• Title/Summary/Keyword: non-Ideal Systems

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Study on the Micellization of TTAB/Brij 35 Mixed Systems in Aqueous Solutions of n-Butanol (n-부탄올 수용액에서 TTAB/Brij 35 혼합계면활성제의 미셀화에 대한 연구)

  • Gil, Han-Nae;Lee, Byung-Hwan
    • Applied Chemistry for Engineering
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    • v.18 no.3
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    • pp.267-272
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    • 2007
  • The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the trimethyltetradecylammonium bromide (TTAB) with the polyoxyethylene (23) lauryl ether (Brij 35) at $25^{\circ}C$ in water and in aqueous solutions of n-butanol (0.1 M, 0.2 M, and 0.3 M) were determined as a function of ${\alpha}_1$ (the overall mole fraction of TTAB) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters ($X_i$, ${\gamma}_i$, $C_i$, ${a_i}^M$, ${\beta}$, and ${\Delta}H_{mix}$) were calculated by means of the equations derived from the nonideal mixed micellar model. The effects of n-butanol on the micellization of TTAB/Brij 35 mixtures have been also studied by analyzing the measured and calculated thermodynamic parameters.

Effect of n-Butanol on the Micellization of DBS/Brij 35 Mixed Surfactant Systems (DBS/Brij 35 혼합계면활성제의 미셀화에 미치는 n-부탄올 효과)

  • Lee, Byeong-Hwan;Park, In-Jeong
    • Journal of the Korean Chemical Society
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    • v.50 no.5
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    • pp.355-361
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    • 2006
  • The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the sodium dodecylbenzenesulfonate (DBS) with the polyoxyethylene(23) lauryl ether (Brij 35) at 25oC in water and aqueous solutions of n-butanol (0.1M, 0.2M, and 0.3M) were determined as a function of a1 (the overall mole fraction of DBS) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters (Xi, i, Ci, aiM, , and Hmix) were calculated by means of the equations derived from the nonideal mixed micellar model. The effect of n-butanol on the micellization of the DBS/Brij 35 mixtures has been also studied by analyzing the measured and calculated thermodynamic parameters.

Current Status of Gene Therapy as a New Drug Delivery System (신약전달기술체계인 유전자 치료의 현재까지의 개발동향)

  • Bae, Yun-Sung;Cho, Jung-Yoon;Ji, Sang-Mi;Lee, Young-Joo
    • Journal of Pharmaceutical Investigation
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    • v.32 no.3
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    • pp.153-159
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    • 2002
  • Gene therapy is fundamentally a sophisticated drug delivery technology to cure a disease by the transfer of genetic material to modify living cells. In other words, the gene is used as a therapeutic drug much like a chemical compound is employed in chemotherapy. Currently almost 600 clinical trials are underway worldwide since the first clinical trials carried out in 1990 to treat adenosine deaminase deficiency using retroviral vectors. Despite the great progress still is there no gene therapy product being approved as a new drug. This is partly due to a lack of an ideal gene delivery system that is safe and can provide stable, optimal level production of the therapeutic proteins in the cell. This review covers the current status of several different biological and physico-chemical agents that are being developed as gene delivery vehicles. Although gene therapy promises great hopes toward the cure of a broad spectrum of genetic and acquired diseases, the success of gene therapy heavily asks for the development of vector systems for safe and efficient application in humans.

Performance Improvement in Single-Phase Electric Spring Control

  • Wang, Qingsong;Zuo, Wujian;Cheng, Ming;Deng, Fujin;Buja, Giuseppe
    • Journal of Power Electronics
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    • v.19 no.3
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    • pp.784-793
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    • 2019
  • Two objectives can be pursued simultaneously with the ${\delta}$ control of a single-phase electric spring (ES). These objectives are the stabilization of the voltage across the critical load (CL) of a power system, and the achievement of a specific functionality similar to the pure compensation of reactive power or the correction of the power factor. However, existing control systems implementing the ${\delta}$ control do not cope with non-ideal operating conditions, such as line voltage distortions, and exhibit a somewhat sluggish regulation of the CL voltage. In an effort to improve both the steady-state and transient performances of an ES power system, this paper proposes implementing the ${\delta}$ control by means of a control system built up on the repetitive control and assisted by state feedback with pole assignment. This paper starts by analyzing the dynamics of an ES power system in terms of its poles and zeros. After that, a reduced second-order model of the dynamics is formulated to avoid a notch filter in the pole assignment. A repetitive control for an ES power system is then designed to meet the two above mentioned objectives. Experimental tests carried out on a laboratory setup demonstrate the effectiveness of the proposed control system in significantly improving the ES power system performance, while reaching the two objectives. In particular, the tests outline the large mitigation of harmonics in the CL voltage under line voltage distortions and its fast stabilization action.

