• 제목/요약/키워드: non-peroxide

검색결과 214건 처리시간 0.022초

Enhanced Biodegradation of Total Petroleum Hydrocarbons (TPHs) in Contaminated Soil using Biocatalyst

  • Owen, Jeffrey S.;Pyo, Sunyeon;Kang, Guyoung
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제20권5호
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    • pp.47-51
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    • 2015
  • Biocatalytic degradation of total petroleum hydrocarbons (TPHs) in contaminated soil by hemoglobin and hydrogen peroxide is an effective soil remediation method. This study used a laboratory soil reactor experiment to evaluate the effectiveness of a nonspecific biocatalytic reaction with hemoglobin and H2O2 for treating TPH-contaminated soil. We also quantified changes in the soil microbial community using real-time PCR analysis during the experimental treatment. The results show that the measured rate constant for the reaction with added hemoglobin was 0.051/day, about 3.5 times higher than the constant for the reaction with only H2O2 (0.014/day). After four weeks of treatment, 76% of the initial soil TPH concentration was removed with hemoglobin and hydrogen peroxide treatment. The removal of initial soil TPH concentration was 26% when only hydrogen peroxide was used. The soil microbial community, based on 16S rRNA gene copy number, was higher (7.1 × 106 copy number/g of bacteria, and 7.4 × 105 copy number/g of Archaea, respectively) in the hemoglobin catalyzed treatment. Our results show that TPH treatment in contaminated soil using hemoglobin catalyzed oxidation led to the enhanced removal effectiveness and was non-toxic to the native soil microbial community in the initial soil.

유사-펜톤 반응과 계면활성제에 의한 해양퇴적물의 PCBs 정화 (Reduction of PCBs in Contaminated Marine Sediments by Using Fenton-like Reaction with Surfactants)

  • 최진영;김경련
    • 대한환경공학회지
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    • 제37권6호
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    • pp.340-348
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    • 2015
  • 본 연구에서는 해양퇴적물 내에 자연적으로 존재하는 철 성분과 과산화수소수를 이용한 유사-펜톤 공정에서 퇴적물의 입자크기 별 분율 내의 PCBs제거효율을 파악하고 여러 가지 계면활성제(Triton X-100, Tween 60, Tween 80)의 동시 사용에 따른 효율을 실험하였다. 퇴적물 시료를 1%와 15%의 과산화수소수와 Triton X-100, Tween 60, Tween 80을 이용하여 1시간 동안 처리 시 tPCBs제거효율은 24.1~46.7%로 나타났다. 퇴적물의 입자 크기, 오염형태에 따라 제거 효율의 차이는 있었으나, 과산화수소수와 계면활성제를 동시에 사용하여 처리한 퇴적물의 tPCBs 농도는 수저준설토사 유효활용 기준을 충족하였다. 또한 적절한 계면활성제를 유사-펜톤 반응에 첨가제로 사용시 낮은 산화제 농도 조건에서도 보다 높은 산화제 농도 조건에서의 제거효율과 유사하게 나타났다. 그러므로 유사-펜톤 반응과 계면활성제에 의한 처리에서 해양오염퇴적물의 미세입자에 함유된 PCBs를 효율적으로 정화하는 것이 가능한 것으로 확인되었다.

과산화수소/케로신을 사용하는 액체로켓엔진의 촉매 점화기 설계에 관한 연구 (A Study on Design of a Catalytic Ignitor for Liquid Rocket Engine using Hydrogen Peroxide and Kerosene)

  • 채병찬;이양석;전준수;고영성
    • 한국추진공학회지
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    • 제15권6호
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    • pp.56-62
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    • 2011
  • 본 연구에서는 과산화수소와 케로신을 사용하는 소형 이원추진제 액체로켓엔진의 점화원으로서, 과산화수소의 촉매 반응에 의한 고온의 분해 가스와 케로신의 자연 발화를 이용하는 촉매형 점화기에 대한 연구를 수행하였다. 먼저 점화기를 설계하기 위해 열역학적 상용코드프로그램인 CEA를 사용하여 점화기 유량 및 혼합비를 선정하고 촉매형 점화기를 설계/제작하였으며, 점화 성공 및 지연 등을 판단하기 위한 가시화창과 분해 가스의 온도 분포를 파악하기 위한 열전대 장착이 가능한 연소실을 설계제작하였다. 분해 가스 유속을 결정하는 고정링(fixed ring)의 출구 면적 변화와 혼합비 변화에 따른 점화 성능 시험을 수행하였다. 결과적으로 쵸킹 면적보다 큰 출구 면적에서와 혼합비 6~8 사이에서 안정적인 점화 성능을 보임을 확인하였다.

