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Electrical and Morphology Properties of Self-Assembled Dendrimer on Au (111) Substrate (Au (111)기판에 자기조립된 덴드리머 분자의 형태와 전기적 특성에 관한 연구)

  • Jung, Kyung-Han;Shin, Hoon-Kyu;Kim, Chung-Kyun;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.120-123
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    • 2003
  • To investigate the characteristics of the single dendrimer molecule, we attempt to measure morphology and electrical properties of the self-assembled dendrimer on Au (111)substrate with SPM(scanning probe microscopy). The same self-assembly procedure was used for two different concentrations, $10{\mu}mol/ml$ and $100{\mu}mol/ml$. The case of lower concentration, we can measure the diameter and the height of the single molecule with the tapping mode AFM image. The imaged single molecules were dome shaped and the average diameter and height were 15.6 nm, 1.2 nm respectively. From these sizes, we can calculate the volume of the single molecule. The volume of the single molecule was estimated about $116nm^3$. However, that of higher concentration, it is difficult to obtain obvious image of the single molecule. To add to, I-V characteristics were investigated using STM, on which the phenomenon of negative differential resistance (NDR)was observed between 0.14 V and 0.24 V reproductively.

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Simultaneous analysis method of 89Sr and 90Sr in liquid sample using automated separation system (자동핵종분리장치를 이용한 액체시료 중 89Sr, 90Sr 동시분석법 연구)

  • Kim, Heewon;Lee, Yong-Jin;Kim, Sun-Ha;Lee, Jin-Hong;Lim, Jong-Myoung;Kim, Hyuncheol
    • Analytical Science and Technology
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    • v.33 no.6
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    • pp.274-284
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    • 2020
  • This study described the analytical method for simultaneous determination of 89Sr and 90Sr in liquid sample using automated separation system. Radiostrontium in 0.5 kg of liquid sample was concentrated as SrCO3 to reduce the volume of sample, and purified from the sample using Sr-resin 2 mL (BV, Bed volume). The behavior of Sr and interferences such as Ba, Ca and Y were estimated with various flow rate ranging from 1 to 4 mL min-1. The detailed procedure for the purification of Sr on Sr-resin was presented. The purified radiostronitum was measured in Cerenkov mode and then measured in Scintillation mode by mixing scintillation cocktail. The measured value in both modes were used to calculate the activity of 89Sr and 90Sr. The performance tests were carried out the lab-control-sample having various activity ratio of between 89Sr and 90Sr. The recovery of Sr was ranged from 68 to 94 %. The relative bias of 89Sr activity was ranged from -5 to 20 %, and it was ranged from -10 to 10 % for 90Sr.

The Effect of Reaction Temperature and Volume in the Sonolysis of 1,4-Dioxane (1,4-Dioxane의 초음파 처리시 반응 온도와 부칙의 영향)

  • Son, Hyun-Seok;Choi, Seok-Bong;Eakalak, Khan;Zoh, Kyung-Duk
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.10
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    • pp.1114-1122
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    • 2005
  • This research investigates the effects of sonication mode, reaction temperature and volume on sonolysis of 1,4-dioxane in order to increase the degradation efficiency and kinetics. The degradation efficiency in case with pulse mode was about 10 % higher than that in case with continuous mode. The degradation profiles in both cases, which were performed without the control of reaction temperature and in 1000 mL, were composed of three steps. However, 1,4-D was mainly degraded in the initiation step as the first portion and the acceleration step as the second portion. The initial step agreed with zero-order expression well, while the acceleration step could be fitted with pseudo 1st-order expression. The kinetic model in case with $5^{\circ}C$ and 300 mL conformed to pseudo 1st-order, while that in cases with $10^{\circ}C$ to $40^{\circ}C$ agreed with zero-order expression. The degradation efficiency and profile of 1,4-D in the experiment with $20^{\circ}C$ and 300 mL was higher and simpler than that in case with $20^{\circ}C$ and 1000 mL. The reaction temperature and volume influence bubble intensity, which was produced in sonication. The increase of bubble intensity induced to augment the production of OH radical in sonication.

