• 제목/요약/키워드: molecular distribution

검색결과 1,401건 처리시간 0.024초

Influence of porosity and axial preload on vibration behavior of rotating FG nanobeam

  • Ehyaei, Javad;Akbarshahi, Amir;Shafiei, Navvab
    • Advances in nano research
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    • 제5권2호
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    • pp.141-169
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    • 2017
  • In this paper, a nanobeam connected to a rotating molecular hub is considered. The vibration behavior of rotating functionally graded nanobeam based on Eringen's nonlocal theory and Euler-Bernoulli beam model is investigated. Furthermore, axial preload and porosity effect is studied. It is supposed that the material attributes of the functionally graded porous nanobeam, varies continuously in the thickness direction according to the power law model considering the even distribution of porosities. Porosity at the nanoscopic length scale can affect on the rotating functionally graded nanobeams dynamics. The equations of motion and the associated boundary conditions are derived through the Hamilton's principle and generalized differential quadrature method (GDQM) is utilized to solve the equations. In this paper, the influences of some parameters such as functionally graded power (FG-index), porosity parameter, axial preload, nonlocal parameter and angular velocity on natural frequencies of rotating nanobeams with pure ceramic, pure metal and functionally graded materials are examined and some comparisons about the influence of various parameters on the natural frequencies corresponding to the simply-simply, simplyclamped, clamped-clamped boundary conditions are carried out.

New insights about coke deposition in methanol-to-DME reaction over MOR-, MFI- and FER-type zeolites

  • Migliori, Massimo;Catizzone, Enrico;Aloise, Alfredo;Bonura, Giuseppe;Gomez-Hortiguela, Luis;Frusteri, Leone;Cannilla, Catia;Frusteri, Francesco;Giordano, Girolamo
    • Journal of Industrial and Engineering Chemistry
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    • 제68권
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    • pp.196-208
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    • 2018
  • The effect of channel-system of zeolite on methanol-to-DME reaction was studied. Results revealed that channels size and topology affect catalyst lifetime, type and location of coke precursors. FER and MFI showed the best resistance towards coke deposition, whilst fast deactivation was observed on MOR. Although the higher concentration and strength of acid sites, FER structure formed a lower coke amount, preferably located within the pores, while coke cluster deposited on the external surface of MOR. Analysis of acid sites distribution and strength was performed during deactivation-regeneration process. Coke location assessment was also supported by molecular simulations.

HTPB/AP/Zr 추진제의 연소 특성 (Combustion Characteristics of HTPB/AP/Zr Propellant)

  • 민병선;현형수;임유진
    • 한국추진공학회지
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    • 제9권2호
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    • pp.9-16
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    • 2005
  • HTPB/AP의 성능을 이론적 계산에 의해 분석한 결과, Zr 함유 추진제는 Al 추진제보다 비추력이 낮은데 그 이유는 화염온도가 낮고, Zr 산화물의 분자량이 크기 때문이었다. HTPB/AP/Zr 추진제에서 Zr의 입도가 작을수록 연소속도가 증가하며, 입도가 작은 $2{\mu}m$ Zr은 함량이 증가할수록 금속화염으로부터 연소표면으로 전달되는 열량이 증가하여 연소 속도가 빨라지는 것으로 나타났다. 150nm 크기의 Al을 HTPB/AP/Zr 추진제에 적용하면 연소 속도가 증가하지만, 연소속도 증진 효과가 매우 좋은 Butacene 및 $1{\mu}m$ AP가 함께 함유된 추진제에서는 AP의 입도 분포의 영향에 의해 nano Al으로 인하여 연소속도가 감소할 수도 있다는 것을 알게 되었다.

Benthic dinoflagellates in Korean waters

  • Lim, An Suk;Jeong, Hae Jin
    • ALGAE
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    • 제36권2호
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    • pp.91-109
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    • 2021
  • The occurrence of benthic dinoflagellates, many of which are known to be toxic, is a critical concern for scientists, government officers, and people in the aquaculture, dining, and tourism industries. The interest in these dinoflagellates in countries with temperate climate is increasing because tropical or subtropical species introduced into temperate waters by currents are able to survive the winter season in the new environment owing to global warming. Recently, several species from the benthic dinoflagellate genera Amphidinium, Coolia, Ostreopsis, Gambierdiscus, and Prorocentrum have been reported in the waters of the South and East Sea of Korea. The advent of the benthic dinoflagellates in Korean waters is especially important because raw or slightly cooked seaweeds, which may harbor these benthic dinoflagellates, as well as raw fish, which can be potentially intoxicated by phytotoxins produced by some of these benthic dinoflagellates, are part of the daily Korean diet. The recent increase in temperature of Korean coastal waters has allowed for the expansion of benthic dinoflagellate species into these regions. In the present study, we reviewed the species, distribution, and toxicity of the benthic dinoflagellates that have been reported in Korean waters. We also provided an insight into the ecological and socio-economic importance of the occurrence of benthic dinoflagellates in Korean waters.

