• Journal of the Korean Applied Science and Technology
• /
• v.21 no.2
• /
• pp.132-139
• /
• 2004

Film forming behavior of monodispersed model composite latexes with particle size of 190 nm, which consist of n-butyl acrylate as a soft phase monomer and methyl methacrylate as a hard phase monomer with different morphology was examined. Five different types of model latexes were used in this study such as random copolymer particle, soft-core/hard-shell particle, hard-core/soft-shell particle, gradient type particle, and mixed type particle. The film forming behavior was evaluated using pseudo on-line measurements of the cumulative weight loss, the UV transmittance, and the tensile fracture energy. Each stages of film formation I, II were not sensitive to the morphology of model latexes, but stage-ill was largely dependent on the morphology of model latexes. The chain mobility of polymer which composed the shell component was found to dominantly determine the behavior of film forming stage-III.

• Journal of Theoretical and Applied Mechanics
• /
• v.2 no.1
• /
• pp.51-70
• /
• 1996

This study is generalization of the study of Miles[Physica 11D, 1984, pp.309-323]on the resonant motion of a spherical pendulum, which is equivalent to a particle on a spherical container subject to a linear, horizontal excitation. This study covers an arbitrary shape of container and a more general excitation (horizontal but elliptic motion). The averaging method is applied to reduce the governing equations to an autonomous system with cubic nonlinear terms, under the assumption of small amplitude of the container motion. It is shown that both the container shape and the excitation pattern affect the particle dynamics. Under the linear excitation, the anharmonic motion of the particle is possible only for a certain finite range of the parameter a controling the container shape. Stability of the particle's harmonic motion is also influenced by the excitation pattern; as the excitation trajectory becomes closer to a circle, the particle's motion has a stronger tendency to become stable and to follow the rotational direction of the excitation. Under a circular excitation, the motion is always stable and circular with the same rotational direction as the excitation. Analogy between the present model and that of the surface wave inside a circular is studied quantitatively.

• Journal of Korea Foundry Society
• /
• v.5 no.2
• /
• pp.85-96
• /
• 1985

In order to investigate the effect of particle size and distribution of silica sand on the characteristics of investment, W/P ratio, setting time, temperature change during setting, setting expansion, thermal expansion and compressive strength of the investments were measured. In this experiment, magnesia clinker and mono ammonium phosphate were used as binder, and particle size and distribution of silica sand were classified for convinence into 10 categories. The main results obtained from this investigation were summerized as follows. 1. W/P ratio decreased with increase of particle size and evenness in distribution of sand grain. 2. Setting time decreased with increase of evenness in distribution of sand grain, and temperature during setting increased with evenness in distribution of sand grain. 3. Setting expansion decreased with increase of particle size, while it increased with evenness in distribution of sand grain. 4. Thermal expansion decreased with increase of particle size. 5. Compressive strength increased with increase of particle size and evenness in distribution of sand grain. From above results, G.F.N. 250 sand which contains 30% of 50-100 mesh could be recommended for investment casting.

• Journal of Electrical Engineering and Technology
• /
• v.9 no.2
• /
• pp.415-422
• /
• 2014

This paper presents a new approach to solve the multi area unit commitment problem (MAUCP) using an evolutionary programming based particle swarm optimization (EPPSO) method. The objective of this paper is to determine the optimal or near optimal commitment schedule for generating units located in multiple areas that are interconnected via tie lines. The evolutionary programming based particle swarm optimization method is used to solve multi area unit commitment problem, allocated generation for each area and find the operating cost of generation for each hour. Joint operation of generation resources can result in significant operational cost savings. Power transfer between the areas through the tie lines depends upon the operating cost of generation at each hour and tie line transfer limits. Case study of four areas with different load pattern each containing 7 units (NTPS) and 26 units connected via tie lines have been taken for analysis. Numerical results showed comparing the operating cost using evolutionary programming-based particle swarm optimization method with conventional dynamic programming (DP), evolutionary programming (EP), and particle swarm optimization (PSO) method. Experimental results show that the application of this evolutionary programming based particle swarm optimization method has the potential to solve multi area unit commitment problem with lesser computation time.

• Journal of the Korean Ceramic Society
• /
• v.46 no.6
• /
• pp.592-595
• /
• 2009

Nanosize NiO powder was prepared by mixing acidic nickel nitrate with basic nickel carbonate. The particle size and morphology of NiO were mainly governed by the mole ratio of the nitrate to the carbonate. The effects were studied by DSC, XRD, FTIR, and SEM. Heat treatment conditions influence the particle size distribution of produced NiO powder extensively for the case of 3N7C (3 moles of the nitrate and 7 moles of the carbonate) and 4N6C, but only slightly for 1N9C and 2N8C. Uniform pseudospherical NiO particles were obtained in $50{\sim}70$ nm for 1N9C and $30{\sim}60$ nm for 2N8C by calcination at $750{^{\circ}C}$ for 2 h.