Visibility of Internal Target Volume of Dynamic Tumors in Free-breathing Cone-beam Computed Tomography for Image Guided Radiation Therapy

  • Kauweloa, Kevin I.;Park, Justin C.;Sandhu, Ajay;Pawlicki, Todd;Song, Bongyong;Song, William Y.
    • Progress in Medical Physics
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    • v.24 no.4
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    • pp.220-229
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    • 2013
  • Respiratory-induced dynamic tumors render free-breathing cone-beam computed tomography (FBCBCT) images with motion artifacts complicating the task of quantifying the internal target volume (ITV). The purpose of this paper is to study the visibility of the revealed ITV when the imaging dose parameters, such as the kVp and mAs, are varied. The $Trilogy^{TM}$ linear accelerator with an On-Board Imaging ($OBI^{TM}$) system was used to acquire low-imaging-dose-mode (LIDM: 110 kVp, 20 mA, 20 ms/frame) and high-imaging-dose-mode (HIDM: 125 kVp, 80 mA, 25 ms/frame) FBCBCT images of a 3-cm diameter sphere (density=0.855 $g/cm^3$) moving in accordance to various sinusoidal breathing patterns, each with an unique inhalation-to-exhalation (I/E) ratio, amplitude, and period. In terms of image ITV contrast, there was a small overall average change of the ITV contrast when going from HIDM to LIDM of $6.5{\pm}5.1%$ for all breathing patterns. As for the ITV visible volume measurements, there was an insignificant difference between the ITV of both the LIDM- and HIDM-FBCBCT images with an average difference of $0.5{\pm}0.5%$, for all cases, despite the large difference in the imaging dose (approximately five-fold difference of ~0.8 and 4 cGy/scan). That indicates that the ITV visibility is not very sensitive to changes in imaging dose. However, both of the FBCBCT consistently underestimated the true ITV dimensions by up to 34.8% irrespective of the imaging dose mode due to significant motion artifacts, and thus, this imaging technique is not adequate to accurately visualize the ITV for image guidance. Due to the insignificant impact of imaging dose on ITV visibility, a plausible, alternative strategy would be to acquire more X-ray projections at the LIDM setting to allow 4DCBCT imaging to better define the ITV, and at the same time, maintain a reasonable imaging dose, i.e., comparable to a single HIDM-FBCBCT scan.

Effects of Solidification Modes on the Pit Initiation and Propagation in Austenitic Stainless Steel Weld Metals (오스테나이트계 스테인리스강 용착금속의 응고모드가 공식 생성 및 성장에 미치는 영향 x Effects of Solidification Modes on the Pit Initiation and Propagation in Austenitic Stainless Steel Weld Metals)

  • 최한신;김규영;이창희
    • Journal of Welding and Joining
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    • v.16 no.6
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    • pp.59-68
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    • 1998
  • In this study, effects of solidification modes (primary $\delta$-ferrite, primary ${\gamma}$-austenite) on the pit initiation and propagation in the 304L and 316L austenitic stainless steel weld metals were investigated. The solidification mode of weld metal was controlled by the addition of nitrogen to Ar shielding gas. Through the electrochemical experiments (potentiodynamic anodic polarization and potentiostatic time-current transient test) and metallographic examination (microstructure and elemental distribution), the following results were obtained. The more the volume content of nitrogen in the shielding gas were, the lower critical current density for passivity was observed. In comparison with weldments solidified through the primary $\delta$-ferrite solidification mode and the primary ${\gamma}$-solidification mode, the former showed higher critical pitting potential and a longer incubation time for stable pit initiation than the latter. However, in the pit propagation stage the former exhibited a faster dissolution rate than the latter. These results were believed to ee related to the distribution of alloying elements such as Cr, Mo, Ni and S.

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아트리움 공간에 있어서 화재에 의한 연기 유동에 관한 수치해석적 연구

  • 노재성;유홍선;정연태
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 1997.11a
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    • pp.43-48
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    • 1997
  • The smoke filling process for the atrium space containing a fire source is simulated using two types of deterministic fire modus: Zone model and Field model. The zone mode used is the CFAST(version 1.6) mode developed at the Building and Fire Research laboratories, NIST in the USA. The lied model is a self-developed fire field model based on Computational Fluid Dynamics(CFD) theories. This article is focused on finding out the smoke movement and temperature distribution in atrium space which is cubic in shape. A computational procedure for predicting velocity and temperature distribution in fro-induced flow is based on the solution, in finite volume method and non-staggered grid system, of 3-dimensional equations for the conservation of mass, momentum, energy, species and so forth. The fire model i. e. Zone model and Field model predicted similar results for Ire clear height and the smoke layer temperature.