Kinetic Biodegradation of Polycyclic Aromatic Hydrocarbons for Five Different Soils under Aerobic Conditions in Soil Slurry Reactors

  • Ha, Jeong Hyub;Choi, Suk Soon
    • 공업화학
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    • 제32권5호
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    • pp.581-588
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    • 2021
  • In this study, soil slurry bioreactors were used to treat soils containing 16 polycyclic aromatic hydrocarbons (PAHs) for 35 days. Five different soil samples were taken from manufactured gas plant (MGP) and coal tar disposal sites. Soil properties, such as carbon content and particle distribution, were measured. These properties were significantly correlated with percent biodegradation and degradation rate. The cumulative amount of PAH degraded (P), degradation rate (Km), and lag phase (𝜆) constants of PAHs in different MGP soils for 16 PAHs were successfully obtained from nonlinear regression analysis using the Gompertz equation, but only those of naphthalene, anthracene, acenaphthene, fluoranthene, chrysene, benzo[k]fluoranthene, benzo(a)pyrene, and benzo(g,h,i)perylene are presented in this study. A comparison between total non-carcinogenic and carcinogenic PAHs indicated higher maximum amounts of PAH degraded in the former than that in the latter owing to lower partition coefficients and higher water solubilities (S). The degradation rates of total non-carcinogenic compounds for all soils were more than four times higher than those of total carcinogenic compounds. Carcinogenic PAHs have the highest partitioning coefficients (Koc), resulting in lower bioavailability as the molecular weight (MW) increases. Good linear relationships of Km, 𝜆, and P with the octanol-water partitioning coefficient (Kow), MW, and S were used to estimate PAH remaining, lag time, and biodegradation rate for other PAHs.

바인더의 공중합체 조성에 따른 안료잉크의 발색성 및 견뢰도 연구 (Color Strength and Fastness of Pigment Ink with Various Binder Monomer Compositions)

  • 권웅;이민규;정의경;배진석
    • 한국염색가공학회지
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    • 제30권4호
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    • pp.256-263
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    • 2018
  • The binder polymers for digital textile printing(DTP) pigment inks were prepared using miniemulsion polymerization with various monomer compositions to study effects of monomer compositions on particle size distribution, average molecular weight, Tg, and color strength and rubbing fastness of the dyed fabrics with the prepared binder based pigment ink. The monomers used were MMA(Methyl methacrylate), BA(Butyl acrylate), MAA(Methacrylic acid), NMA(N-methylol acrylamide), NEA(N-ethylol acrylamide) and the ratios of the monomers were changed. The particle size was the smallest with 136nm when the MMA to BA weight ratio was 4:16 and the largest with 290nm when the MMA, BA, MAA, NEA ratio was 2.5:17:0.25:0.25. However, the glass transition temperature was lowest with $-41.90^{\circ}C$ and the color strength and rubbing fastness of the resulting sample were the best when the MMA, BA, MAA, NEA ratio was used. This suggested that the introduction of the NEA monomer to the binder polymer for the pigment ink could be an efficient way to enhance the rubbing fastness of the DTP pigment inks present.

Genomic Variations of Rice Regenerants from Tissue Culture Revealed by Whole Genome Re-Sequencing

  • Qin, Yang;Shin, Kong-Sik;Woo, Hee-Jong;Lim, Myung-Ho
    • Plant Breeding and Biotechnology
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    • 제6권4호
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    • pp.426-433
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    • 2018
  • Plant tissue culture is a technique that has invariably been used for various purposes such as obtaining transgenic plants for crop improvement or functional analysis of genes. However, this process can be associated with a variety of genetic and epigenetic instabilities in regenerated plants, termed as somaclonal variation. In this study, we investigated mutation spectrum, chromosomal distributions of nucleotide substitution types of single-nucleotide polymorphisms (SNPs) and insertions/deletions (InDels) by whole genome re-sequencing between Dongjin and Nipponbare along with regenerated plants of Dongjin from different induction periods. Results indicated that molecular spectrum of mutations in regenerated rice against Dongjin genome ranged from $9.14{\times}10^{-5}$ to $1.37{\times}10^{-4}$ during one- to three-month callus inductions, while natural mutation rate between Dongjin and Nipponbare genomes was $6.97{\times}10^{-4}$. Non-random chromosome distribution of SNP and InDel was observed in both regenerants and Dongjin genomes, with the highest densities on chromosome 11. The transition to transversion ratio was 2.25 in common SNPs of regenerants against Dongjin genome with the highest C/T transition frequency, which was similar to that of Dongjin against Nipponbare genome.

