• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2017년도 춘계학술대회 논문집
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• pp.158-158
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• 2017

Titanium and its alloys have been used in the field dental and orthopedic implants because of their excellent mechanical properties and biocompatibility. Despite these attractive properties, their passive films were somewhat bioinert in nature so that sufficient adhesion of bone cells to implant surface was delayed after surgical treatment. Recently, plasma electrolyte oxidation (PEO) of titanium metal has attracted a great deal of attention is a comparatively convenient and effective technique and good adhesion to substrates and it enhances wear and corrosion resistances and produces thick, hard, and strong oxide coatings. Silicon(Si), Zinc(Zn), and Manganese(Mn) have a beneficial effect on bone. Si in particular has been found to be essential for normal bone and cartilage growth and development. And, Zn has been shown to be responsible for variations in body weight, bone length and bone biomechanical properties. Also, Mn influences regulation of bone remodeling because its low content in body is connected with the rise of the concentration of calcium, phosphates and phosphatase out of cells. The objective of this work was research on bone-like apatite morphology on Si-Zn-Mn-hydroxyapatite coating on Ti-6Al-4V alloy by plasma electrolytic oxidation. Anodized alloys were prepared at 280V voltage in the solution containing Si, Zn, and Mn ions. The surface characteristics of PEO treated Ti-6Al-4V alloy were investigated using XRD, FE-SEM, and EDS.

• 한국재료학회지
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• 제25권9호
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• pp.492-496
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• 2015

Hydroxyapatite (HA), which is an important calcium phosphate mineral, has been applied in orthopedics, dentistry, and many other fields depending upon its morphology. HA can be synthesized with different morphologies through controlling the synthesis method and several parameters. Here, we synthesize various morphologies of HA using two simple methods: hydrothermal combustion and solution combustion. The phase purity of the synthesized HA is confirmed using X-ray diffractometry. It demonstrates that pure phased hydroxyapatite can be synthesized using both methods. The morphology of the synthesized powder is examined using scanning electron microscopy. The effects of pH and temperature on the final powder are also investigated. At $140^{\circ}C$, using the hydrothermal method, nano-micro HA rods with a hexagonal crystal structure can be synthesized, whereas using solution combustion method at $600^{\circ}C$, a dense cubic morphology can be synthesized, which exhibits monoclinic crystal structures.

• 한국재료학회지
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• 제18권5호
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• pp.229-234
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• 2008

Porous Ti implant samples were fabricated by the sintering of spherical Ti powders in a high vacuum furnace. To increase their surface area and biocompatibility, anodic oxidation and a hydrothermal treatment were then applied. Electrolytes in a mixture of glycerophosphate and calcium acetate were used for the anodizing treatment. The resulting oxide layer was found to have precipitated in the phase form of anatase $TiO_2$ and nano-scaled hydroxyapatite on the porous Ti implant surface. The porous Ti implant can be modified via an anodic oxidation method and a hydrothermal treatment for the enhancement of the bioactivity, and current multi-surface treatments can be applied for use in a dental implant system.

• 한국표면공학회지
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• 제39권6호
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• pp.302-311
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• 2006

Nowadays the open-type lead-acid battery for vehicle use is being replaced with the sealed-type because it needs no maintenance and has a longer cycle life. Thus researches on this battery are being conducted very actively by many advanced battery companies. There is, however, a serious problem with the maintenance free(MF) battery that its cathode electrode has a limited cycle life due to a corrosion of grid. In this study, it was aimed to improve a corrosion resistance of the cathode grid which is commonly made of Pb-Ca alloy for a mechanical strength. For this purpose, various amounts of alloying elements such as Sn, Ag and Ba were added singly or together to the Pb-Ca alloys and investigated their corrosion behaviors. Batteries fabricated by using these alloys as cathode grids were subjected to life cycle test and their corrosion layers appeared at the interface between the grids and the active materials were carefully observed in order to clarify effects of alloying elements.

• 한국표면공학회지
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• 제40권5호
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• pp.225-233
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• 2007

Effects of alloying elements on the corrosion layer formation of Pb-grid/active materials interface has been researched for improvement of corrosion resistance of Pb-Ca alloy. For this research, various amounts of alloying elements such as Sn, Ag and Ba were added to the Pb-Ca alloys and investigated their corrosion behaviors. Batteries fabricated by using these alloys as cathode grids were subjected to life cycle test. Overcharge life cycle test was carried out at $75^{\circ}C$, 4.5 A, for 110 hrs. with KS standard (KSC 8504). And then, after keeping the battery with open circuit state for 48 hr, discharge was carried out at 300A for 30 sec. Corrosion morphology and interface between Pb-grid and active materials were investigated by using ICP, SEM, WDX, and LPM. Corrosion layer of Pb-Ca alloy got thicken with increasing Ca content. For Pb-Ca-Sn alloy, thickness of corrosion layer decreased as Sn and Ag content increased gradually. In case of Pb-Ca-Sn-Ba alloy, thickness of corrosion layer decreased up to 0.02 wt% Ba addition, whereas, it was not changed in case of above 0.02 wt% Ba addition.