The Task of the Translator: Walter Benjamin and Cultural Translation (번역자의 책무-발터 벤야민과 문화번역)

  • Yoon, Joewon
    • Journal of English Language & Literature
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    • v.57 no.2
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    • pp.217-235
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    • 2011
  • On recognizing the significance of Walter Benjamin's "The Task of a Translator" in recent discourses of postcolonial cultural translation, this essay examines the creative postcolonialist appropriations of Benjamin's theory of translation and their political implications. In an effort to dismantle the imperialist political hierarchy between the West and the non-West, modernity and its "primitive" others, which has been the operative premise of the traditional translation studies and anthropology, newly emergent discourses of cultural translation actively adopts Benjamin's notion of translation that does not prioritize the original text's claim on authenticity. Benjamin theorizes each text-translation as well as the original-as an incomplete representation of the pure language. Eschewing formalistic views propounded by deconstructionist critics like Paul de Man, who tend to regard Benjamin's notion of the untranslatable purely in terms of the failure inherent in the language system per se, such postcolonialist critics as Tejaswini Niranjana, Rey Chow, and Homi Bhabha, each in his/her unique way, recuperate the significatory potential of historicity embedded in Benjamin's text. Their further appropriation of the concept of the "untranslatable" depends on a radically political turn that, instead of focusing on the failure of translation, salvages historical as well as cultural potentiality that lies between disparate cultural entities, signifying differences, or disjunctures, that do not easily render themselves to existing systems of representation. It may therefore be concluded that postcolonial discourses on cultural translation of Niranhana, Chow, and Bhabha, inspired by Benjamin, each translate the latter's theory into highly politicized understandings of translation, and this leads to an extensive rethinking of the act of translation itself to include all forms of cultural exchange and communicative activities between cultures. The disjunctures between these discourses and Benjamin's text, in that sense, enable them to form a sort of theoretical constellation, which aspires to an impossible yet necessary utopian ideal of critical thinking.

Improved Method to Select Targets in Phase Gradient Autofocus on Real Time Processing (실시간 처리를 위한 PGA 표적 선택기법 개선)

  • Lee, Hankil;Kim, Donghwan;Son, Inhye
    • The Journal of Korean Institute of Information Technology
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    • v.17 no.10
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    • pp.57-63
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    • 2019
  • Motion errors which are caused by several reasons, non-ideal path, errors of navigation systems, and radar system errors, have to be corrected. Motion compensation methods can compensate the motion error, but not exactly. To correct these residual errors, several autofocus methods are invented. A popular method is phase gradient autofocus (PGA). PGA does not assume specific circumstances, such as isolated point targets and shapes of errors. PGA is an iterative and adaptive method, so that the processing time is the main problem for the real time processing. In this paper, the improved method to select targets for PGA is proposed to reduce processing time. The variances of image pixels are used to select targets with high SNR. The processing of PGA with these targets diminishes the processing time and iterations effectively. The processed results with real radar data, obtained by flight tests, show that the proposed method compensates errors well, and reduce working time.

A Note for 1.5σ Shift of Six Sigma (식스시그마의 1.5σ 이동에 대한 소고)

  • Park, Jong Hun
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.45 no.1
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    • pp.31-40
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    • 2022
  • Six Sigma is a philosophy and systematic methodology for quality improvement. It encourages continuous quality improvement efforts to achieve the ideal goal of 6σ. Sigma(σ) is a statistic representing the standard deviation of the normal distribution, and 6σ level means a level where the tolerance of the specification is six times the standard deviation of the process distribution. In terms of the defective rate, the 6σ level achieves the 0.002 defectives per one million units. However, in the field, the 6σ level is used in the sense of achieving 3.4 defects per one million opportunities, which shows a large gap from the 6σ level in the statistical viewpoint. This is because field practitioners accept a 1.5σ shift of the mean of process when calculating the defective rate under sigma level. It said that the acceptance of 1.5σ shift of the mean is from experience, but there is no research or theoretical explanation to support it logically. Although it is a non-scientific explanation based on experience, considering that there has been no objection to the 1.5σ shift for a long time and it is rather accepted, it is judged that there is a reasonable basis for the 1.5σ shift. Therefore, this study tries to find a reasonable explanation through detective power of control chart via the run-rules to the 1.5σ shift empirically recognized by practitioners.