Thermoelastoplastic response of FGM linearly hardening rotating thick cylindrical pressure vessels

  • Ebrahimi, Tayebeh;Nejad, Mohammad Zamani;Jahankohan, Hamid;Hadi, Amin
    • Steel and Composite Structures
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    • 제38권2호
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    • pp.189-211
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    • 2021
  • An analytical solution is presented to analyze the thermoelastoplastic response of a rotating thick-walled cylindrical pressure vessel made of functionally graded material (FGM). The analysis is based on Tresca's yield condition, its associated flow rule and linear strain hardening material behaviour. The uncoupled theory of thermoelasticity is used, and the plane strain condition is assumed. The material properties except for Poisson's ratio, are assumed to vary nonlinearly in the radial direction. Elastic, partially plastic, fully plastic, and residual stress states are investigated. The heat conduction equation for the one-dimensional problem in cylindrical coordinates is used to obtain temperature distribution in the vessel. It is assumed that the inner surface is exposed to an airstream and that the outer surface is exposed to a uniform heat flux. Tresca's yield criterion and its associated flow rule are used to formulate six different plastic regions for a linearly hardening condition. All these stages are studied in detail. It is shown that the thermoelastoplastic stress response of a rotating FGM pressure vessel is affected significantly by the nonhomogeneity of the material and temperature gradient. The results are validated with those of other researchers for appropriate values of the system parameters and excellent agreement is observed.

Symplocarpus koreanus (Araceae; Orontioideae), a new species based on morphological and molecular data

  • LEE, Joon Seon;KIM, Seon-Hee;KIM, Yongsung;KWON, Youl;YANG, JiYoung;CHO, Myong-Suk;KIM, Hye-Been;LEE, Sangryong;MAKI, Masayuki;KIM, Seung-Chul
    • 식물분류학회지
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    • 제51권1호
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    • pp.1-9
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    • 2021
  • Symplocarpus koreanus (Araceae; Orontioideae) from Korea is described as new. Symplocarpus koreanus has long been considered to be conspecific with S. renifolius in Japan, but phylogenetic, morphological, and cytological data indicate its taxonomic distinction. Compared to S. renifolius, S. koreanus has a much smaller spathe and more spherical spadix with fewer, smaller flowers. Previous phylogenetic studies also suggested that S. koreanus is more closely related to nonthermogenic S. nipponicus than to S. renifolius in Japan. Like its nonthermogenic sister species, S. nipponicus, in Korea and Japan, S. koreanus is diploid (2n = 2x = 30), while S. renifolius in Japan is tetraploid (2n = 4x = 60). A detailed species description, geographical distribution, major morphological differences between the species and a dichotomous key to the species in eastern Asia are provided.

단상계 침지냉각 기술이 적용된 Li-ion계 배터리 발열특성에 관한 연구 (A Study on Heating Characteristics of Li-ion Battery Applicated Single-phase Immersion Cooling Technology)

  • 김운학;강석원;신기석
    • 한국재난정보학회 논문집
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    • 제18권1호
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    • pp.163-172
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    • 2022
  • 연구목적: Li-ion 배터리의 효율적인 열관리 기술을 확보하기 위하여 Single&-phase 침지 냉각 기술을 적용한 시스템의 실험을 통하여 적용가능성을 확인하고자 하였다. 연구방법: LG-Chem에서 생산된 JH3 파우치 셀을 사용하여 14S2P 모듈을 제조하여 미국 카길사에서 생산된 식물성계 냉각유체에 침지한 후 0.3C~1C 속도로 충방전을 시행하여 열분포를 확인하였다. 연구결과: 침지냉각 기술로 배터리 모듈을 40℃ 이하의 온도로 관리할 수 있으며, 침지액의 분자구조 변화가 없다는 결과를 도출하였다. 결론: 침지냉각 방식이 Li-ion 배터리 열관리에 적용 가능함을 확인하였다.