• 제목/요약/키워드: nano crystalline

검색결과 424건 처리시간 0.029초

Doping Controlled Emitter with a Transparent Conductor for Crystalline Si Solar Cells

  • 김민건;김현엽;최우진;이준신;김준동
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
    • /
    • pp.590-590
    • /
    • 2012
  • A transparent conducting oxide (TCO) layer was applied in crystalline Si (c-Si) solar cells without use of the conventional SiNx-coating. A high quality indium-tin-oxide (ITO) layer was directly deposited on an emitter layer of a Si wafer. Three different types of emitters were formed by controlling the phosphorous diffusion condition. A light-doped emitter forming a thinner emitter junction showed an improved photoconversion efficiency of 14.1% comparing to 13.2% of a heavy-doped emitter. This was induced by lower recombination within a narrower depletion region of the light-doped emitter. In the aspect of light management, the intermediate refractive index of ITO is effective to reduce the light reflection leading the enhanced carrier generation in a Si absorber. For the electrical aspect, the ITO layer serves as an efficient electrical conductor and thus relieves the burden of high contact resistance of the light-doped emitter. Additionally, the ITO works as a buffer layer of Ag and Si and certainly prevents the shunting problem of Ag penetration into Si emitter region. It discusses an efficient design scheme of TCO-embedded emitter Si solar cells.

  • PDF

Synthesis of Amorphous Er3+-Yb3+ Co-doped TiO2 and Its Application as a Scattering Layer for Dye-sensitized Solar Cells

  • Han, Chi-Hwan;Lee, Hak-Soo;Lee, Kyung-Won;Han, Sang-Do;Singh, Ishwar
    • Bulletin of the Korean Chemical Society
    • /
    • 제30권1호
    • /
    • pp.219-223
    • /
    • 2009
  • $TiO_2$ doped with $Er^{3+\;and\;Yb^{3+}$ was used for fabricating a scattering layer and a nano-crystalline $TiO_2$ electrode layer to be used in dye-sensitized solar cells. The material was prepared using a new sol-gel combustion hybrid method with acetylene black as fuel. The $Er^{3+}$-$Yb^{3+}$ co-doped titanium oxide powder synthesized at 700oC had embossed structure morphology with a size between 27 to 54 nm that agglomerated to produce micron size particles, as observed by the scanning electron micrographs. The XRD patterns showed that the $Er^{3+}$-$Yb^{3+}$ co-doped titanium oxide had an amorphous structure, while using the same method without doping $Er^{3+}\;or\;Yb^{3+},\;TiO_2$ was obtained in the crystallite form with thea dominance of rutile phase. Fabricating a bilayer structure consisting of nano-crystalline $TiO_2$ and the synthesized $Er^{3+}$-$Yb^{3+}$ co-doped titanium oxide showed better scattering property, with an overall increase of 15.6% in efficiency of the solar cell with respect to a single nano-crystalline $TiO_2$ layer.

함침된 나노결정립 리본을 이용한 광대역 유도형 결합기 연구 (A Study on Broadband Inductive Coupler using Impregnated Nanocrystalline Ribbon)

  • 김현식;주우진;손경락
    • 전기전자학회논문지
    • /
    • 제23권2호
    • /
    • pp.599-605
    • /
    • 2019
  • 페라이트 코어는 연자성 재료로서 유도형 전력선 통신을 위한 결합기 제작에 사용되고 있다. 그러나 전력선 통신환경에 따라 크기를 자유롭게 조절하기 어려운 재료이다. 본 논문에서는 페라이트 보다 투자율이 높은 나노 결정립합금을 이용하여 광대역 전력선 통신용 유도형 결합기 재료로 적용할 수 있음을 보고한다. 나노결정립은 얇은 리본 형태로 제조되므로 토로이달 코어에 감긴 리본의 횟수로 결합기의 크기를 자유롭게 조절할 수 있다. 함침법으로 만든 코어를 이용하여 유도형 결합기를 제작하였고, 이를 비접촉식 전력선 통신용에 적용할 수 있음을 보여주었다. 실험결과 100 A 이하의 선로 전류변동 조건에서 통신거리 100 m 까지는 45 Mbps, 200 m 까지는 8 Mbps의 대역폭을 보였으며 수신율은 100 %이였다.

