• Title/Summary/Keyword: nitrate ($NO_3{^-}$)

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Hydrochemistry of an alluvial aquifer in the Cheonan area: role of the pyrite oxidation on denitrification

  • Kim, Kyoung-Ho;Yun, Seong-Taek;Chae, Gi-Tak;Heo, Chul-Ho;Kim, Hyoung-Soo;Rhee, Chul-Woo;Kim, Kangjoo
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.287-290
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    • 2002
  • To examine the denitrification process in an alluvial aquifer in the Cheonan site, hydrological and hydrogeochemical studies were carried out. Elevated levels of NO$_3$ (maximum 77.6 mg/L) were observed in shallow groundwaters of the area, as a result of poultry and agricultural activity. However, the nitrate concentrations were found to be consistently attenuated down to very low levels (<1.0 mg/L). The abrupt removal of nitrate coincided with the pattern of redox change and indicated that denitrification is the most plausible process. The hydrochemistry and mass balance approach using geochemical modeling (phreeqc 2.0) and redox chemistry indicated that chemo-autotrophic denitrification via pyrite oxidation is the key Process to control the nitrate attenuation in the study area.

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Effects of Nitrogen and Sodium on Growth in Phaeodactylum tricornutum (Bacillariophyceae)

  • Lee Soon Jeong;Choi Han Gil;Nam Ki Wan
    • Fisheries and Aquatic Sciences
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    • v.3 no.2
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    • pp.151-155
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    • 2000
  • Phaeodactylum tricornutum (Bacillariophyceae) is a marine diatom which has been supplied as a food of bivalves. In this study, growth responses of P. tricornutum to some nitrogen sources and sodium were investigated by measuring cell number and contents of chlorophyll a in culture. In medium with nitrogen and sodium, brisk cell division occurred and maximum growth rate was respectively found in the medium with 150 mg/l of nitrate and 10 mg/l of ammonium and urea. At 10-500 mg/l ammonium and urea and 200-500 mg/l nitrate, specific growth rate decreased slightly. However, no cell division observed in sodium-deficient medium, regardless of presence or absence of nitrogen. This suggests that sodium is required for the nitrogen uptake of P. tricornutum, resulting nitrogen uptake leading to cell division. Also the upper limits of ammonium and nitrate for the growth of P. tricornutum seem to be 10 mg/l and 500 mg/l, respectively.

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Characterization of the Growth, Total Lipid and Fatty Acid Profiles in Microalga, Nannochloropsis oceanica under Different Nitrogen Sources

  • Mahdieh, Majid;Shabani, Salimeh;Amirjani, Mohammad Reza
    • Microbiology and Biotechnology Letters
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    • v.47 no.1
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    • pp.11-19
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    • 2019
  • The properties of microalgae as bioresources for biodiesel production can be improved by adding nitrogen sources into the culture medium. Thus, Nannochloropsis oceanica CCAP 849/10 was cultured in f/2 media supplemented with five different forms of nitrogen at $0.88mmol-N\;l^{-1}$ each: ammonium bicarbonate ($NH_4HCO_3$), ammonium sulfate ($(NH_4)_2SO_4$), sodium nitrate ($NaNO_3$), ammonium nitrate ($NH_4NO_3$), and urea. The cell density, lipid content, and fatty acid profile of the microalga were determined after 15 days of cultivation. The growth of N. oceanica based on cell number was lowest in the medium with $NH_4NO_3$, and increased significantly in the medium with $NH_4HCO_3$. Cells treated with $(NH_4)_2SO_4$, and $NH_4NO_3$ produced the highest total lipid contents (i.e., 65% and 62% by dry weight, respectively). The fatty acid profiles of the microalga were significantly different in the various nitrogen sources. The major fatty acids detected in cultures supplemented with $NH_4HCO_3$, $(NH_4)_2SO_4$, $NH_4NO_3$, or urea were C14:0, C16:0, C16:1, C18:0, C18:1, C18:2, C20:5, and C22:6. However, the C16:1 content in the $NaNO_3$-supplemented culture was very low. This study highlights that the nitrogen source can strongly influence lipid production in N. oceanica and its fatty acid composition.

