• Title/Summary/Keyword: nano composites

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Trends of Technologies for High Performance Polymer Barriers against Radiation (고성능 방사선 고분자 차단막 기술동향)

  • Lee, Gi-Bbeum;Park, Sung-Eun;Kim, In-Woo;Jeong, Kwang-Un;Lee, Hong-Ki;Nah, Chang-Woon
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.94-101
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    • 2011
  • The conventional radiation barriers may show some disadvantages such as heavy weight and possibility of poisoning human bodies because they are composed of lead plates or resin plates containing large amounts of lead powders. Another disadvantage may be direct penetration of radiation through small pin holes. In this article, technologies of multi-layered polymer barriers against radiation, which has been extensively focused recently, will be introduced. A new concept of radiation protection as well as improving endurance with employing nano-layered inorganic particles is introduced.

Aging Effect of Bio-inspired Artificial Basilar Membrane with Piezoelectric PVDF Thin Film

  • Kim, Wan Doo;Park, Su A;Kim, Sang Won;Kwak, Jun-Hyuk;Jung, Young Do;Hur, Shin
    • Elastomers and Composites
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    • v.50 no.4
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    • pp.292-296
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    • 2015
  • Biomimetic artificial basilar membrane being a core part of artificial cochlear requires performance evaluation through aging test. To evaluate the aging properties of PVDF piezoelectric membrane used for artificial basilar membrane, its mechanical properties such as tensile strength and elastic modulus and piezoelectric property such as piezoelectric constant were measured. The aging test conditions and acceleration constants were calculated based on Arrhenius model. The changes in tensile strengths and elastic moduli measured were less than 10~20% after aging test equivalent for 10 years. The piezoelectric constants were decreased drastically to 80% of its initial value in the early stage of the aging test and expected to decrease slowly down to 65% over 10 years. The experimental results show the reliability of totally implantable novel artificial cochlear and will contribute its commercialization.

PTCR Characteristics of Multifunctional Polymeric Nano Composites (PTCR 나노 복합기능 소재의 전류 차단 특성 연구)

  • 김재철;박기헌;서수정;이영관;이성재
    • Polymer(Korea)
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    • v.26 no.3
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    • pp.367-374
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    • 2002
  • Electrical characteristics of crystalline polymer composites filled with nano-sized carbon black particle were studied. The developed composite system exhibited a typical positive temperature coefficient resistance (PTCR) characteristic, where the electrical resistance sharply increased at a specific temperature. The PTCR effect was sometimes followed by a negative temperature coefficient resistance (NTCR) feature with temperature, which seemingly caused by the coagulation of nano-sized carbon black particles in the excessive quantity. The PTCR temperature was controlled by the carbon black content and the external voltage. The change of electric conductivity was shown as a function of carbon black content, and the resistance was constant when the carbon black content was over 20 wt%. The room-temperature resistance was maintained by a repeated heating and cooling. The excellent PTCR characteristic was demonstrated by the low resistance in the initial stage and the instantaneous heating capability.

Nanomechanical properties and wear resistance of dental restorative materials

  • Karimzadeh, A.;Ayatollahi, Majid R.;Nikkhooyifar, M.;Bushroa, A.R.
    • Structural Engineering and Mechanics
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    • v.64 no.6
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    • pp.819-826
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    • 2017
  • The effects of thermocycling procedure and material shade on the mechanical properties and wear resistance of resin-based dental restorative materials are investigated. The modulus of elasticity, hardness, plasticity index and wear resistance are determined for the conventional composite, the nanohybrid composite and the nanofilled dental composites. Disc-shape samples are prepared from each material to investigate the effects of thermocycling procedure on the mechanical properties and wear resistance of different types of dental restorative materials. In this respect, a group of samples is thermocycled and the other group is stored in ambient conditions. Then nano-indentation and nano-scratch tests are performed on the samples to measure their mechanical properties and wear resistance. Results show that the A1E shade of the dental nanocomposite possesses higher modulus of elasticity and hardness values compared to the two other shades. According to the experimental results, the mean values for the modulus of elasticity and hardness of the A1E shade of the nanocomposite are 13.71 GPa and 1.08 GPa, respectively. The modulus of elasticity and hardness of the conventional dental composite increase around 30 percent in the oral environment due to the moisture and temperature changes. The wear resistance of the dental composites is also significantly affected by moisture and temperature changes in the oral conditions. It is observed that thermocycling has no significant effect on the hardness, plasticity index and wear resistance of the nanohybrid composite and the nanocomposite dental materials.

High Thermal Conductivity h-BN/PVA Composite Films for High Power Electronic Packaging Substrate (고출력 전자 패키지 기판용 고열전도 h-BN/PVA 복합필름)

  • Lee, Seong Tae;Kim, Chi Heon;Kim, Hyo Tae
    • Journal of the Microelectronics and Packaging Society
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    • v.25 no.4
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    • pp.95-99
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    • 2018
  • High thermal conductivity films with electrically insulating properties have a great potential for the effective heat transfer as substrate and thermal interface materials in high density and high power electronic packages. There have been lots of studies to achieve high thermal conductivity composites using high thermal conductivity fillers such alumina, aluminum nitride, boron nitride, CNT and graphene, recently. Among them, hexagonal-boron nitride (h-BN) nano-sheet is a promising candidate for high thermal conductivity with electrically insulating filler material. This work presents an enhanced heat transfer properties of ceramic/polymer composite films using h-BN nano-sheets and PVA polymer resins. The h-BN nano-sheets were prepared by a mechanical exfoliation of h-BN flakes using organic media and subsequent ultrasonic treatment. High thermal conductivities over $2.8W/m{\cdot}K$ for transverse and $10W/m{\cdot}K$ for in-plane direction of the cast films were achieved for casted h-BN/PVA composite films. Further improvement of thermal conductivity up to $13.5W/m{\cdot}K$ at in-plane mode was achieved by applying uniaxial compression at the temperature above glass transition of PVA to enhance the alignment of the h-BN nano-sheets.