Protocol implementation for simultaneous signal continuation acquisition of industrial plant machine condition in wireless sensor networks (산업플랜트 기계상태 동시신호 연속취득을 위한 무선센서 네트워크프로토콜 구현)

  • Lee, Hoo-Rock;Chung, Kyung-Yul;Rhyu, Keel-Soo
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.7
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    • pp.760-764
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    • 2015
  • Wireless sensors, installed on machinery, and Time Division Multiple Access (TDMA) transmission make an ideal system for monitoring machine conditions in industrial plants because there is no need for electronic wiring. However, there has not yet been a successful field application of such a system, capable of continuously transmitting data at sample rates greater than 100 Hz. In this research, a TDMA network protocol capable of acquiring data from multiple sensors at sample rates greater than 100 Hz was developed for field application. The protocol was implemented in a single cluster-star topology network, and the system was evaluated based on the node number and transmission distance. Network simulator 2 (ns-2) was used for a real field simulation. Non-TDMA and TDMA protocol cases were compared using four sensor nodes. In the cases of 20-s and 40-s transmission times, there was little difference between the reception rates of the non-TDMA and TDMA systems. However, the difference was much greater when using a 60-s transmission time.

The Measurement of Minimum Flash Point Behaviour (MFPB) for Binary Mixtures (이성분계 혼합물의 최소인화점 현상의 측정)

  • Hong, Soon-Kang;Yoon, Myung-O;Lee, Sung-Jin;Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.25 no.3
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    • pp.113-118
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    • 2011
  • The flash point is an important indicator of the flammability of a chemical. The minimum flash point behaviour (MFPB) is exhibited when the flash point of a mixture is below the flash points of the individual components. The identification of this behaviour is critical, because a hazardous situation results from taking the lowest component flash point value as the mixture flash point. In this study, the flash points for the n-butanol + n-decane and n-octane + n-propanol systems which exhibit MFPB, were measured by Tag open-cup apparatus. The experimental data were compared with the alues calculated by the Raoult's law, the van Laar equation and the Wilson equation. The calculated values based on the van Laar and Wilson equations were found to be better than those based on the Raoult's law. It was concluded that the van Laar and Wilson equations were more effective than the Raoult' law at describing the activity coefficients for non-ideal solution such as the n-butanol + n-decane and n-octane + n-propanol systems. The predictive curve of the flash point prediction model based on the Wilson equation described the experimentally-derived data more effectively than was the case when the prediction model was based upon the van Laar equation.

Opticla Angle Sensor Using Pseudorandom-code And Geometry-code (슈도 랜덤 코드와 기하학 코드를 이용한 광학적 Angle Sensor)

  • 김희성;도규봉
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.41 no.2
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    • pp.27-32
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    • 2004
  • Absolute optical angle sensor is described that is an essentially digital opto-electronic device. Its purpose is to resolve the relative and absolute angle position of coded disk using Pseudorandom-code and Geometry-code. In this technique, the angular position of disk is determined in coarse sense first by Pseudorandom-code. A further fine angular position data based on Pixel count is obtained by Geometry-code which result 0.006$^{\circ}$ resolution of the system provided that 7 ${\mu}{\textrm}{m}$ line image sensor are used. The proposed technique is novel in a number of aspects, such that it has the non-contact reflective nature, high resolution of the system, relatively simple code pattern, and inherent digital nature of the sensor. And what is more the system can be easily modified to torque sensor by applying two coded disks in a manner that observe the difference in absolute angular displacement. The digital opto-electronic nature of the proposed sensor, along with its reporting of both torque and angle, makes the system ideal for use in intelligent vehicle systems. In this communication, we propose a technique that utilizes Pseudorandom-code and Geometry-code to determine accurate angular position of coded disk. We present the experimental results to demonstrate the validity of the idea.