• Title/Summary/Keyword: nano-tubes

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Carbon Nano Tube Dispersion Evaluation in B-stage Resin Films (B-stage 레진 필름의 카본나노튜브 분산도 평가 및 제조공정 최적화)

  • Oh, Young-Seok;Park, Tea-Hoon;Byun, Joon-Hyung;Yi, Jin-Woo;Kim, Byung-Sun;Joe, Chee-Ryong
    • Composites Research
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    • v.29 no.6
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    • pp.353-357
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    • 2016
  • An appropriate way to fabricate a hybrid composite containing evenly dispersed carbon nano tubes(CNTs) is to stacking B-stage resin films that contain evenly dispersed CNTs and various reinforcing fiber layers alternatively. In the present study, B-stage resin films are manufactured via shear mixing and three-roll milling. CNT dispersion in resin via these two processes are evaluated by SEM on their fracture surfaces. For more efficient process, the dispersivities are evaluated according to the number of calendering passes. Samples are made for different number of passes during calendering, and their dispersions are evaluated via SEM fractographs as well as by measuring their electrical conductivities. Additionally, the optimal process conditions are obtained by measuring the electrical conductivity and evaluating their dispersivity of the samples prepared by gap mode and force mode.

Development and Application of Conducting Shape Memory Polyurethane Actuators (전도성 형상기억폴리우레탄 작동기의 개발 및 응용)

  • Baek, Il-Hyeon;Gu, Nam-Seo;Jeong, Yong-Chae;Jo, Jae-Hwan
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.1
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    • pp.56-64
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    • 2006
  • This paper presents the development and application of a conducting shape memory polyurethane (CSMPU) actuator. While conventional shape memory polyurethanes were activated by external heat source, conducting shape memory polyurethanes introduced in 2004 are activated by electric power. Conducting shape memory polyurethane actuators were manufactured by adding carbon nano tube to conventional shape memory polyurethane. The main problem of the CSMPU developed in 2004 was bad dispersion of carbon nano tubes. In this paper, we tried to find how to solve the dispersion problem, and with a lot of elaborative works, conducting shape memory polyurethane actuators which had better electrical characteristics were developed. Then the actuation performance of the conducting shape memory polyurethane actuators was also measured and assessed. Finally, the possibility of applications were examined through the installation to Micro Air Vehicle.

Mechanical Properties and Creep Behaviors of Zr-Sn-Fe-Cr and Zr-Nb-Sn-Fe Alloy Cladding Tubes (Zr-Sn-Fe-Cr 및 Zr-Nb-Sn-Fe 합금 피복관의 기계적 특성 및 Creep 거동)

  • Lee, Sang-Yong;Ko, San;Choi, Young-Chul;Kim, Kyu-Tae;Choi, Jae-Ha;Hong, Sun-Ig
    • Korean Journal of Materials Research
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    • v.18 no.6
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    • pp.326-333
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    • 2008
  • Since the 1990s, the second generation of Zirconium alloys containing main alloy compositions of Nb, Sn and Fe have been used as a replacement of Zircaloy-4 (Zr-Sn-Fe-Cr), a first-generation Zirconium alloy, to meet severe and rigorous reactor operating conditions characterized by high-burn-up, high-power and high-pH operations. In this study, the mechanical properties and creep behaviors of Zr-Sn-Fe-Cr and Zr-Nb-Sn-Fe alloys were investigated in a temperature range of $450{\sim}500^{\circ}C$ and in a stress range of $80{\sim}150\;MPa$. The mechanical testing results indicate that the yield and tensile strengths of the Zr-Nb-Sn-Fe alloy are slightly higher compared to those of Zr-Sn-Fe-Cr. This can be explained by the second phase strengthening of the $\beta$-Nb precipitates. The creep test results indicate that the stress exponent for the steady-state creep rate decreases with the increase in the applied stress. However, the stress exponent of the Zr-Sn-Fe-Cr alloy is lower than that of the Zr-Nb-Sn-Fe alloy in a relatively high stress range, whereas the creep activation energy of the former is slightly higher than that of the latter. This can be explained by the dynamic deformation aging effect caused by the interaction of dislocations with Sn substitutional atoms. A higher Sn content leads to a lower stress exponent value and higher creep activation energy.

Preparation and Photosensitivity of Ag-Multi Walled Carbon Nanotube-TiO2 Nano Composite (Ag-Multi walled carbon nanotube-TiO2 복합나노소재 제조 및 광감응성)

  • Kim, Sung-Pil;Kim, Jong-Oh
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.2
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    • pp.5-11
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    • 2016
  • $MWCNT-TiO_2$ nano composites and $Ag-MWCNT-TiO_2$ nano composites were prepared from Multi-Walled Carbon NanoTube (MWCNT), titanium (IV) butoxide (TNB) solution and silver nitrate ($AgNO_3$) by the sol-gel method. The dispersion and structure of Ag in the synthesized composites was observed by Scanning Electron Microscopy (SEM) and Field Emission Transmission Electron Microscopy (FE-TEM). X-Ray Diffraction (XRD) patterns of the composites showed that the composites contained an anatase phase. The Energy Dispersive X-ray spectroscopy (EDX) showed the presence of C, O, Ti and Ag peaks. The $TiO_2$ particles were distributed uniformly in the MWCNT network, and Ag particles were virtually fixed on the surface of the tubes. Also decomposition of the methylene blue was investigated according to UV radiation times for study photocatalytic activity. $Ag-MWCNT-TiO_2$ nano composites show high photodegradation than $MWCNT-TiO_2$ nano composites. The results indicate that the high conductivity of Ag improved the photoactivity of the $MWCNT-TiO_2$ composite.

