisorption, BET, and CO-TPD. As a result, when the active particle diameter was smaller, while the metal dispersion and surface area were larger, the CO room temperature oxidation reaction was better. These physical properties increased the number of active sites, causing the target material to increase the adsorption amount of CO. In addition, when the $O_2$-consumption increased, the CO-room temperature oxidation reaction activity increased due to the excellent oxygen-transferring ability.

• Particle and aerosol research
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• v.13 no.1
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• pp.33-40
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• 2017

Cobalt-iron oxides have emerged as alternative electrode materials for supercapacitors because they have advantages of low cost, natural abundance, and environmental friendliness. Graphene loaded with cobalt ferrite ($CoFe_2O_4$) nanoparticles can exhibit enhanced specific capacitance. In this study, we present three-dimensional (3D) crumpled graphene (CGR) decorated with $CoFe_2O_4$ nanoparticles. The $CoFe_2O_4$-graphene composites were synthesized from a colloidal mixture of GO, iron (III) chloride hexahydrate ($FeCl_3{\cdot}6H_2O$) and cobalt chloride hexahydrate ($CoCl_2{\cdot}6H_2O$) respectively, via one step aerosol spray pyrolysis. Size of $CoFe_2O_4$ nanoparticles was ranged from 5 nm to 10 nm when loaded onto 500 nm CGR. The electrochemical performance of the $CoFe_2O_4$-graphene composites was examined. The $CoFe_2O_4$-graphene composite electrode showed the specific capacitance of $253F\;g^{-1}$.

• Horticultural Science & Technology
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• v.33 no.5
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• pp.705-711
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• 2015

This study was conducted to maintain the postharvest shelf-life of summer strawberry cultivars 'Goha' and 'Flamengo' through $CO_2$ (90%) and $ClO_2$ gas ($5{\mu}L{\cdot}L^{-1}$) pre-treatment. The respiration rate of 'Goha' and 'Flamengo' treated with $CO_2$ and $CO_2$ + $ClO_2$ was the lowest during storage. The weight loss with $CO_2$ + $ClO_2$ treatment was about 1% lower than the control group and 'Goha' was the lowest during storage. The pre-treatments effect on soluble solids contents was minimized. The firmness with $CO_2$ and $CO_2$ + $ClO_2$ treatments was only about 30% higher than $ClO_2$ and control. The firmness of 'Goha' was about 2.15N and 'Flamengo' was 2.37N, 15 days after storage. Decayed fruit was shown from after 6 days after storage in control. Control group lost quality 10 days after storage due to decayed fruit rate 20% of 'Goha' and 'Flamengo'. $CO_2$ and $CO_2$ + $ClO_2$ treatments showed the lowest decay rate during storage. Especially, 'Goha' showed around 5% decay fruit rate 10 days after storage. As a result, $CO_2$ + $ClO_2$ pre-treatment is recommended to extend the shelf-life of the summer strawberries.