• Advances in nano research
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• 제3권4호
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• pp.225-242
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• 2015

The current investigation aims to study performance of geopolymer mortar reinforced with Multiwalled carbon nanotubes upon exposure to $200^{\circ}C$ to $1000^{\circ}C$ for 2 hrs. MWCNTs are doped into slag Geopolymer mortar matrices in the ratio of 0.0 to 0.4, % by weight of binder. Mortar composed of calcium aluminosilicate to sand (1:2), however, binder composed of 50% air cooled slag and 50% water cooled slag. Various water / binder ratios in the range of 0.114-0.129 used depending on the added MWCNT, while 6 wt., % sodium hydroxide used as an alkali activator. Results illustrate reduction in mechanical strength with temperature except specimens containing 0.1 and 0.2% MWCNT at $200^{\circ}C$, while further increase in temperature leads to decrease in strength values of the resulting geopolymer mortar. Also, decrease in firing shrinkage with MWCNT up to 0.1% at all firing temperatures up to $500^{\circ}C$ is observed, however the shrinkage values increase with temperature up to $500^{\circ}C$. Further increase on the firing temperature up to $1000^{\circ}C$ results in an increase in the volume due to expansion.

• Advances in nano research
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• 제4권4호
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• pp.295-307
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• 2016

The present research work reports a low temperature ($40^{\circ}C$) chemical precipitation technique for synthesizing hydroxyapatite (HAp) nanoparticles of spherical morphology through a simple reaction of calcium nitrate tetrahydrate and di-ammonium hydrogen phosphate at pH 11. The crystallinity of the single-phase nanoparticles could be improved by calcinating at $600^{\circ}C$ in air. Thermogravimetric and differential thermal analysis (TG-DTA) revealed the synthesized HAp is stable up to $1200^{\circ}C$. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) studies confirmed the formation of spherical nanoparticles with average size of $23.15{\pm}2.56nm$ and Ca/P ratio of 1.70. Brunauer-Emmett-Teller (BET) isotherm of the nanoparticles revealed their porous structure with average pore size of about 24.47 nm and average surface area of $78.4m2g^{-1}$. Fourier transform infrared spectroscopy (FTIR) was used to confirm the formation of P-O, OH, C-O chemical bonds. Cytotoxicity and MTT assay on MG63 osteogenic cell lines revealed nontoxic bioactive nature of the synthesized HAp nanoparticles.

• 한국해양환경ㆍ에너지학회지
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• 제17권4호
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• pp.333-337
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• 2014

본 연구의 목적은 해수담수화 과정 중 생기는 농축수(Concentrated seawater)에서 염소이온은 제거하고 유용미네랄인 마그네슘, 칼슘은 잔존시키는 수질조정 기술로 고경도 농축수 제조 공정 개발에 있다. 기존의 고경도 농축수를 생산하는 일반적인 방법으로 증발법을 사용하고 있는 실정이다. 증발법은 에너지 소비량이 큰 단점을 가지고 있어, 본 연구에서는 에너지 소비량을 줄일 수 있는 막여과법을 사용하여 고경도 농축수를 제조하였다. 연구에 사용한 막은 나노여과막으로서, 제품의 사양, 농축 차수, 압력 등의 인자에 따라 고경도 농축수를 다양하게 만들 수 있었다. 본 연구의 실험 결과로 나노여과 막을 이용하여 고경도 농축수를 제조한 실험 결과, 압력은 15 bar~20 bar, 농축차수는 2차~3차에서의 결과 값이 경제성 등을 고려하였을 때 효과가 큰 것으로 나타났다. 본 실험을 통하여 나노여과막을 이용한 고경도 농축수 제조에 경제적인 효과를 얻을 수 있을 것으로 사료되어진다.

• Maxillofacial Plastic and Reconstructive Surgery
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• 제31권6호
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• pp.478-484
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• 2009

Three-dimensional porous scaffolds play an important role in tissue engineering strategies. They provide a void volume in which vascularization, new tissue formation, and remodeling can occur. Like any grafted materials, the ideal scaffold for bone tissue engineering should be biocompatible without causing an inflammatory response. It should also possess biodegradability, which provides a suitable three-dimensional environment for the cell function together with the capacity for gradual resorption and replacement by host bone tissue. Various scaffolds have already been developed for bone tissue engineering applications, including naturally derived materials, bioceramics, and synthetic polymers. The advantages of biodegradable synthetic polymers include the ability to tailor specific functions. The purpose of this study was to examine the osteogenic activity of periosteal-derived cells in a polydioxanone/pluronic F127 scaffold. Periosteal-derived cells were successfully differentiated into osteoblasts in the polydioxanone/pluronic F127 scaffold. ALP activity showed its peak level at 2 weeks of culture, followed by decreased activity during the culture period. Similar to biochemical data, the level of ALP mRNA in the periosteal-derived cells was also largely elevated at 2 weeks of culture. The level of osteocalcin mRNA was gradually increased during entire culture period. Calcium content was detactable at 1 week and increased in a time-dependent manner up to the entire duration of culture. Our results suggest that polydioxanone/pluronic F127 could be a suitable scaffold of periosteal-derived cells for bone tissue engineering.

• 한국해양환경ㆍ에너지학회지
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• 제18권1호
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• pp.9-14
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• 2015

바닷물 속에는 다양한 종류의 이온들이 존재한다. 바닷물을 음용수로 사용하기 위해서는 특정 성분은 농축하고 또 다른 특정 성분은 제거되어야 한다. 이러한 특성을 갖기 위해서는 바닷물의 수질을 조정하는 것이 필요하다. 특히 2가 양이온인 칼슘과 마그네슘은 인체에 유용한 물질이므로 이를 농축하는 기술이 필요하다. 본 연구에서는 나노막을 거친 농축수를 전기투석 장치를 이용하여 칼슘과 마그네슘을 농축하는 고경도수 제조기술을 연구하였다. 나노막을 이용하여 2가 이온 성분을 농축한 처리수를 얻은 후 이를 전기투석 장치에 적용시켜 1가 이온인 염화나트륨성분을 제거하였다. 이와 같이 전기투석 장치를 이용하여 고경도수를 제조할 수 있었다.