High Temperature Compressive Deformation Behavior of the Bulk Metallic Glass Zr-Ti-Cu-Ni-Be Alloy

벌크 비정질 Zr-Ti-Cu-Ni-Be 합금의 고온 압축 변형 특성

  • 이광석 (포항공과대학교 항공재료연구센터) ;
  • 하태권 (포항공과대학교 항공재료연구센터) ;
  • 안상호 (포항산업과학연구원 재료공정연구센터) ;
  • 장영원 (포항공과대학교 항공재료연구센터)
  • Published : 2001.12.01

Abstract

It is well known that a multicomponent $Zr_{4l.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ bulk metallic glass alloy shows good bulk glass forming ability due to its high resistance to crystallization in the undercooled liquid state. DSC and XRD have been performed to confirm the amorphous structure of the master alloy. To investigate the mechanical properties and deformation behavior of the bulk metallic $Zr_{4l.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ alloy, a series of compression tests has been carried out at the temperatures ranging from $351^{\circ}C$ to $461^{\circ}C$at the various initial strain rates from $2{\times}10^4s^1$ to $2{\times}10^2s^1$. Three types of nominal stress-strain curves have been identified such as linear stress-strain relationship meaning fracture at maximum stress, plastic deformation including stress overshoot and steady-state flow, plastic deformation without stress overshoot depending on the strain rate and test temperature. Also DSC analysis for the compressed specimens was carried out to investigate the change of structure, thermal stability and crystallization behavior for the various test conditions.

Keywords

References

  1. Appl. Phys. Lett v.63 A highly processable metallic glass: $Zr_{41.2} Ti_{13.8} Cu_{12.5} Ni_{10} Be_{22.5}$ A. Peker;W. L. Johnson
  2. Nature v.187 W. Klement;R. Willens;P. Duwez
  3. J. Appl. Phys. v.46 Mechanical behavior of metallic glasses J. J. Gilman
  4. Mater. Sci. Eng. v.13 Compressive plastic deformation of a bulk metallic glass C. A. Pampillo;H. S. Chen
  5. Materials Transactions JIM v.32 Mg-Cu-Y bulk amorphous alloys with high tensile strength produced by a high-pressure die casting method A. Inoue;T. Nakamura;N. Nishiyama;T. Masumoto
  6. Materials Transactions JIM v.31 Zr-Al-Ni amorphous alloys with high glass transition temperature and significant supercooled liquid region A. Inoue;T. Zhang;T. Masumoto
  7. Materials Transactions JIM v.32 Amorphous Zr-Al-TM(TM=Co, Ni, Cu) alloys with significant supercooled liquid region of over 100K T. Zhang;A. Inoue;T. Masumoto
  8. Materials Transactions JIM v.36 Preparation of bulky amorphous Zr-Al-Co-Ni-Cu alloys by copper mold casting and their thermal and mechanical properties A. Inoue;T, Zhang;T. Masumoto
  9. Materials Transactions JIM v.38 Effect of oxygen impurity on crystallization of an undercooled bulk glass forming Zr-Ti-Cu-Ni-Al alloy X. H. Lin;W. L. Johnson;W. K. Rhim
  10. Acta Mater v.46 Workability of the supercooled liquid in the $Zr_{65}Al_{10}Ni_{10}Cu_{15}$ bulk metallic glass Y. Kawamura;T. Shibata;A. Inoue;T. Masumoto
  11. Scipta Mater v.39 Superplasticity in $Pd_{40}Ni_{40}P_{20}$metallic glass Y. Kawamura;T. Nakamura;A. Inoue
  12. Scipta Mater v.40 Superplastic behavior of a Zr-10Al-5Ti-17.9Cu-14.6Ni metallic glass in the supercooled liquid region T. G. Nieh;T. Mukai;C. T. Liu;J. Wadsworth
  13. Scripta Mater v.43 Newtonian flow of $Zr_{55}Cu_{30}Al_{10}Ni_{5}$ bulk metallic glassy alloys A. Reger-Leonhard;M. Heilmaier;J. Eckert
  14. Scripta Matall v.30 Quasi-static constitutive behavior of $Zr_{41.2} Ti_{13.8} Cu_{12.5} Ni_{10} Be_{22.5}$ bulk amorphous alloys H. A. Bruck;T. Christman;A. J. Rosakis;W. L. Johnson
  15. Metals and Materials International v.7 Nanocrystallization and high tensile strength of amorphous Zr-Al-Ni-Cu-Ag alloys T. K. Han;S. J. Kim;Y. S. Yang;A. Inoue;Y. H. Kim;I. B. Kim