• 제목/요약/키워드: multicomponent

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Monitoring observation of PG0934+013 using The Southern African Large Telescope

  • Park, Dawoo;Woo, Jong-Hak;Romero-Colmenero, Encarni;Crawford, Steven M.;Barth, Aaron J.;Pei, Liuyi
    • 천문학회보
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    • 제38권2호
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    • pp.54-54
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    • 2013
  • We performed spectroscopic and photometric monitoring observations of a QSO, PG0934+013 for a reverberation-mapping analysis, using the 9-m Southern African Large Telescope (SALT) for spectroscopy and the 2-m Faulkes Telescope North and the South for photometry. The monitoring campaign was carried out for 5 month between December 2012 to April 2013, providing 20 spectroscopic epochs and ~40 photometric epochs. Based on the obtained spectra, which typically have a signal-to-noise ratio to 30-60, we performed multicomponent decomposition using various components, i.e., power-law continuum, FeII emission complex, and broad and narrow emission lines, to properly measure the Hbeta line flux. After a flux normalization using [O III] 5007 line luminosity, we obtained a rms spectrum from all epochs, which shows clear variability of Hbeta line. We find that Hbeta line flux decreases by ~20% during the monitoring period while the continuum flux obtained from the aperture photometry based on the imaging data, shows similar variability. The current Hbeta light curve shows monotonic decrease and a reliable cross correlation analysis between Hbeta and continuum light is difficult. Nevertheless, we obtained a preliminary lag measurements as ~24 light days.

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Experimental and Theoretical Studies on the Tautomerism in 2-Aminopyridines and 2(1H)-Pyridinones: Synthesis of 2-Amino-4-aryl-3-cyano-6-(3,4-dimethoxyphenyl)pyridines and 4-Aryl-3-cyano-6-(3,4-dimethoxyphenyl)-2(1H)-pyridinones

  • Davoodnia, Abolghasem;Attar, Paria;Morsali, Ali;Eshghi, Hossein;Tavakoli-Hoseini, Niloofar;Khadem, Shahriar
    • Bulletin of the Korean Chemical Society
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    • 제32권6호
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    • pp.1873-1878
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    • 2011
  • Under solvent-free conditions and in one-pot, a series of 2-amino-4-aryl-3-cyano-6-(3,4-dimethoxyphenyl)-pyridines and 4-aryl-3-cyano-6-(3,4-dimethoxyphenyl)-2(1H)-pyridinones were prepared using 3,4-dimethoxyacetophenone, an aldehyde, malononitrile (or ethyl cyanoacetate), and ammonium acetate in the presence of 3-methyl-1-(4-sulfonylbutyl)imidazolium hydrogen sulfate $[HO_3S(CH_2)_4MIM][HSO_4]$ (a Br${\o}$nsted acidic ionic liquid) as the catalyst in very short reaction time. The preference for the formation of more stable tautomers was consistence with the theoretical calculation using the Gaussian 03 program at the B3LYP hybrid density functional level.

Fabrication of Ti Doped ZnO Nanostructures by Atomic Layer Deposition and Block Copolymer Templates

  • Kwack, Won-Sub;Zhixin, Wan;Choi, Hyun-Jin;Jang, Seung-Il;Lee, Woo-Jae;Kwon, Se-Hun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.452-452
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    • 2013
  • ZnO is one of the most attractive transparent conductive oxide (TCO) films because of low toxicity, a wide band gap material and relatively low cost. However, the electrical conductivity of un-doped ZnO is too high to use it as TCO films in practical application. To improve electrical properties of undoped ZnO, transition metal (TM) doped ZnO films such as Al doped ZnO or Ti doped ZnO have been extensively studied. Here, we prepared Ti doped ZnO thin films by atomic layer deposition (ALD) for the application of TCO films. ALD was used to prepare Ti-doped ZnO thin films due to its inherent merits such as large area uniformity, precise composition control in multicomponent thin films, and digital thickness controllability. Also, we demonstrated that ALD method can be utilized for fabricating highly ordered freestanding nanostructures of Ti-doped ZnO thin films by combining with BCP templates, which can potentially used in the photovoltaic applications.