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The Research about Free Piston Linear Engine Fueled with Hydrogen using Numerical Analysis (수소를 연료로 사용한 프리피스톤 리니어 엔진의 수치해석에 관한 연구)

  • Nguyen, Ba Hung;Oh, Yong-Il;Lim, Ock-Taeck
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.2
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    • pp.162-172
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    • 2012
  • This paper presents a research about free piston linear engine (FPLE) fueled with hydrogen, in which, the numerical models are built to simulate the operation during the full stroke of the engine. Dynamic model, linear alternator model and thermodynamic model are used as the numerical models to predict piston velocity, in-cylinder pressure and electric power of FPLE. The spark timing and air gap length are changed to provide information for the prediction. Beside, the heat transfer problem is also investigated in the paper. The results of research are divided by two parts, including motoring mode and firing mode. The result of motoring mode showed that there is validation between simulation and experiment for volume and pressure in cylinder. For firing mode, by increasing spark timing, the velocity of piston, peak pressure and electric power also increase respectively. Beside, when increasing air gap length, the electric power increases accordingly while the motion of piston is not symmetric. The effect of heat transfer also observed clearly by reducing of the peak pressure, velocity of piston and electric power.

Shear Transfer Strength Evaluation for Ultra-High Performance Fiber Reinforced Concrete (강섬유 보강 초고성능 콘크리트의 전단 전달 모델)

  • Lee, Ji-Hyung;Hong, Sung-Gul
    • Journal of Korean Association for Spatial Structures
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    • v.15 no.2
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    • pp.69-77
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    • 2015
  • Ultra High Performance Fiber Reinforced Concrete (UHPFRC) has a outstanding tensile hardening behaviour after a crack develops, which gives ductility to structures. Existing shear strength model for fiber reinforced concrete is entirely based on crack opening behavior(mode I) which comes from flexural-shear failure, not considering shear-slip behavior(mode II). To find out the mode I and mode II behavior on a crack in UHPFRC simultaneously, maximum shear strength of cracked UHPFRC is investigated from twenty-four push-off test results. The shear stress on a crack is derived as variable of initial crack width and fiber volume ratio. Test results show that shear slippage is proportional to crack opening, which leads to relationship between shear transfer strength and crack width. Based on the test results a hypothesis is proposed for the physical mechanics of shear transfer in UHPFRC by tensile hardening behavior in stead of aggregate interlocking in reinforced concrete. Shear transfer strength based on tensile hardening behavior in UHPFRC is suggested and this suggestion was verified by comparing direct tensile test results and push-off test results.

Dynamic Performance Simulation of the Propulsion System for the CRW Type UAV Using $SIMULINK^{\circledR}$

  • Changduk Kong;Park, Jongha;Jayoung Ki
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.499-505
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    • 2004
  • A Propulsion System of the CRW(Canard Rotor Wing) type UAV(Unmanned Aerial Vehicle) was composed of the turbojet engine to generate the propulsive exhaust gas, and the duct system including straight bent ducts, tip-jet nozzles, a master valve and a variable main nozzle for three flight modes such as lift/landing mode, low speed transition flight mode and high speed forward flight mode. In this study, in order to operate safely the propulsion system, the dynamic Performance behavior of the system was modeled and simulated using the SIMULIN $K^{ }$, which is the user-friendly GUI type dynamic analysis tool provided by MATLA $B^{ }$. In the transient performance model, the inter-component volume model was used. The performance analysis using the developed models was performed at various flight condition, valve angle positions and fuel flow schedules, and these results could set the safe flight mode transition region to satisfy the inlet temperature overshoot limitation as well as the compressor surge margin. Performance analysis results using the SIMULIN $K^{ }$ performance program were compared with them using the commercial program GSP.m GSP.

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The Study of Plasma Torch for Solid Waste Treatment (고상 廢棄物處理를 위한 플라즈마 토치에 관한 硏究)

  • Park, Hyun-Seo
    • Resources Recycling
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    • v.14 no.1
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    • pp.39-46
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    • 2005
  • A solid-state high power torch with inter-electrode insert (IEI) was developed to treat solid waste (for example, incinerated ash), and it's operation characteristics were obtained in the plasma facility test for waste treatment. According to torch test from this study, at the non-transferred mode voltage is increased by gas volume proportionally, and at the transferred mode it is not affected to voltage change. Especially arc voltage is sustained stable at the range of 10% of total Fe in slag. In addition, Electrical conductivity is 0.05~0.25${\Omega}^{-1}cm^{-1}$, torch efficiency is 75~85% and Erosion rate is 2${\times}10^{-6}~6{\times}10^{-6}$ kg/s.