STI CMP용 나노 세리아 슬러리에서 연마입자의 결정특성에 따른 평탄화 효율의 의존성 (Dependency of Planarization Efficiency on Crystal Characteristic of Abrasives in Nano Ceria Slurry for Shallow Trench Isolation Chemical Mechanical Polishing)

  • Kang, Hyun-Goo;Takeo Katoh;Kim, Sung-Jun;Ungyu Paik;Park, Jea-Gun
    • 한국재료학회:학술대회논문집
    • /
    • 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
    • /
    • pp.65-65
    • /
    • 2003
  • Chemical mechanical polishing (CMP) is one of the most important processes in recent ULSI (Ultra Large Scale Integrated Circuit) manufacturing technology. Recently, ceria slurries with surfactant have recently been used in STI-CMP,[1] became they have high oxide-to-nitride removal selectivity and widen the processing margin The role of the abrasives, however, on the effect of planarization on STI-CMP is not yet clear. In this study, we investigated how the crystal characteristic affects the planarization efficiency of wafer surface with controlling crystallite size and poly crystalline abrasive size independently.

  • PDF

Direct Deposition of high quality nanocrystalline Silicon Films by Catalytic CVD at Low Temperatures (<200 K)

  • Kim, Tae-Hwan;Lee, Kyoung-Min;Hwang, Jae-Dam;Hong, Wan-Shick
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
    • /
    • pp.261-263
    • /
    • 2008
  • We attempted modulation of the hydrogen dilution ratio in a Cat-CVD system to achieve both the minimal incubation layer and the high throughput. We obtained the incubation layer thickness of 3 nm, and were able to grow a 200 nm-thick film having a 70 % crystallinity in 18 minutes.

  • PDF

Precipitation of Calcium Phosphate at pH 5.0 for the β Tri-calcium Phosphate Cement

  • Chang, Myung Chul
    • 한국세라믹학회지
    • /
    • 제50권4호
    • /
    • pp.275-279
    • /
    • 2013
  • The purpose of this study was to prepare calcium phosphate cement [CPC] for use in artificial bone. Nano-crystalline calcium phosphate [CaP] was precipitated at $37^{\circ}C$ using highly active $Ca(OH)_2$ in DI water and an aqueous solution of $H_3PO_4$. From the XRD measurements, the nano-CaP powder was close to apatitic TCP phase and the powders fired at $800^{\circ}C$ showed a critical ${\beta}$-TCP phase. A mixture of one mole $CaCO_3$ and two moles di-calcium phosphate was calcined at $1100^{\circ}C$ to make a reference ${\beta}$-TCP material. The nano-CaP powders were added to the normal ${\beta}$-TCP matrix and fired at $900^{\circ}C$ to make a ${\beta}$-TCP block. The sintered block showed improved mechanical strength, which was caused by the solid state interaction between nano-CaP and normal ${\beta}$-TCP.

Transmission Electron Microscopy Specimen Preparation for Layer-area Graphene by a Direct Transfer Method

  • Cho, Youngji;Yang, Jun-Mo;Lam, Do Van;Lee, Seung-Mo;Kim, Jae-Hyun;Han, Kwan-Young;Chang, Jiho
    • Applied Microscopy
    • /
    • 제44권4호
    • /
    • pp.133-137
    • /
    • 2014
  • We suggest a facile transmission electron microscopy (TEM) specimen preparation method for the direct (polymer-free) transfer of layer-area graphene from Cu substrates to a TEM grid. The standard (polymer-based) method and direct transfer method were by TEM, high-resolution TEM, and energy dispersive X-ray spectroscopy (EDS). The folds and crystalline particles were formed in a graphene specimen by the standard method, while the graphene specimen by the direct method with a new etchant solution exhibited clean and full coverage of the graphene surface, which reduced several wet chemical steps and accompanying mechanical stresses and avoided formation of the oxide metal.

RF 마그네트론 스퍼터링 법으로 유리 기판 위에 성장 시킨 Ga 도핑된 ZnO 박막의 열처리에 따른 구조적, 광학적 특성 평가 (Structural and optical properties of heat-treated Ga doped ZnO thin films grown on glass substrate by RF magnetron sputtering)