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Design and Synthesis of Multi Functional Noble Metal Based Ternary Nitride Thin Film Resistors

  • Kwack, Won-Sub;Choi, Hyun-Jin;Lee, Woo-Jae;Jang, Seung-Il;Kwon, Se-Hun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.93-93
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    • 2013
  • In recent years, multifunctional ternary nitride thin films have received extenstive attention due to its versatility in many applications. In particular, noble metal based ternary nitride thin films showed a promising properties in the application of Multifunctional heating resistor films because its good electrical properties and excellent resistance against oxidation and corrosion. In this study, we prepared multifunctional noble metal based ternary nitride thin films by atomic layer deposition (ALD) and plasma-enhanced ALD (PEALD) method. ALD and PEALD techniques were used due to their inherent merits such as a precise composition control and large area uniformity, which is very attractive for preparing multicomponent thin films on large area substrate. Here, we will demonstrate the design concept of multifunctional noble metal based ternary thin films. And, the relationship between microstructural evolution and electrical resistivity in noble metal based ternary thin films will be systemically presented. The useful properties of noble metal based ternary thin films including anti-corrosion and anti-oxidation will be discussed in terms of hybrid functionality.

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Nanotechnology in Biodevices

  • Choi, Jeong-Woo;Oh, Byung-Keun;Kim, Young-Kee;Min, Jun-Hong
    • Journal of Microbiology and Biotechnology
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    • 제17권1호
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    • pp.5-14
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    • 2007
  • Nanotechnology is the creation and utilization of materials, devices, and systems through the control of matter on the nanometer. The technology has been applied to biodevices such as bioelectronics and biochips to improve their performances. Nanoparticles, such as gold (Au) nanoparticles, are the most widely used of the various other nanotechnologies for manipulation at the nanoscale as well as nanobiosensors. The immobilization of biomolecules is playing an increasingly important role in the development of biodevices with high performance. Nanopatteming technology, which is able to increase the density of chip arrays, offers several advantages, including cost lowering, simultaneous multicomponent detection, and the efficiency increase of biochemical reactions. A microftuidic system incorporated with control of nanoliter of fluids is also one of the main applications of nanotechnologies. This can be widely utilized in the various fields because it can reduce detection time due to tiny amounts of fluids, increase signal-to-noise ratio by nanoparticles in channel, and detect multi-targets simultaneously in one chamber. This article reviews nanotechnologies such as the application of nanoparticles for the detection of biomolecules, the immobilization of biomolecules at nanoscale, nanopatterning technologies, and the microfluidic system for molecular diagnosis.

Fragility assessment of RC-MRFs under concurrent vertical-horizontal seismic action effects

  • Farsangi, Ehsan Noroozinejad;Tasnimi, Abbas Ali;Mansouri, Babak
    • Computers and Concrete
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    • 제16권1호
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    • pp.99-123
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    • 2015
  • In this study, structural vulnerability of reinforced concrete moment resisting frames (RC-MRFs) by considering the Iran-specific characteristics is investigated to manage the earthquake risk in terms of multicomponent seismic excitations. Low and medium rise RC-MRFs, which constitute approximately 80-90% of the total buildings stock in Iran, are focused in this fragility-based assessment. The seismic design of 3-12 story RC-MRFs are carried out according to the Iranian Code of Practice for Seismic Resistant Design of Buildings (Standard No. 2800), and the analytical models are formed accordingly in open source nonlinear platforms. Frame structures are categorized in three subclasses according to the specific characteristics of construction practice and the observed seismic performance after major earthquakes in Iran. Both far and near fields' ground motions have been considered in the fragility estimation. An optimal intensity measure (IM) called Sa, avg and beta probability distribution were used to obtain reliable fragility-based database for earthquake damage and loss estimation of RC buildings stock in urban areas of Iran. Nonlinear incremental dynamic analyses by means of lumped-parameter based structural models have been simulated and performed to extract the fragility curves. Approximate confidence bounds are developed to represent the epistemic uncertainties inherent in the fragility estimations. Consequently, it's shown that including vertical ground motion in the analysis is highly recommended for reliable seismic assessment of RC buildings.

기계적 합금방법으로 제조한 극초미세 조직의 W-Cu 복합분말의 금속사출성형 연구 (Metal Injection Molding of Nanostructured W-Cu Composite Powders Prepared by Mechanical Alloying)

  • 김진천
    • 한국분말재료학회지
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    • 제5권2호
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    • pp.145-153
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    • 1998
  • W-Cu alloy is attractive to thermal managing materials in microelectronic devices because of its good thermal properties. The metal injection molding (MIM) of W-Cu systems can satisfy the need for mass production of the complex shaped W-Cu parts in semiconductor devices. In this study, the application of MIM process of the mechanically alloyed (MA) W-Cu composite powders, which had higher sinterability were investigated. The MA W-Cu powders and reduction treated (RT) powders were injected by using of the multicomponent binder system. The multi-stage debinding cycles were adopted in $N_2$ and $H_2$ atmosphere. The isostatic repressing treatment was carried out in order to improve the relative density of brown parts. The brown part of RT W-Cu composite powder sintered at 110$0^{\circ}C$ had shown the higher sinterability compared to that of MA powder. The relative sintered density of all specimens increased to 96% by sintering at 120$0^{\circ}C$ for 1 hour. The relationship between green density and the sintering behavior of MA W-Cu composite powder was analyzed and discussed on the basis of the nanostructured characteristics of the MA W-Cu composite powder.