오미자칠해목 추출물의 과산화수소로 유발된 PC12뇌세포 사멸과 스코폴라민으로 유발된 렛드 동물모델에 대한 개선 효과 (Ameliorative Effect of Schisandra chinensis and Ribes fasciculatum Extracts on Hydrogen Peroxide-Induced Neuronal Cell Death in Neuroblastic PC12 Cells and the Scopolamine-Induced Cognitive Impairment in a Rat Model)

  • 박은국;한경훈;허재혁;김남기;배문형;서영하;용윤중;정선용;최춘환
    • 한국식품영양학회지
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    • 제33권3호
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    • pp.347-355
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    • 2020
  • Cognitive impairment is considered to be key research topics in the field of neurodegenerative diseases and in understanding of learning and memory. In the present study, we investigated neuroprotective effects of Schisandra chinensis (SC) and Ribes fasciculatum (RF) extracts in hydrogen peroxide-induced neuronal cell death in vitro and scopolamine-induced cognitive impairment in Sprague Dawley® (SD) rat in vivo. Apoptotic cell death in neuroblastic PC12 cell line was induced by hydrogen peroxide for 1 hour at 100 μM. However, mixture of SC and RF treatment prevented peroxide induced PC12 cell death with no neurotoxic effects. For in vivo experiment, the effect of SC and RF extracts on scopolamine-induced cognitive impairment in SD rat was evaluated by spontaneous alternation behavior in Y-Maze test. After 30 min scopolamine injection, the scopolamine-induced rats presented significantly decreased % spontaneous alteration and acetylcholine level, compared to non-induced group. However, treatment of SC+RF extracts rescued the reduced % spontaneous alteration with acetylcholine concentration from hippocampus in scopolamine-induced rats. These results suggested that mixture of SC and RF extract may be a potential natural therapeutic agent for the prevention of cognitive impairment.

Enhanced Antioxidant Enzymes Are Associated with Reduced Hydrogen Peroxide in Barley Roots under Saline Stress

  • Kim, Sang-Yong;Lim, Jung-Hyun;Park, Myoung-Ryoul;Kim, Young-Jin;Park, Tae-Il;Seo, Yong-Won;Choi, Kyeong-Gu;Yun, Song-Joong
    • BMB Reports
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    • 제38권2호
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    • pp.218-224
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    • 2005
  • Antioxidant enzymes are related to the resistance to various abiotic stresses including salinity. Barley is relatively tolerant to saline stress among crop plants, but little information is available on barley antioxidant enzymes under salinity stress. We investigated temporal and spatial responses of activities and isoform profiles of superoxide dismutase (SOD), catalase (CAT), ascorbate peroxidase (APX), non-specific peroxidase (POX), and glutathione reductase (GR) to saline stress in barley seedlings treated with 200 mM NaCl for 0, 1, 2, 5 days, respectively. In the control plant, hydrogen peroxide content was about 2-fold higher in the root than in the shoot. Under saline stress, hydrogen peroxide content was decreased drastically by 70% at 2 d after NaCl treatment (DAT) in the root. In the leaf, however, the content was remained unchanged by 2 DAT and increased about 14 % at 5 DAT. In general, the activities of antioxidant enzymes were increased in the root and shoot under saline stress. But the increase was more significant and consistent in the root. The activities of SOD, CAT, APX, POX, and GR were increased significantly in the root within 1 DAT, and various elevated levels were maintained by 5 DAT. Among the antioxidant enzymes, CAT activity was increased the most drastically. The significant increase in the activities of SOD, CAT, APX, POX, and GR in the NaCl-stressed barley root was highly correlated with the increased expression of the constitutive isoforms as well as the induced ones. The hydrogen peroxide content in the root was most highly correlated with the CAT activity, indicating an increased role of CAT in hydrogen peroxide detoxification under salinity stress. In addition, the results suggest the significance of temporal and spatial regulation of each antioxidant isoform in determining the competence of the antioxidant capacity under saline stress.

