• 제목/요약/키워드: nitrogen generation

검색결과 290건 처리시간 0.032초

Dielectric barrier discharge 플라즈마 펄스 레이져 증착법을 통해 성장한 nitrogen 도핑 된 산화아연 박막의 광학적 특성 (Optical properties of nitrogen doped ZnO thin films grown by dielectric barrier discharge plasma-assisted pulsed laser deposition)

  • 이득희;김상식;이상렬
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2009년도 제40회 하계학술대회
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    • pp.1256_1257
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    • 2009
  • We have grown, for the first time to our knowledge, N-doped ZnO thin films on sapphire substrate by employing novel dielectric barrier discharge in pulsed laser deposition (DBD-PLD). DBD guarantees an effective way for massive in-situ generation of N-plasma under the conventional PLD process condition. Low-temperature photoluminescence spectra of the N-doped ZnO film provided near band-edge emission after thermal annealing process. The emission peak was resolved by Gaussian fitting to find a dominant acceptor-bound exciton peak ($A^0X$) that indicates the successful p-type doping of ZnO with N.

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폴리나이트로젠 에너지물질 (Polynigrogen Energetic Materials)

  • 이준웅
    • 한국군사과학기술학회지
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    • 제19권3호
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    • pp.319-329
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    • 2016
  • Current research trends of prediction of possible structures, synthesis and explosive characteristics of polynitrogen molecules(PNs) are reviewed. Theoretically PNs are composed only of nitrogen atoms, in which N-N bonds are either single or double bonds, and thus when these molecules decompose, release of enormous energy is accompanied. From the middle of 20th century energetic material chemists have been seeking possible structures and the methods of synthesis of these new materials. As a results, from $N_4$ to $N_{60}$ together with their ions are predicted, and experimental chemists have been trying to synthesize these materials with a few success, including the famous ${N_5}^+$ ion in 1999. Although experimental successes are very rare beyond $N_5$ until today, the author believes that renovative ideas together with sincere efforts will bring someday next generation of high energy materials such as nitrogen fullerene($N_{60}$) in reality.

초미세 발포성형에서 게이트의 형상 변화에 따른 셀의 크기 및 밀도에 대한 영향도 분석 (Analysis of the effect of changes in the gate design on cell size and density in Mucell injection molding)

  • 최재혁
    • Design & Manufacturing
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    • 제17권1호
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    • pp.64-69
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    • 2023
  • This paper explores the impact of gate shape changes on the size and density of foamed cells in microcellular foam injection molding. Five different gate shapes were examined while varying the amount of nitrogen gas(N2) injected for foaming. Analysis of the results showed that while average values did not change significantly, deviation values decreased by approximately 65% for cell size and 56% for density when 3.5wt% of nitrogen gas was injected in the film gate. Further analysis was conducted to verify this phenomenon, revealing that the contact area between the gate and product had the greatest impact. Our findings indicate that to ensure uniform generation of foamed cells in microcellular foaming product design, a gate with a wide contact area should be secured.

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암모니아 활용 고체산화물 연료전지 재순환 발전 시스템 (Ammonia-fueled Solid Oxide Fuel Cell Recirculation Systems for Power Generation)

  • 박진영;쿠 엔;김진선;배용균;이동근;김영상;이선엽;김영
    • 한국수소및신에너지학회논문집
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    • 제35권1호
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    • pp.40-47
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    • 2024
  • Ammonia is drawing attention as carbon free fuel due to its ease of storage and transportation compared to hydrogen. This study suggests ammonia fueled solid oxide fuel cell (SOFC) system with electrochemical hydrogen compressor (EHC)-based recirculation. Performance of electrochemical hydrogen pump is based on the experimental data under varying hydrogen and nitrogen concentration. As a result, the suggested system shows 62.04% net electrical efficiency. The efficiency is 10.33% point higher compared to simple standalone SOFC system (51.71%), but 0.02% point lower compared to blower-based recirculation system (62.06%). Further improvement in the EHC-based SOFC recirculation system can be achieved with EHC performance improvement.

실리콘과 코발트 박막의 계면구조에서 발생하는 1/f 잡음현상 연구 (Generation of 1/f Noise in Interfacial Structures between Silicon Substrate and Cobalt Thin Film)

  • 조남인;남형진;박종윤
    • 한국진공학회지
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    • 제5권1호
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    • pp.48-53
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    • 1996
  • We present a microscopic description for generation of 1/f noise in interfaces between cobalt thin film and silicon substrate. Along with surface resistance measurements and transmission electron diffraction observations. 1/f noise power spectral density has been measured for the interfacial structures at the liquid nitrogen temperature . The cobalt films have been deposited by the electron-beam evaporation technique onto p-type (100) silicon in the high vacuum condition. The measured noise power spectral density shows highest magnitude near the structural transition and metallization transition region. The noise magnitude rapidly decreased after the cobalt silicide nucleation. The noise parameter is concluded to be originated form the structural fluctuations.