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Reference Electrode at Molten Salt: A Comparative Analysis of Electroceramic Membranes

  • Yoon, Seokjoo;Kang, Dokyu;Sohn, Sungjune;Park, Jaeyeong;Lee, Minho;Choi, Sungyeol
    • 방사성폐기물학회지
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    • 제18권2호
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    • pp.143-155
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    • 2020
  • A reference electrode is important for controlling electrochemical reactions. Evaluating properties such as the reduction potential of the elements is necessary to optimize the electrochemical processes in pyroprocessing, especially in a multicomponent environment. In molten chloride systems, which are widely used in pyroprocessing, a reference electrode is made by enclosing the silver wire and molten salt solution containing silver chloride into the membranes. However, owing to the high temperature of the molten salt, the choice of the membrane for the reference electrode is limited. In this study, three types of electroceramic, mullite, Pyrex, and quartz, were compared as reference electrode membranes. They are widely used in molten salt electrochemical processes. The potential measurements between the two reference electrode systems showed that the mullite membrane has potential deviations of approximately 50 mV or less at temperatures higher than 650℃, Pyrex at temperatures lower than 500℃, and quartz at temperatures higher than 800℃. Cyclic voltammograms with different membranes showed a significant potential shift when different membranes were utilized. This research demonstrated the uncertainties of potential measurement by a single membrane and the potential shift that occurs because of the use of different membranes.

분무열분해법에의한 형광체 입자의 제조 (Preparation of Fluorescence Particles by Spray Pyrolysis)

  • 강윤찬;정경렬;박승빈
    • Korean Chemical Engineering Research
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    • 제44권3호
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    • pp.235-242
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    • 2006
  • 분무 열분해법이란 전구체를 용해시킨 용액을 수 마이크론에서 수십 마이크론 크기의 액적으로 분무한 후, 용매를 증발시키고 석출된 전구체를 열분해하여, 입자 및 필름을 제조하는 공정이다. 이 분무 열분해법의 핵심 요소는 전구체,용매, 액적 제조 그리고 분해 반응기 등 4가지이다. 이 4가지 요소의 적절한 조합에 의해서 현존하는 거의 대부분의 입자와 필름을 제조할 수 있는 범용성이 높은 기술이다. 현재 기술 수준으로는 상업적인 성공을 거두기는 힘들지만 향후 다성분계의 입자나 필름, 혹은 고기능성 입자의 제조에 응용될 경우 매우 유용한 기술로 각광을 받을 전망이다. 본 총설에서는 이 분문 열분해법을 이용해서 만들어지는 입자 중에서 주로 형광체를 중심으로 지금까지 개발된 다양한 분무 열분해 공정 기술을 소개한다

벌크 비정질 Zr-Ti-Cu-Ni-Be 합금의 고온 압축 변형 특성 (High Temperature Compressive Deformation Behavior of the Bulk Metallic Glass Zr-Ti-Cu-Ni-Be Alloy)

  • 이광석;하태권;안상호;장영원
    • 소성∙가공
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    • 제10권7호
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    • pp.565-572
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    • 2001
  • It is well known that a multicomponent $Zr_{4l.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ bulk metallic glass alloy shows good bulk glass forming ability due to its high resistance to crystallization in the undercooled liquid state. DSC and XRD have been performed to confirm the amorphous structure of the master alloy. To investigate the mechanical properties and deformation behavior of the bulk metallic $Zr_{4l.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ alloy, a series of compression tests has been carried out at the temperatures ranging from $351^{\circ}C$ to $461^{\circ}C$at the various initial strain rates from $2{\times}10^4s^1$ to $2{\times}10^2s^1$. Three types of nominal stress-strain curves have been identified such as linear stress-strain relationship meaning fracture at maximum stress, plastic deformation including stress overshoot and steady-state flow, plastic deformation without stress overshoot depending on the strain rate and test temperature. Also DSC analysis for the compressed specimens was carried out to investigate the change of structure, thermal stability and crystallization behavior for the various test conditions.

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