• 제목/요약/키워드: nano composite

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Effect of Nano-silicate on the Mechanical, Electrical and Thermal Properties of Epoxy/Micro-silica Composite

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • 제13권3호
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    • pp.153-156
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    • 2012
  • In order to develop electrical insulation materials, epoxy/micro-silica composite (EMC) and epoxy/micro-silica/nano-silicate composite (EMNC) were prepared, and their tensile and flexural strength, AC insulation breakdown strength and thermal conductivity and thermal expansion coefficient were compared. Nano-silicate was prepared in an epoxy matrix by our AC electric field process. All properties of the neat epoxy were improved by the addition of micro-silica, which was improved much further by the addition of nano-silicate to the EMC system.

나노 Ruthenium Oxide 고분자 복합재료 pH전극 (Nano-Ruthenium Oxide Polymeric Composite pH Electrodes)

  • 박종만
    • 대한화학회지
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    • 제62권4호
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    • pp.269-274
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    • 2018
  • 금속산화물 고분자 복합재료전극 제조기법을 수소이온 감응성이 높은 $RuO_2$에 적용하여 표면연마가 가능한 나노 $RuO_2$ 복합재료 pH전극을 제조하였다. $RuO_2$ 함량 53 wt%을 가지는 나노 $RuO_2$ 복합재료 전극의 경우 나노 $IrO_2$ 복합재료 전극과 비슷한 수소이온 감응특성을 나타내었다. pH 1~9의 범위에서 이론치에 가까운 -58.7 mV/pH의 감응기울기, 1초 이하의 감응속도, 평균 $-57.0{\pm}0.3mV/pH$ (n=5)의 표면재생성, 장기 안정성 등 제반 특성과 전기화학적으로 활성이 높은 화학종에 의한 방해효과도 비슷하게 나타났다. 그러나 pH 10 이상의 염기성 용액에서의 감응기울기와 감응속도는 나노 $IrO_2$ 복합재료전극에 비하여 현저히 떨어지는 결과를 보였으며 이는 복합재료 매질 속의 금속산화물 함량에 따른 물리적 성질 차이에 따른 것으로 추측된다.

Experimental Investigation on Dielectric and Thermal Characteristics of Nanosized Alumina Filler Added Polyimide Enamel

  • Sugumaran, C. Pugazhendhi
    • Journal of Electrical Engineering and Technology
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    • 제9권3호
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    • pp.978-983
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    • 2014
  • The polymer nano composite possess good priority recently for engineering applications. Especially the electrical insulating materials attract the high performance of nano composites. In this work the ballmill synthesiation process of nano sized Alumina ($Al_2O_3$), the preparation of new nano composite material with an content of enamel and synthesized Alumina as 1wt%, 3wt% and 5wt%. Experimental investigation has been carried out for the prepared nano composites materials with respect to dielectric parameter measurements such as dielectric loss (tan ${\delta}$), dielectric constant (${\varepsilon}$), dielectric strength under various temperature. The partial discharge level also measured for all the samples and the PD inception voltage is also observed and compared. Weight loss of the material has been analyzed through TGA. It has been experimentally proved that 3wt% of Alumina nano filler added enamel has significant improvement in the dielectric and thermal properties.

우럭 껍질 젤라틴 복합필름의 특성 (Characterization of Rockfish Skin Gelatin Composite Films)

  • 백송이;김혜리;송경빈
    • 한국식품영양과학회지
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    • 제46권3호
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    • pp.394-399
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    • 2017
  • 플라스틱 포장 폐기물로 인한 환경오염을 해결하기 위한 대안으로 생분해성 필름이 많이 연구되어 왔다. 본 연구에서는 우럭 껍질 젤라틴(RFG)과 nano-clay(Cloisite $Na^+$, 10A)의 복합필름의 특성에 관하여 연구하였다. 우럭 껍질로부터 젤라틴을 추출하여 sorbitol을 가소제로서 첨가한 단백질 필름을 제조하였고, 제조된 RFG 필름의 tensile strength(TS), water vapor permeability(WVP), water solubility(WS)는 각각 15.0 MPa, $2.70{\times}10^{-9}g\;m/m^2\;s\;Pa$, 53.8%였다. RFG에 nano-clay를 첨가한 복합필름은 TS가 증가하고 WVP와 WS는 감소하였다. XRD 분석과 SEM 측정 결과를 통하여 RFG/nano-clay 복합필름 내부에 박리형 구조를 형성함을 확인할 수 있었다. 결론적으로 본 연구 결과 RFG/nano-clay 복합필름은 생분해성 포장재로 적용될 수 있음을 시사한다.

Filler Nano/Micro 혼합비가 Epoxy 수지의 유전특성에 미치는 영향

  • 정인범;최현민;신종열;이종용;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.249-249
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    • 2009
  • we have studied that a effect depending on dielectric properties of epoxy resin mixing filler nano/micro. When compare with nano/micro composite and virgin, the nano/micro composite is better than virgin. A specimen mixing nano/micro is changed as temperate, however the width of change is low.