Study on Characteristics of Electrodeposited Thin Copper Film by Inorganic Additives in Pyrophosphate Copper Plating Bath (피로인산동욕의 무기첨가제에 의한 전해동박의 특성에 관한 연구)

  • Koo, Seokbon;Hur, Jinyoung;Lee, Hongkee
    • Journal of the Korean institute of surface engineering
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    • v.47 no.1
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    • pp.1-6
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    • 2014
  • The copper deposit on steel plate was prepared by pyrophosphate copper plating solution made with variation of inorganic additive. $NH_4OH$ and $NH_4NO_3$ were used as inorganic additives. The copper layer characteristics - tensile strength, crystallite size and crystal orientation - were evaluated by X-ray diffraction and Universal Test Machine. The presence of ammonium nitrate results in reduction of average roughness value from $0.08{\mu}m$ to $0.03{\mu}m$. In pyrophosphate copper plating solution without Inorganic additive, tensile strength of electrodeposit copper foil was reduced from 600 MPa to 180 MPa after 7 days aging. However, when adding ammonium nitrate, there was almost no change of tensile strength, intensity of crystal orientation - (111), (200) and (220) - and crystallite size (2~30 nm).

Effects of Temperature and Ethylene Response Inhibitors on Growth and Flowering of Passion Fruit

  • Liu, Fang-Yin;Peng, Yung-Liang;Chang, Yu-Sen
    • Horticultural Science & Technology
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    • v.33 no.3
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    • pp.356-363
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    • 2015
  • This study examined the effects of different day/night temperature regimes or silver ion on growth and flowering of passion fruit 'Tai-nung No.1'. Low temperature treatment ($20/15^{\circ}C$) caused passion fruit cultivar 'Tai-nung No.1' to fail to flower. Flowering induction occurred within a temperature range of $20-30^{\circ}C$, with no significant difference in the days to first flower bud and the total number of flower buds between plants grown at $30/25^{\circ}C$ and $25/20^{\circ}C$. However, plants grown at $30/25^{\circ}C$ exhibited their first flower buds set on the higher nodes and had higher abortion rates of flower buds than those at $25/20^{\circ}C$. Plants grown at $30/25^{\circ}C$ had the most rapid growth and the shortest plastochron. We also evaluated the effect of the ethylene response inhibitors silver nitrate ($AgNO_3$) and silver thiosulfate (STS) on growth and flowering of potted passion fruit 'Tai-nung No.1', when they were exposed to low temperature conditions ($20/15^{\circ}C$) following chemical treatments ($AgNO_3$ or STS, at 0.5 or 1.0 mM). $AgNO_3$ and STS treatments induced flower formation and initial flower bud formation within approximately two weeks at $20/15^{\circ}C$ whereas non-treated control plants exhibited no flower formation. ACC content and activity of ACC oxidase in the leaves of passion fruit 'Tai-nung No.1'exposed to low temperature conditions ($20/15^{\circ}C$) were significantly inhibited by the ethylene inhibitor treatments. These results indicate that ethylene, which is produced under low temperature conditions, plays an important role in inhibiting flower formation in passion fruit.

Effect of DPF Regeneration on Emission Characteristics in Diesel Engines (DPF 재생이 경유자동차 배출특성에 미치는 영향)

  • Moon, Taeyoung;Son, Jihwan;Yun, Hyunjin;Hong, Heekyoung;Choi, Kwangho;Kim, Jeongsoo;Kim, Heekyoung
    • Journal of ILASS-Korea
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    • v.19 no.3
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    • pp.142-148
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    • 2014
  • In this study, characteristics of gaseous pollutants and particulate matter were investigated on the condition of DPF regeneration and normal DPF condition. THC, CO, $CO_2$, NOx, and $CH_4$ were analyzed by MEXA-7200H and CVS-7100 respectively. Particulate Matter (PM) was measured by difference in weight of Membrane filter. Particle Number (PN) was measured by CPC analyzer. And Sulfate, Nitrate, Organic were measured by Aerosol Mass Spectrometer (AMS). As a result, gaseous pollutants and particulate matter were detected in higher concentration during DPF regeneration than normal DPF condition. And the PN increased by 94%, the fuel consumption was reduced by 29% on DPF generation process. Sulfate, Nitrate and Organic were undetectable level during normal DPF condition. But the highest concentration of Sulfate, Nitrate and Organic were measured as $100{\mu}g/m^3$, $20{\mu}g/m^3$ and $15{\mu}g/m^3$ respectively on DPF regeneration condition. VOCs concentrations (Benzene, Toluene, Ethylbenzene, Xylene) were analyzed by using PTR-MS. Benzene and Toluene emission have little or no change depending on DPF regeneration. But the Ethylbenzene and Xylene have comparatively low emissions on DPF regeneration.