  • 이지수;김금채;전훈하;황보수정;김도현;성창모;전민현
    • 한국진공학회지
    • /
    • 제17권1호
    • /
    • pp.23-27
    • /
    • 2008
  • 본 연구에서는 상온에서 RF 마그네트론 스퍼터링 법으로 유리 기판위에 증착된 Ga 도핑 된 다결정 ZnO 박막의 특성을 개선하기 위하여 적정 열처리 조건을 분석하였다. 먼저 박막 성장 후 박막의 특성을 분석하였고 각각 $400{\sim}600^{\circ}C$에서 30분, 60분간 질소 분위기에서 열처리를 한 후 구조적, 광학적 특성을 평가하였다. XRD와 FE-SEM을 사용하여 열처리온도 변화에 따른 결정입자의 크기의 변화를 관찰하였다. 그 결과 성장된 결정의 크기의 증가와 박막의 결정성이 향상되었음을 확인할 수 있었으며 그로 인해 박막 특성을 중시하는 투명 전도막의 투과도의 향상 또한 확인할 수 있었다. 결론적으로, 본 실험을 통하여 ZnO 성장 후 적절한 열처리를 수행함으로서 GZO 박막을 사용하여 제작된 소자의 특성을 개선할 수 있으리라 판단된다.

나노 구리-니켈 혼합분말의 충격압축법을 통한 복합벌크재의 제조 및 특성평가 (Manufacturing and Evaluation of the Properties of Hybrid Bulk Material by Shock-compaction of Nanocrystalline Cu-Ni Mixed Powder)

  • 김우열;안동현;박이주;김형섭
    • 한국분말재료학회지
    • /
    • 제21권3호
    • /
    • pp.196-201
    • /
    • 2014
  • In this study, nanocrystalline Cu-Ni bulk materials with various compositions were cold compacted by a shock compaction method using a single-stage gas gun system. Since the oxide layers on powder surface disturbs bonding between powder particles during the shock compaction process, each nanopowder was hydrogen-reduced to remove the oxide layers. X-ray peak analysis shows that hydrogen reduction successfully removed the oxide layers from the nano powders. For the shock compaction process, mixed powder samples with various compositions were prepared using a roller mixer. After the shock compaction process, the density of specimens increased up to 95% of the relative density. Longitudinal cross-sections of the shock compacted specimen demonstrates that a boundary between two powders are clearly distinguished and agglomerated powder particles remained in the compacted bulk. Internal crack tended to decrease with an increase in volumetric ratio of nano Cu powders in compacted bulk, showing that nano Cu powders has a higher coherency than nano Ni powders. On the other hand, hardness results are dominated by volume fraction of the nano Ni powder. The crystalline size of the shock compacted bulk materials was greatly reduced from the initial powder crystalline size since the shock wave severely deformed the powders.

진공자외선 여기에 의한 YAGG:Ce3+ 형광체의 광발광 특성에 미치는 Al2O3 나노입자 원료의 결정상의 영향 (Effect of the Crystalline Phase of Al2O3 Nanoparticle on the Luminescence Properties of YAGG:Ce3+ Phosphor under Vacuum UV Excitation)

  • 우미혜;최성호;정하균
    • 한국재료학회지
    • /
    • 제22권4호
    • /
    • pp.195-201
    • /
    • 2012
  • $Ce^{3+}$-doped yttrium aluminum gallium garnet (YAGG:$Ce^{3+}$), which is a green-emitting phosphor, was synthesized by solid state reaction using ${\alpha}$-phase or ${\gamma}$-phase of nano-sized $Al_2O_3$ as the Al source. The processing conditions and the chemical composition of phosphor for the maximum emission intensity were optimized on the basis of emission intensity under vacuum UV excitation. The optimum heating temperature for phosphor preparation was $1550^{\circ}C$. Photoluminescence properties of the synthesized phosphor were investigated in detail. From the excitation and emission spectra, it was confirmed that the YAGG:$Ce^{3+}$ phosphors effectively absorb the vacuum UV of 120-200 nm and emit green light positioned around 530 nm. The crystalline phase of the alumina nanoparticles affected the particle size and the luminescence property of the synthesized phosphors. Nano-sized ${\gamma}-Al_2O_3$ was more effective for the achievement of higher emission intensity than was nano-sized ${\alpha}-Al_2O_3$. This discrepancy is considered to be because the diffusion of $Al^{3+}$ into $Y_2O_3$ lattice is dependent on the crystalline phase of $Al_2O_3$, which affects the phase transformation of YAGG:$Ce^{3+}$ phosphors. The optimum chemical composition, having the maximum emission intensity, was $(Y_{2.98}Ce_{0.02})(Al_{2.8}Ga_{1.8})O_{11.4}$ prepared with ${\gamma}-Al_2O_3$. On the other hand, the decay time of the YAGG:$Ce^{3+}$ phosphors, irrespective of the crystalline phase of the nano-sized alumina source, was below 1 ms due to the allowed $5d{\rightarrow}4f$ transition of the $Ce^{3+}$ activator.