• 제목/요약/키워드: mixing route

검색결과 35건 처리시간 0.022초

나노에멀젼 형성에서의 혼합 경로와 온도의 영향 (Effect of Mixing Route and Temperature on Formation of Nanoemulsions)

  • 조완구;김은희;장선일;조병옥
    • 대한화장품학회지
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    • 제42권4호
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    • pp.387-392
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    • 2016
  • 본 연구에서는 동일한 농도의 유동파라핀/ Span 80-Tween 80/ 정제수로 구성되는 조성물을 혼합 경로와 온도에 따라 형성되는 에멀젼 상태를 비교하였다. 3성분계도상에서 최종 조성에 이르는 혼합경로는 세 가지로 구성하였다. 혼합 경로에 따라서 제조된 에멀젼의 평균 입자크기는 큰 차이를 보였으며 제조 온도가 증가함에 따라서도 에멀젼의 입자크기가 감소하였다. 그러나 혼합 온도보다는 혼합 경로에 따른 영향이 더욱 컸다.

Effect of 50 ㎛ class granules on the Injection Behavior of Brushite Bone Cement Prepared via Pre-dissolution Route

  • Mun, Da Hye;Lee, Sang Cheon;Oh, Kyung-Sik
    • 한국분말재료학회지
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    • 제27권6호
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    • pp.468-476
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    • 2020
  • The bone cement used for vertebroplasty must be sufficiently injectable. The introduction of granules reduces the amount of liquid required for liquefaction, implying that higher fluidity is achieved with the same amount of liquid. By employing β-tricalcium phosphate granules with an average diameter of 50 ㎛, changes in injectability are observed based on the paste preparation route and granular fraction. To obtain acceptable injectability, phase separation must be suppressed during injection, and sufficient capillary pressure to combine powder and liquid must work evenly throughout the paste. To achieve this, the granules should be evenly distributed. Reduced injection rates are observed for dry mixing and excessive granular content, owing to phase separation. All these correspond to conditions under which the clustered granules weakened the capillary pressure. The injected ratio of the paste formed by wet mixing displayed an inverted U-type shift with the granular fraction. The mixture of granules and powder resulted in an increase in the solid volume fraction, and a decrease in the liquid limit. This resulted in the enhancement of the liquidity, owing to the added liquid. It is inferred that the addition of granules improves the injectability, provided that the capillary pressure in the paste is maintained.

Economic Analysis of Foldable Containers on the Jeju-Mokpo Container Route

  • Shin, Chang-Hoon;Kim, Sung-Nam;Den, Mariia;Wang, Gao-Feng
    • 한국항해항만학회지
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    • 제42권5호
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    • pp.331-340
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    • 2018
  • Shipping containers promote rapid development of the transport industry, and generate economic and social value. However, problems often occur due to imbalance in dynamics between exports and imports, container relocation, traffic congestion, and general shipping network designs. So, efficient and cost-effective cargo management has become crucial for the Jeju Island - Mokpo container route (JMCR) in South Korea. Dozens of recent studies reveal that collapsible or foldable containers, may become an innovative solution to problematic issues within the shipping industry. The major purpose of this study is to discuss conditions required for successful commercial application of foldable containers, based on a cost-benefit analysis precisely for the JMCR. Findings reveal usage of foldable containers can be cost-effective, if containers make a "FULL<->EMPTY" route. To the contrary, a "FULL<->FULL" route can drastically increase expenditure. However, economic analysis of actual figures for 2010-2015 indicate that benefits for Mokpo - Jeju direction are significant to cover losses on the Jeju - Mokpo line. Seasonal patterns and mixing percentages of foldable and standard containers on the route, may also produce cost-effective solutions. Sensitivity analysis reveals that benefits from using foldable containers, depend mostly on empty container shares in addition to various extra costs.

폴리머용액법 및 알루미나 seed를 도입한 YAG:Ce3+ 형광체 분말 합성 (Synthesis of YAG:Ce3+ Phosphor Powders by Polymer Solution Route and Alumina Seed Application)

  • 김용현;이상진
    • 한국분말재료학회지
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    • 제20권1호
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    • pp.37-42
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    • 2013
  • $YAG:Ce^{3+}$ phosphor powders were synthesized using a $Al_2O_3$ seed (average particle size: 5 ${\mu}m$) by the polymer solution route. PVA solution was added to the sol precursors consisting of the seed powder and metal nitrate salts for homogeneous mixing in atomic scale. All dried precursor gels were calcined at $500^{\circ}C$ and then heated at $1400^{\circ}C{\sim}1500^{\circ}C$ in $N_2/H_2$ atmosphere. The final powders were characterized by using XRD, SEM, PSA, PL and PKG test. All synthesized powders were crystallized to YAG phase without intermediate phases of YAM or YAP. The phosphor properties and morphologies of the synthesized powders were strongly dependent on the PVA content. Finally, the synthesized $YAG:Ce^{3+}$ phosphor powder heated at $1500^{\circ}C$, which is prepared from 12:1 PVA content and has an average particle size of 15 ${\mu}m$, showed similar phosphor properties to a commercial phosphor powder.