Effect of Nitrogen Levels and Harvest Intervals on Dry Matter Yield of Barnyard Millet

  • Lee, Bae Hun;Choi, Ki Choon;Yang, Seung Hak;Oh, Mirae;Park, Hyung Soo
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.42 no.3
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    • pp.176-182
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    • 2022
  • The aim of this study was to investigate dry matter productivity and nitrate nitrogen content in the growth stages of barnyard millet (Echinochloa esculenta) cultivated for feed, which was treated with different nitrogen fertilization levels. An early variety of barnyard millet (cv. Shirohie) was used for the test, and the different treatments with nitrogen fertilizer were as follows: 50% (N-40 kg/ha, T1), 100% (N-80 kg/ha, reference amount, T2), 150% (N-120 kg/ha, T3), 200% (N- 160 kg/ha, T4), 250% (N-200 kg/ha, T5), and 300% (N-240 kg/ha, T6). Sowing was done on May 13, 2021 and plants were harvested for four stage; vegetative stage, elongation stage, heading stage, and milk stage. The length of the millet increased significantly as the amount of nitrogen fertilization increased during the harvest period (p<0.05), but the difference was insignificant during the milk stage (p>0.05). Moreover, barnyard millet dry matter yield increased significantly as the levels of nitrogen fertilization increased (p<0.05), but there was no significant difference in dry matter yield among nitrogen fertilization levels during the heading stage (p>0.05). Chlorophyll also was significantly higher in T5 (250%) at all harvesting times, whereas nitrate nitrogen content was highest at the vegetative stage, gradually decreased as growth progressed, and lowest at the milk stage. Finally, as the nitrogen fertilization levels increased, the nitrate nitrogen content was significantly higher in all treatment groups (p<0.05). Therefore, our results suggest that the most appropriate nitrogen fertilizer levels is between 150%-200%, considering the dry matter yield, feed ingredients and nitrate nitrogen content in barnyard millet for feed.

Mechanical and Thermal Conductivity Properties of Yttrium Nitrate Added AlN Sintering Body (Y(NO3)3·6H2O 첨가된 AlN 소결체의 기계적 및 열전도도 특성)

  • Chung, J.K.;Lee, J.H.;Ha, T.K.
    • Transactions of Materials Processing
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    • v.27 no.1
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    • pp.48-53
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    • 2018
  • Aluminum nitride (AlN) is used by the semiconductor industry that has requirements for high thermal conductivity. The theoretical thermal conductivity of single crystal AlN is 320W/mK. Whereas, the values measured for polycrystalline AlN ceramics range from 20 W/mK to 280 W/mK. The variability is strongly dependent upon the purity of the starting materials and non-uniform dispersibility of the sintering additive. The conventional AlN sintering additive used yttria ($Y_2O_3$), but the dispersibility of the powder in the mixing process was important. In this study, we investigated the mechanical and thermal conductivity of yttrium nitrate ($Y(NO_3)_3{\cdot}6H_2O$), as a sintering additive in order to improve the dispersibility of $Y_2O_3$. The sintering additives content was in the range of 2 to 4.5wt.%. The density of AlN gradually increased with increasing contents of sintering additive and the flexural strength gradually increased as well. The flexural strength of the sintered body containing 4 wt% of $Y_2O_3$ and $Y(NO_3)_3{\cdot}6H_2O$ was 334.1 MPa and 378.2 MPa, respectively. The thermal conductivities were 189.7W/mK and 209.4W/mK, respectively. In the case of hardness, there was only a slight difference and the average value was about 10 GPa. Therefore, densification, density and strength values were found to be proportional to its content. It was confirmed that AlN using $Y(NO_3)_3{\cdot}6H_2O$ displayed relatively higher thermal conductivity and mechanical properties than the $Y_2O_3$.