Fabrication and Characteristics of CNT-FEAs with Under-gate Structure

  • Noh, Hyung-Wook;Jun, Pil-Goo;Ko, Sung-Woo;Kwak, Byung-Hwak;Park, Sang-Sik;Lee, Jong-Duk;Uh, Hyung-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1470-1473
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    • 2005
  • We proposed new triode-type Field Emitter Arays using Carbon NanoTubes(CNT-FEAs) as electron emission sources at low electric fields. The CNTs were selectively grown on the patterned catalyst layer by Plasma-Enhanced Chemical Vapor Deposition (PECVD). In this structure, gate electrodes are located underneath the cathode electrodes and extracted gate is surrounded by CNT emitters. Furthermore, in order to control density of CNTs, we investigated effect of using rapid thermal annealing (RTA).

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Fabrication of Super Water Repellent Surfaces by Vacuum Plasma (진공 플라즈마 처리를 통한 초소수성 표면 제작 및 특성 평가)

  • Rha, Jong-Joo;Jeong, Yong-Soo;Kim, Wan-Doo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.2
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    • pp.143-147
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    • 2008
  • Super-hydrophobic surfaces showed that contact angle of water was higher than 140 degrees. That surface could be made several methods such as Carbon nano tubes grown vertically, PDMS asperities arrays, hydrophobic fractal surfaces, and self assembled monolayers coated by CVD and so on. However, we fabricated super-hydrophobic surfaces with plasma treatments which were very cost efficient processes. Their surfaces were characterized by static contact angles, advancing, receding, and stability against UV irradiation. Optimal surfaces showed static contact angles were higher than 150 degrees. Super-hydrophobic property was remained after UV irradiation for one week.

An XPS Study of Oxyfluorinated Multiwalled Carbon Nano Tubes

  • Yun, Seok-Min;Kim, Ju-Wan;Jung, Min-Jung;Nho, Young-Chang;Kang, Phil-Hyun;Lee, Young-Seak
    • Carbon letters
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    • v.8 no.4
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    • pp.292-298
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    • 2007
  • In order to investigate functional groups on the surface of Multi-walled Carbon Nanotubes (MWCNTs) induced by oxyfluorination, XPS (X-ray photoelectron spectroscopy) analysis was carried out. All core level spectra of MWCNTs were deconvoluted to several Pseudo-Voigt functions (sum of Gaussian-Lorentzian functions). Both O1s and F1s binding energy of oxyfluorinated MWCNTs shifted high value as increment of fluorine mixing ratio. The carbon-fluorine covalent bonding concentration increased as increment of fluorine mixing ratio. The shape and intensity of OF10-MWCNTs are similar with those of as-received MWCNTs. However, the intensity and binding energies of main peak position of OF20-MWCNTs and OF30-MWCNTs were dramatically increased by oxyfluorination.

Simulation of Hydrogen Transport in a Single-walled Carbon Nanotube for Storage Safety

  • Oh, Kyung-Su;Kim, Dong-Hyun;Park, Seung-Ho;Kim, Jung-Soo
    • International Journal of Safety
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    • v.6 no.1
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    • pp.16-21
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    • 2007
  • Carbon nanotubes hold much promise as future materials for safe storage of hydrogen. In this paper, hydrogen transport mechanisms in single-walled carbon nano-tubes (SWNTs) for various temperatures and chiral indices were studied using molecular dynamics simulation method. The SWNT models of zigzag (10,0), chiral (10,5) and armchair (10,10) with hydrogen molecules inside were simulated at temperatures ranging from 253K to 373K. Movements of hydrogen molecules ($H_2$) inside a SWNT were analyzed using mean-square displacements and velocity autocorrelation functions.

Electrical Resistance Characteristics of Conductive Cement Composite with Deterioration Damage (열화손상이 발생된 전도성시멘트복합체의 전기저항특성)

  • Kim, Young-Min;Lee, Gun Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.149-150
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    • 2020
  • Granting self-sensing performance in a building is an important performance to ensure the degree of damage and safety of the building. Since the current research is being conducted in the state before deterioration loss occurs, it is necessary to confirm whether the self-sensing performance is maintained even in the damaged conductive cement composite. As part of the study, electrical resistance characteristics were analyzed in conductive cement composites in which freeze-thawing and chemical corrosion occurred. As a result, it was found that the change in electrical resistance value due to freeze-thawing was not as large as 1%, and chemical corrosion occurred. It was found that the change in electrical resistance value of the tested specimen increased by about 10%.

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Impact and post-impact of ring supports: Eigenfrequency response at nano-scale

  • Madiha Ghamkhar;MohamedA. Khadimallah;Muzamal Hussain;Abdelouahed Tounsi
    • Structural Engineering and Mechanics
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    • v.88 no.2
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    • pp.109-115
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    • 2023
  • In this paper, frequencies of zigzag structure of carbon nanotubes isinvestigated based on Donnell shell theory. These tubes are wrapped with the ring supports in the axial direction. The fundamental frequency curves displayed in article show the dependence of vibrations attributes to zigzag single walled carbon nanotubes. Various zigzag indices are introduced against the variation of length to predict the vibration. Also, the influence of ring supports is sketched with proposed structure for frequency analysis. The frequencies of zigzag tube decreases as the length increases. It is observed that the frequencies decreases with ring support and have higher frequencies without ring. The problem is formulated using Partial Differential Equation. Three expressions of modal deformation displacement functions is used for the elimination of temporal variation to form the solution in the eigen from. For the stability of present study the results are compared with experimentally and numerically in the open text.