미백 후 유예 기간에 따른 상아질과 레진의 결합 강도의 변화 (Effect of post-bleaching time intervals on resin in dentin bonding strength)

  • 송신재;김선종;노영선;류재준
    • 대한치과보철학회지
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    • 제47권2호
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    • pp.174-181
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    • 2009
  • 연구목적: 본 연구에서는 35% 과산화수소를 사용하는 전문가 미백 술식에서 레진 접착제의 접착력 회복을 위한 유예 기간을 비교하고자 한다. 연구 재료 및 방법:3M사의 Single Bond와 Z350을 이용하여 미백 직 후, 1일후, 2일후, 일주일 후의 시간 차이를 두고 상아질에 접착된 복합 레진의 전단 결합 강도를 측정하여 다음과 같은 결과를 얻었다. 결과: 미백 처리 직 후의 상아질 전단 결합 강도는 다른 군에 비해 유의하게 낮았으며(P<.05), 미백 처리 전에 비해 약 78%의 결합력 감소를 보였다. 미백 처리 1일 후의 상아질 결합 강도는 미백 직 후 감소된 결합력의 51%에 이르는 회복을 보였으며, 2일 경과한 시편에서는 감소된 결합력의 63%가 회복되었다. 두 군은 미백 직 후에 비해 유의하게 큰 회복력을 보였으나, 두 군 간에는 유의한 차이가 없었다(P>.05). 미백 처리 후 결합력의 회복은 초기 24시간 이내에 급격히 일어나며 그 이후에는 서서히 일어나는 것으로 사료된다. 미백 일주일 후의 시편은 미백 처리 전에 비해97%에 이르는 결합력을 보이며 두 군 간에는 유의한 차이가 없었다(P>.05). 결론: 그러므로35% 과산화수소를 적용하는 전문가 미백 술식에서는 1주일간의 유예기간을 두고 복합 레진 접착술을 시행하는 것이 적절할 것으로 사료된다.

Cordyceps militaris alleviates non-alcoholic fatty liver disease in ob/ob mice

  • Choi, Ha-Neul;Jang, Yang-Hee;Kim, Min-Joo;Seo, Min Jeong;Kang, Byoung Won;Jeong, Yong Kee;Kim, Jung-In
    • Nutrition Research and Practice
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    • 제8권2호
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    • pp.172-176
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    • 2014
  • BACKGROUND/OBJECTIVES: Non-alcoholic fatty liver disease (NAFLD) is becoming an important public health problem as metabolic syndrome and type 2 diabetes have become epidemic. In this study we investigated the protective effect of Cordyceps militaris (C. militaris) against NAFLD in an obese mouse model. MATERIALS/METHODS: Four-week-old male ob/ob mice were fed an AIN-93G diet or a diet containing 1% C. militaris water extract for 10 weeks after 1 week of adaptation. Serum glucose, insulin, free fatty acid (FFA), alanine transaminase (ALT), and proinflammatory cytokines were measured. Hepatic levels of lipids, glutathione (GSH), and lipid peroxide were determined. RESULTS: Consumption of C. militaris significantly decreased serum glucose, as well as homeostasis model assessment for insulin resistance (HOMA-IR), in ob/ob mice. In addition to lowering serum FFA levels, C. militaris also significantly decreased hepatic total lipids and triglyceride contents. Serum ALT activities and tumor necrosis factor-${\alpha}$ (TNF-${\alpha}$) and interleukin-6 (IL-6) levels were reduced by C. militaris. Consumption of C. militaris increased hepatic GSH and reduced lipid peroxide levels. CONCLUSIONS: These results indicate that C. militaris can exert protective effects against development of NAFLD, partly by reducing inflammatory cytokines and improving hepatic antioxidant status in ob/ob mice.