Physical and Chemical Management Practices for Improving Water Quality in Channel Catfish Ictalurus punctatus Aquaculture

  • Seo, Jin-Won
    • Journal of Aquaculture
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    • v.15 no.1
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    • pp.49-60
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    • 2002
  • Research on practices for improving water quality in channel catfish Ictalurus punctatus ponds was conducted at the Auburn University Fisheries Research Station, Auburn, Alabama, in 1998 and 1999. The objective of this two-year study was to determine better management practices to enhance water quality and improve production efficiency. In the first year, oxidation of bottom soil by drying, tilling, and applying sodium nitrate was performed (dry-till and dry-till with sodium nitrate treatments). The second year, based on the results obtained during the first year, precipitation of phosphorus (P) from water by applying gypsum was compared to the dry-till treatment (dry-till and dry-till with gypsum treatments). Control ponds were not subjected to bottom drying, tilling, sodium nitrate, or gypsum treatment. Channel catfish fingerings were stocked at 15,000/ha. In the first year, water in ponds from dry-till and dry-till with sodium nitrate treatments had lower concentrations (P < 0.01) of soluble reactive P, nitrate ($NO_{3} ^{-}) and nitrite ($NO_{2} ^{-}) nitrogen (N), total ammonia ($NH_3$) nitrogen, total suspended solids and turbidity, and higher values of pH, Secchi disk visibility, total alkalinity, total hardness, and calcium ($Ca^{2+}) hardness than water in control ponds. Ponds of the dry-till treatment also had lower concentrations (P < 0.01) of total P and total N than control ponds. Total fish production and survival rate did not differ among the treatments (P > 0.05). The findings suggested that drying and tiling pond bosoms between crops could achieve water quality improvement. Applying sodium nitrate to dry, tilled pond bosoms did not provide water quality improvement. In the second year, the treatment with the best results from the first year, dry-till, was compared with a dry-till with gypsum treatment. Enough gypsum was applied to give a total hardness of about 200 mg/L, and gypsum was reapplied as needed to maintain the hardness. Compared to the control, dry-till and dry-till with gypsum treatments had lower concentrations (P < 0.01) of total and soluble reactive P, total N, and total $NH_3$-N, and higher concentrations (P < 0.01) of dissolved oxygen. Ponds of the duty-till with gypsum treatment also had lower concentrations (P < 0.01) of chlorophyll $\alpha$, chemical oxygen demand, and total alkalinity than the control. Total fish production and survival rate did not differ (P > 0.05) among the treatments. These findings suggest that drying and tilling pond bosoms between crops and treating low hardness waters with gypsum could achieve water Quality improvement.

Evaluation of Photochemical Pollution during Transport of Air Pollutants in Spring over the East China Sea

  • Sadanaga, Yasuhiro;Kobashi, Tadashi;Yuba, Akie;Kato, Shungo;Kajii, Yoshizumi;Takami, Akinori;Bandow, Hiroshi
    • Asian Journal of Atmospheric Environment
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    • v.9 no.4
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    • pp.237-246
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    • 2015
  • We conducted intensive observations of ozone, CO, $NO_x$ (=NO and $NO_2$), $NO_y$ (total odd nitrogen species including particulate nitrate) and total nitrate (the sum of gaseous $HNO_3$ and particulate nitrate) at Cape Hedo, Okinawa, Japan, from 19 March to 3 April, 2009, to investigate ozone production during long-range transport from the Asian continent. Ozone production efficiency (OPE) was used to evaluate photochemical ozone production. OPE is defined as the number of molecules of ozone produced photochemically during the lifetime of a $NO_x$ molecule. OPE is calculated by the ratio of the concentration increase of ozone to that of $NO_z$ ($=NO_y-NO_x$). Average OPE during observation was estimated to be $12.6{\pm}0.5$, but concentrations of ozone increased nonlinearly with those of $NO_z$. This non-linearity suggests that OPE depends on air mass origin and $NO_z$ concentrations. There were very different values of OPE for the same air mass origin, so that only the air mass origin alone does not control OPE. OPE was low when $NO_z$ concentration was high. We examined the correlation between $NO_z$ and $CO/NO_y$ ratios, which we used instead of the ratio of non-methane hydrocarbons (NMHCs) to $NO_x$. The $CO/NO_y$ ratios decreased with increasing $NO_z$ concentrations. These results indicate that competition reactions of OH with NMHCs and $NO_2$ are the rate determining steps of photochemical ozone production during long-range transport from the Asian continent to Cape Hedo, for high concentrations of nitrogen oxides.