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키토산/나노실버 복합섬유 혼방 부직포의 천연염색 염착특성 -감국을 중심으로- (Natural Dyeing Absorption Properties of Chitosan and Nano Silver Composite Non-Woven Fabrics -Focus on Chrysanthemum Indicum Linn-)

  • 홍병숙;주영주;이은진
    • 한국의류학회지
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    • 제34권5호
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    • pp.775-783
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    • 2010
  • This study examines the dyeability, light fastness, washing fastness, and the antibacterial activity of chitosan and nano silver composite non-woven fabrics dyed with an extracted solution from Chrysanthemum Indicum Linn. The results show that an increase in the chitosan and nano silver percentage resulted in an increase in the $a^*$ values and $b^*$ values; however, the $L^*$ values decreased in the undyed condition. ${\Delta}E$ values of chitosan and nano silver composite non-woven fabrics were higher than cotton 100% non-woven fabrics in the dyed condition with an extracted solution from Chrysanthemum Indicum Linn, and mordant treatments influenced the chrominance change. In the dyed condition with an extracted solution from Chrysanthemum Indicum Linn, an increase in the percentage of chitosan and nano silver resulted in an increase of the K/S values. The dyeability of chitosan and nano silver composite non-woven fabrics increased by mordant treatments. The light fastness and washing fastness of the mordanted non-woven fabrics were better than the non-mordanted. For the antibacterial activity, the bacterial reduction rate of chitosan and nano silver composite non-woven fabrics was 99.9% to Staphylococcus aureus and Klebsiella pneumoniae.

Preparation of Ru-C Nano-composite Film by MOCVD and Electrode Properties for Oxygen Gas Sensor

  • Kimura, Teiichi;Goto, Takashi
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.358-359
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    • 2006
  • Ru-C nano-composite films were prepared by MOCVD, and their microstructures and their electrode properties for oxygen gas sensors were investigated. Deposited films contained Ru particles of 5-20 nm in diameter dispersed in amorphous C matrix. The AC conductivities associating to the interface charge transfer between Ru-C composite electrode and YSZ electrolyte were 100-1000 times higher than that of conventional paste-Pt electrodes. The emf values of the oxygen gas concentration cell constructed from the nano-composite electrodes and YSZ electrolyte showed the Nernstian theoretical values at low temperatures around 500 K. The response time of the concentration cell was 900 s at 500 K.

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나노컴포지트 카본 잉크가 전착된 일회용 도파민 바이오센서 (A new nano-composite carbon ink for disposable dopamine biosensors)

  • 띠루 디나카란;장승철
    • 분석과학
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    • 제29권1호
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    • pp.35-42
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    • 2016
  • A new nano-composite carbon ink for the development of disposable dopamine (DA) biosensors based on screen-printed carbon electrodes (SPCEs) is introduced. The method developed uses SPCEs coupled with a tyrosinase modified nano-composite carbon ink. The ink was prepared by an “in-house” procedure with reduced graphene oxide (rGO), Pt nanoparticles (PtNP), and carbon materials such as carbon black and graphite. The rGO-PtNP carbon composite ink was used to print the working electrodes of the SPCEs and the reference counter electrodes were printed by using a commercial Ag/AgCl ink. After the construction of nano-composite SPCEs, tyrosinase was immobilized onto the working electrodes by using a biocompatible matrix, chitosan. The composite of nano-materials was characterized by X-ray photoelectron spectroscopy (XPS) and the performance characteristics of the sensors were evaluated by using voltammetric and amperometric techniques. The cyclic voltammetry results indicated that the sensors prepared with the rGO-PtNP-carbon composite ink revealed a significant improvement in electro-catalytic activity to DA compared with the results obtained from bare or only PtNP embedded carbon inks. Optimum experimental parameters such as pH and operating potential were evaluated and calibration curves for dopamine were constructed with the results obtained from a series of amperometric detections at −0.1 V vs. Ag/AgCl. The limit of detection was found to be 14 nM in a linear range of 10 nM to 100 µM of DA, and the sensor’s sensitivity was calculated to be 0.4 µAµM−1cm−2.

나노입자 첨가 유리섬유강화 복합재료의 전자기파 차폐특성 (Electromagnetic-wave Shielding by Nano Particles-contained Glass Fiber Reinforced Composite Materials)

  • 정우균;안성훈;원명식
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2004년도 추계학술대회 논문집
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    • pp.1331-1334
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    • 2004
  • The research on electromagnetic shielding has been advanced for military applications as well as for commercial products. Utilizing the reflective properties and absorptive properties of shielding material, the replied signal measured at the rear surface or at the signal source can be minimized. The shielding effect was obtained from materials having special absorptive properties or from structural characteristics such as stacking sequence. Recently researchers studied the electromagnetic properties of nano size particles. In this research {glass fiber}/{epoxy}/{nano particle} composites(GFR-Nano composites), was fabricated using various nano particles, and their properties in electromagnetic shielding were compared. For the visual observation of the nano composite materials, SEM(Scanning Electron Microscope) and TEM(Transmission Electron Microscope) were used. For the measurement of electromagnetic shielding, HP8719ES S-parameter Vector Network Analyser System was used on the frequency range of 8 GHz~12GHz. Among the nano particles, carbon black and Multi-Walled Carbon Nano-Tube (MWCNT) revealed outstanding electromagnetic shielding. Although silver nano particles (flake and powder) were expected to have effective electromagnetic shielding due to their excellent electric conductivities, test showed little shielding effect.

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Strain gradient based static stability analysis of composite crystalline shell structures having porosities

  • Fenjan, Raad M.;Faleh, Nadhim M.;Ridha, Ahmed A.
    • Steel and Composite Structures
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    • 재36권6호
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    • pp.631-642
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    • 2020
  • This paper studies nonlinear stability behavior of a nanocrystalline silicon curved nanoshell considering strain gradient size-dependency. Nanocrystallines are composite materials with an interface phase and randomly distributed nano-size grains and pores. Imperfectness of the curved nanoshell has been defined based on an initial deflection. The formulation of nanocrystalline nanoshell has been established by thin shell theory and an analytical approach has been used in order to solve the buckling problem. For accurately describing the size effects related to nano-grains or nano-pores, their surface energies have been included. Nonlinear stability curves of the nanoshell are affected by the size of nano-grain, curvature radius and nano-pore volume fraction. It is found that increasing the nano-pore volume fraction results in lower buckling loads.