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배기가스 재순환 버너에서 연소가스 출구 위치에 따른 연소 유동 특성에 관한 연구 (A Study on the Combustion Flow Characteristics of a Exhaust Gas Recirculation Burner with the Change of Outlet Opening Position)

  • 하지수
    • 한국산학기술학회논문지
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    • 제19권8호
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    • pp.8-13
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    • 2018
  • 질소산화물은 최근에 초미세먼지 발생에 많은 영향을 주고 있어서 대기환경 개선 측면에서 사회적으로도 크게 관심이 되고 있다. 질소산화물은 주로 화력발전 등의 연소기기에서 고온의 연소가스 분위기에서 공기 중의 질소와 산소가 반응하여 발생한다. 이에 대한 저감 방법으로 원통형 버너에 코안다 노즐을 이용한 배관으로 배기가스를 재순환하는 연소에 대한 연구가 최근에 이루어지고 있다. 본 연구에서는 코안다 노즐을 사용하여 배기가스를 재순환하는 원통형 버너의 연소가스 출구의 위치를 오른쪽으로 하는 버너(Case 1 버너), 양쪽을 출구로 하는 버너(Case 2 버너), 왼쪽을 출구로 하는 버너(Case 3 버너) 형상에 대하여 전산유체해석을 통해 연구를 수행하였으며 연소 유동의 압력, 유선, 온도, 연소 반응 속도와 질소산화물의 분포 특성을 비교 분석하였다. 연소반응은 Case 1과 Case 2버너는 연소가스 재순환 유입구가 있는 오른쪽 방향으로 일어나고 Case 3 버너는 혼합가스 유입구 부근에서 일어나고 있었다. 출구에서의 온도는 Case 2버너가 양쪽으로 배출되면서 다른 버너 보다 약 $100^{\circ}C$ 정도 온도가 낮게 나타났으며 출구에서의 NOx 농도는 Case 1버너가 다른 형상 버너 보다 약 20배 크게 나타났다. 이로부터 NOx 저감을 위해서는 배기가스 재순환 버너의 출구는 양쪽으로 배출되게 하거나 연소가스 재순환 유입구 반대 방향으로 배출 되도록 하는 것이 효과적임을 알 수 있었다.

고밀도 플라즈마 내에서의 plasma species의 변화 (The generation of nitrogen ion species in high-density plasma with HCD)

  • 김상권;김성완
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2009년도 춘계학술대회 논문집
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    • pp.234-234
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    • 2009
  • 고밀도 플라즈마 질화를 위해 장비 내에 보조 HCD (Hollow Cathode Discharge) 전극을 설치하여 고밀도의 플라즈마가 발휘되도록 장비를 구축하였다. 기존 bias 플라즈마 질화는 1-10Torr의 공정압력인데 반하여 $10^{-1}-10^{-2}$Torr의 비교적 고 진동에서 고밀도의 플라즈마를 발생시켰다. HCD 질화는 bias plasma 질화 공정의 플라즈마를 비교하면 가스 비의 영향이 매우 큰 것드로 관찰되었으며 기존에 발표된 플라즈마 질화 관련 모델과 비교하여 관찰된 플라즈마 내에서는 ion species가 실제 공정에서도 영향을 미치는 것을 알 수 있었다.

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초전도케이블 냉각시험 (Cooling Test of The HTS Power Cable)

  • 염한길;고득용;홍용주;김익생;김춘동;김도형
    • 한국초전도저온공학회:학술대회논문집
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    • 한국초전도저온공학회 2003년도 학술대회 논문집
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    • pp.295-297
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    • 2003
  • Cryogenic systems is requirement for the operation of HTS power cables. In general, HTS power cables require temperature below 77K, a temperature that can be achieved from the liquid nitrogen or sub-cooled LN2. HTS power cable is needed for sufficient refrigeration to overcome its low temperature heat loading. This loading typically comes in two forms : (1) heat leaks from the surroundings and (2) internal heat generation. This paper is a explanation for the cooling test of 10m HTS power cable.

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고에너지 음향환경시험 튜브 개발 (Development of High Intensity Progressive Wave Tube)

  • 김영기;김홍배;문상무;우성현;임종민
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2005년도 춘계학술대회논문집
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    • pp.962-965
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    • 2005
  • A high intensity progressive wave tube is installed at Korea Aerospace Research Institute (KARI) for acoustic environmental tests. The test facility has 700 mm x 800 mm cross-sectional area, and provides acoustic environment of 165 dB over the frequency range of $25Hz{\sim}10,000Hz$. The facility consists of a 6 m long acoustic wave tube, acoustic power generation systems, gases nitrogen supply systems, and acoustic control systems. This paper describes how the basic parameters of the facility and power generation systems are controlled to meet the requirement of the test. The shape and length of the tube has been designed by using the size of test objects and the wave propagation characteristics of the tube. The capacity of acoustic power generation systems is determined by the energy conversion of acoustic wave and the efficiency of acoustic modulators. Moreover, the paper introduces test run results of the tube. Overall of 163dB has been generated by using the test facility.

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고무류 반응특성이 LPG액상공급시스템의 연료분사기 성능에 미치는 영향 (Reaction Characteristics of Rubbers and LPG fuels in LPLi Fuel Supply System)

  • 김창업;박철웅;최교남;강건용
    • 한국분무공학회지
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    • 제12권2호
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    • pp.94-100
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    • 2007
  • The liquid phase LPG injection (LPLi) system (the third generation technology) has been considered as one of the next generation fuel supply systems for LPG vehicles, since it has a very strong potential to accomplish the higher power, higher efficiency, and lower emission characteristics than the mixer type (the second generation technology) fuel supply system. To investigate the characteristics of LPG residue in liquid phase LPG injection system, various rubbers in LPG fuel system were reacted with LPG fuels during 3 months. The experimental results showed that the residue of a cover rubber in a fuel pump after test increased 10 times higher than that before test. Furthermore, the amount of sulfur, nitrogen species which are considered as main sources in deposit formation in the LPLi fuel injector were also found to be higher than that in original LPG fuel. And rubber properties of fuel pump cover were decreased after reaction test compared with those of the original rubber. Therefore, the rubber for fuel pump cover is not suitable for a proper material in LPLi fuel system. And these results can provide more information if a motor company shares the data of core rubber parts in field test LPLi vehicles.

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