• Journal of Powder Materials
• /
• v.22 no.4
• /
• pp.278-282
• /
• 2015

The GaN-powder scrap generated in the manufacturing process of LED contains significant amounts of gallium. This waste can be an important resource for gallium through recycling of scraps. In the present study, the influence of annealing temperatures on the structural properties of GaN powder was investigated when the waste was recycled through the mechanochemical oxidation process. The annealing temperature varied from $200^{\circ}C$ to $1100^{\circ}C$ and the changes in crystal structure and microstructure were studied. The annealed powder was characterized using various analytical tools such as TGA, XRD, SEM, and XRF. The results indicate that GaN structure was fully changed to $Ga_2O_3$ structure when annealed above $900^{\circ}C$ for 2 h. And, as the annealing temperature increased, crystallinity and particle size were enhanced. The increase in particle size of gallium oxide was possibly promoted by powder-sintering which merged particles to larger than 50 nm.

• Korean Journal of Materials Research
• /
• v.9 no.3
• /
• pp.269-273
• /
• 1999

Polycrystalline silicon films are generally deposited by LPCVD, utilizing the thermal decomposition of $SiH_4$ gas. When silicon wafers are loaded into the furnace in order to reduce oxygen concentration of the films, we flow 20slm N, gas from top to bottom of the furnace, and then deposit films of $1000\AA$ thickness to measure oxygen concen­tration by SIMS. As a consequence of SIMS, we obtain oxygen concentration in films lower about 30 times than that of films deposited with 20slm $N_2$ gas-flow through the short injector in the hatch of furnace. In our long injector system, we estimate a reproducibility by uniformity, particle, and Rs of the deposited films.

• Journal of Korean Society for Atmospheric Environment
• /
• v.29 no.2
• /
• pp.211-216
• /
• 2013

For diffusion limited cluster agglomerates the ratio of the mobility radius to the radius of gyration $R_m/R_g$ vs. N and the ratio of the mobility radius to the radius of primary particle $R_m$/a are determined using experimental data obtained with DMA-APM and tandem DMA over a range of Knudsen numbers extending into the transition region where there is a lack of data. It was found that in slip regime with the number of primary particles between 100 and 400, datapoints are found to be between the two asymptotic lines for the continuum and free molecular regimes as those datapoints are plotted in both $R_m/R_g$ vs. N and $R_m$/a vs. N.

• Korean Journal of Materials Research
• /
• v.9 no.4
• /
• pp.392-397
• /
• 1999

The tensile strength and water resistance of ADC12 alloy matrix composites reinforced with saffil/ceraklwool and saffil/Si particle prepared by squeeze casting have been investigated in room temperature and $250^{\circ}C$. Adhesive and scuffing wear phenomena was studied when load was changed to 10~40N and wear velocity was 2.0m/s at room temperature and $250^{\circ}C$. Generally, the morphology of tensile fractured surface revealed dimple pattern which implies ductile fracture of the composites. However, cleavage fracture was also observed in case of ADC12 alloy based saffil/Si particle composite. The maximum tensile strength of 320MPa was obtained in ADC12 alloy based composites reinforced by saffil/cerakwool(5:5) preformed fibers. In the results of dry wear test, it was observed that scuffing was occurred at 40N in room temperature and 30N for $250^{\circ}C$.

• Korean Journal of Materials Research
• /
• v.14 no.11
• /
• pp.790-794
• /
• 2004

Ultra-fine Copper particles for a conductive paste in electric-electronic field were prepared using wet-reduction process with hydrazine hydrate ($N_{2}H_4{\cdot}H_{2}O$) as a reductor. The effect of reaction conditions such as the amount of dispersion ($Na_{4}O_{7}P_2{\cdot}10H_{2}O$) and reductor ($N_{2}H_4{\cdot}H_{2}O$) on the particle size and shape for the prepared Cu powders was investigated. The quantity of dispersion and reductor varied from 0 to 0.0025 M and from 5 to 40 ml at a reaction temperature of $70^{\circ}C$, respectively. The particle size, shape, and structure for the obtained Cu particles were characterized by means of XRD, SEM, TEM, EDS and TGA. The aggregation of Cu particles was reduced with relatively increasing of the amount of dispersion at fixed other reaction conditions. The smaller Cu particle with size of approximately 300nm was obtained from 0.032 M $CuSO_4$ with adding of 0.0025 M $Na_{4}O7P_2{\cdot}10H_{2}O$ and 40ml $N_{2}H_4{\cdot}H_{2}O$ at a reaction temperature of $70^{\circ}C$.