Multiscale approach to predict the effective elastic behavior of nanoparticle-reinforced polymer composites

  • Kim, B.R.;Pyo, S.H.;Lemaire, G.;Lee, H.K.
    • Interaction and multiscale mechanics
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    • v.4 no.3
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    • pp.173-185
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    • 2011
  • A multiscale modeling scheme that addresses the influence of the nanoparticle size in nanocomposites consisting of nano-sized spherical particles embedded in a polymer matrix is presented. A micromechanics-based constitutive model for nanoparticle-reinforced polymer composites is derived by incorporating the Eshelby tensor considering the interface effects (Duan et al. 2005a) into the ensemble-volume average method (Ju and Chen 1994). A numerical investigation is carried out to validate the proposed micromechanics-based constitutive model, and a parametric study on the interface moduli is conducted to investigate the effect of interface moduli on the overall behavior of the composites. In addition, molecular dynamics (MD) simulations are performed to determine the mechanical properties of the nanoparticles and polymer. Finally, the overall elastic moduli of the nanoparticle-reinforced polymer composites are estimated using the proposed multiscale approach combining the ensemble-volume average method and the MD simulation. The predictive capability of the proposed multiscale approach has been demonstrated through the multiscale numerical simulations.

3D Printable Composite Materials: A Review and Prospective (3D 프린터용 복합재료 연구 동향)

  • Oh, Eunyoung;Lee, Jinwoo;Suhr, Jonghwan
    • Composites Research
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    • v.31 no.5
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    • pp.192-201
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    • 2018
  • The use of 3D printing for rapid tooling and manufacturing has promised to produce components with complex geometries according to computer designs and it is emerging as the next generation key of manufacturing. Due to the intrinsically limited mechanical/electrical properties and functionalities of printed pure polymer parts, there is a critical need to develop 3D printable polymer composites with high performance. This article gives a review on 3D printing techniques of polymer composite materials and the properties and performance of 3D printed composite parts as well as their potential applications in the various fields.

Study of Antimicrobial Properties for Silver/Celite Composites (은/셀라이트 복합체의 항균특성에 관한 연구)

  • Lee, Chul-Jae;Kim, Byung-So
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.696-699
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    • 2009
  • In present work, the antimicrobial effect of silver-nanoparticles/celite (SN/C) and silver carbonate/celite (SC/C) composites on Escherichia coli (E. coli) by use of silver nanoparticles and silver carbonate has been studied. Characteristics of the SN/C and SC/C composites were identified by scanning electron microscopy (SEM), X-ray diffraction (XRD) and atomic absorption spectroscopy (AAS). SN/C and SC/C composites showed antimicrobial activity and the minimum inhibitory concentration of E. coli were 0.541, 0.344 ppm and the complete sterilizing concentration for the test organism were 1.427, 1.623 ppm. From the results we identified that SN/C and SC/C composites have antimicrobial activity to E. coli.

Performance Assessment of PVA Geotextile/HDPE Geomembrane Composites

  • Jeon, Han-Yong;Hong, Sang-Jin;Lyoo, Won-Seok
    • Journal of the Korean Geosynthetics Society
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    • v.4 no.1
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    • pp.37-46
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    • 2005
  • PVA geotextile/HDPE geomembrane composites were made to examine the waste landfill related properties. Tensile properties, tear and bursting strengths, AOS(apparent opening size) and permittivity of PVA geotextiles were evaluated, respectively. Ultraviolet stability and chemical resistance to the leachate was evaluated also. Friction property and creep deformation were tested at various loading condition. From this, it was seen that PVA geotextile/HDPE geomembrane composites have more excellent properties than the typically used polypropylene and polyester geotextiles in waste landfill. Finally, creep deformation behaviours of PVA geotextile/HDPE geomembrane composites were more stable than polypropylene and polyester geotextiles through the reduction factor analysis.

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Fabrication and Performance Evaluation of Carbon Fiber/Graphene Nano-Platelets Composites for Wear Resistance Application (GNP 첨가 탄소복합재료의 제조 및 마모 특성 평가)

  • Park, Seung-Bhin;Park, Jin-Chul;Cho, Chang-Woo;Song, Jung-Il
    • Korean Journal of Materials Research
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    • v.25 no.10
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    • pp.531-536
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    • 2015
  • GNPs have several excellent mechanical properties including high strength, a good young's modulus, thermal conductivity, corrosion resistance, electronic shielding, etc. In this study, CF/GNP/Epoxy composites were manufactured using GNP weight ratios of 0.15 wt%, 0.3 wt%, 0.5 wt%, 0.7 wt% and 1 wt%. The composites were manufactured with a mechanical method (3-roll-mill). Tensile, impact and wear tests were performed according to ASTM standards D3039, D256 and D3181, respectively. The results show that the CF/GNP0.3wt%/Epoxy composites have good mechanical properties, e.g., tensile strength and impact and wear resistance. In this study, both carbon fabric and GNPs were used as reinforcements in the composites. The mechanical properties increased and weight loss decreased as the GNP content in the resin films was increased.