Cure Kinetics of a Bisphenol-A Type Vinyl-Ester Resin Using Non-Isothermal DSC

  • Ahn, WonSool
    • Elastomers and Composites
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    • 제53권1호
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    • pp.1-5
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    • 2018
  • In the current research, the curing kinetics of a mixture system consisting of a Bisphenol-A type vinyl ester resin and styrene monomer was studied. Methylethylketone peroxide and cobalt octoate were used as the polymerization initiator and accelerator respectively. Thermograms with several different heating rates were obtained using non-isothermal differential scanning calorimetry. Activation energy values analyzed by the Flynn-Wall-Ozawa isoconversional method showed a three-step change with conversion ${\alpha}$: a slight decrease initially for ${\alpha}$ < 0.1, a constant value of 47.9 kJ/mol in the range 0.1 < ${\alpha}$ < 0.7, and a slow increase for 0.7 < ${\alpha}$. When assuming a constant activation energy of 47.9 kJ/mol, an autocatalytic model of the Sestak-Berggren equation was considered as the proper mathematical model of the conversion function, indicating an overall order of 1.2.

A Comparative Investigation on Alkaline Peroxide Mechanical Pulp of Poplar Fast-Growing Clones and a Native Species

  • Ramezani, Omid
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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    • pp.349-352
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    • 2006
  • The conventional pulping processes in Iran were reviewed in this paper. On account of forest resources restriction, a considerable extent of non-harvestable hardwood forests, the possibility of accessable non-wood resources and Poplar fast-growing species for using in pulp and paper industry was investigate. The cultivated area and abundance of each mentioned raw material (Wheat Straw, Sugarcane Bagasse, Poplars) were specified and the quality of their produced papers were compared in strength and opacity properties. Spruce species data was used for experiments comparisons. Regarding to environmental pollutions, low yield, inflexibility in wood and non-wood species resulted from the existent conventional processes of paper manufacturing, APMP is recommended due to high quality paper, desirable opacity properties, high yield and also the usage for all the raw materials.

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유자액 처리에 의한 고등어유와 필렛의 냉장 저장중 품질 특성 (Quality Characteristics of Citron Treated Mackerel Oil and Fillet during Refrigerated Storage)

  • 정복미;정규화;장미순;신석우
    • 한국식품과학회지
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    • 제36권4호
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    • pp.574-579
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    • 2004
  • 유자를 이용하여 등푸른생선인 고등어에 유자 자숙액 및 착즙액을 처리하여 냉장 보관하면서 기름을 추출한 고등어유와 고등어 필렛의 여러 가지 특성을 측정한 결과는 다음과 같다. 고등어 필렛를 냉장 보관하면서 25일간의 저장기간별 휘발성 염기질소와 TMA-N를 측정한 결과 유자액을 처리하지 않은 대조구에 비하여 1, 2% 처리구와 자숙액 처리구에서 유의적으로 낮게 나타났으며, 저장기간이 증가함에 따라 대조구는 유자액 처리구에 비하여 더욱 높게 나타났으며, 유자액 처리구중 특히 자숙액 처리구가 가장 낮게 나타났다. 고등어유의 과산화물가, 카르보닐가, 산가 및 TBA가를 측정한 결과 대조구에서 대체로 저장기간이 실험 시작 시에 비해 25일 후에는 급격히 증가하는데 비하여 유자액 처리구에서는 완만한 증가를 보였으며, 특히 자숙액 처리구에서 더욱 완만하게 나타나 다른 처리구에 비해 유의적으로 낮게 나타났다. 관능평가 결과에서도 전반적인 기호도에서 자숙액 처리구가 가장 높은 점수를 나타내 대조구와 2% 처리구에 비해 유의적인 차이를 나타냈으며, 1% 처리구에서도 높은 점수를 나타내 자숙액 처리구와 차이를 나타내지 않았다. 본 실험결과로 볼 때 간 고등어 제조 시 유자액 처리는 고등어의 산패를 감소시키고, 비린내를 완화하는데 효과적이며 특히 유자 자숙액 처리군이 좋은 결과를 나타냈으며, 유자 자숙액 대신 착즙액 처리 시 1% 용액을 사용하는 것이 바람직하다고 사료된다.