Magnetically Driven Assemblies of γ-Fe3O4 Nanoparticles into Well-Ordered Permanent Structures

  • Byun, Myunghwan
    • 한국분말재료학회지
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    • 제24권3호
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    • pp.229-234
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    • 2017
  • We report on a simple and robust route to the spontaneous assembly of well-ordered magnetic nanoparticle superstructures by irreversible evaporation of a sessile single droplet of a mixture of a ferrofluid (FF) and a nonmagnetic fluid (NF). The resulting assembled superstructures are seen to form well-packed, vertically arranged columns with diameters of $5{\sim}0.7{\mu}m$, interparticle spacings of $9{\sim}2{\mu}m$, and heights of $1.3{\sim}3{\mu}m$ The assembled superstructures are strongly dependent on both the magnitude of magnetic field and the mixing ratio of the mixture. As the magnitude of the externally applied magnetic field and the mixing ratio of the mixture increase gradually, the size and interspacing of the magnetic nanoparticle aggregations decrease. Without an externally applied magnetic field, featureless patterns are observed for the ${\gamma}-Fe_3O_4$ nanoparticle aggregations. The proposed approach may lead to a versatile, cost-effective, fast, and scalable fabrication process based on the field-induced self-assembly of magnetic nanoparticles.

Evolution of phase morphology and in-situ compatibilization of polymer blends during ultrasound-assisted melt mixing

  • Kim, Hyungsu;Ryu, Joung-Gul;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • 제14권3호
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    • pp.121-128
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    • 2002
  • A series of thermoplastic polymers and their blends were melt-processed with high intensity ultrasonic wave in an intensive mixer. For the effective transfer of ultrasonic energy, an experimental apparatus was specially designed so that polymer melt can directly contact with ultrasonic horn. It was observed that significant variations in the rheological properties of polymers occur due to the unique action of ultrasonic wave without any aid of chemical additives. It was also found that the direct sonication on immiscible polymer blends in melt state reduces the domain sizes considerably and stabilizes the phase morphology of the blends. The degree of compatibilization was strongly affected by viscosity ratio of the components and the morphology was stable after annealing in properly compatibilized blends. It is suggested that ultrasound assisted melt mixing can lead to in-situ copolymer formation between the components and consequently provide an effective route to compatibilize immiscible polymer blends.

메탄/순산소 혼합층에서 edge flame의 구조 (Structure of Edge Flame in a Methane-Oxygen Mixing Layer)

  • 최상규;김준홍;정석호;김종수
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제32회 KOSCO SYMPOSIUM 논문집
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    • pp.149-156
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    • 2006
  • Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

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메탄/순산소 혼합층에서 Edge Flame의 구조 (Structure of Edge Flame in a Methane-Oxygen Mixing Layer)

  • 최상규;김준홍;정석호;김종수
    • 한국연소학회지
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    • 제11권1호
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    • pp.19-26
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    • 2006
  • Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

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An Application of K-$\varepsilon$ Turbulence Model for Predicting Effect of a Rectanguler Obstacle with Heat Flux in a Solt-Ventilated Enclosure on Air Flow

  • 최홍림;김현태;김우중
    • 한국농공학회지
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    • 제34권E호
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    • pp.30-44
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    • 1992
  • A modification of the TEACH-like computer program based on the k-$\varepsilon$ turbulence transport was applied for predicting air mixing patterns and temperature distributions in a rectangular, slot-ventilated enclosure having obstructions ; a rectangular obstacle with heat flux, solid walls separates the passage and the pig pens, and purlins beneath the ceiling. Air flow patterns were calculated for the cases with and without the purlin, extending 300mm beneath the ceiling. Comparisons of prediction data of Randall & Battams(1976) showed air flow pattern predicted well for the case without the purlin. Heat was accumulated at the corner of the left side of the solid wall and the right-upper region of the simulated pigs. However the air distribution pattern was completely different from data for the case with the purlin. The deviation from the observation may be attributed to the difference of the geometric configuation. Exploring the cause of the deviation should be conducted in a further study. Temperature stratification was also observed due to incomplete mixing. The obstruction in the route of the inlet air jet at inlet should be avoided since most of kinetic energy dissipates at the abstacle duet to impingement.

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플라스틱 자석 혼합물의 균질도 평가방법과 균질도가 자기특성에 미치는 영향 (Evaluation Methods of Homogeneity for Feedstocks and Effect of Homogeneity on the Magnetic Properties of Plastic Magnets)

  • 이석희;최준환;문탁진;정원용
    • 한국자기학회지
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    • 제8권2호
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    • pp.86-92
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    • 1998
  • 플라스틱 자석에는 균일한 자장분포와 높은 자기특성을 얻기 위해서는 균질화된 혼합물이 요구되며, 이를 위해서는 적절한 혼합경로와 혼합물의 균질도 평가방법이 필수적이다. 본 연구에서는 Sr-ferrite/EVA 플라스틱 자석에서 혼합균질도의 평가방법과 혼합균질도가 자기특성에 미치는 영향을 조사하였다. 회분식 혼합기와 단축압출기를 이용하여 균질도가 서로 다른 혼합균질도를 조사하였다. 토크센서를 이요한 혼합시 토크변화 측정방법은 임계분말충전율 결정에는 효과적인데 반해 혼합균질도 평가에는 적합하지 않았다. 이그이방성 플라스틱 자석의 분말이방화율을 이용한 균질도 평가방법은 정밀도는 높으나, 시편제조와 측정에 고가의 장비와 필요하고 자성분말 혼합물 이외에는 이용될수 없다. 모세관 레오미터를 이용한 압출압력변화 측정방법은 정밀도가 높고 측정이 간편하여 효과적이었다. 혼합물의 균질도가 증가함에 따라 분말이방화율이 증가하였으며, 분말이방화율의 증가에 따라 잔류자속밀도는 직선적으로 증가하였다.

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