• Title/Summary/Keyword: mixed potential

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Electrochemical Characteristics of Ruthenium Oxide Electrode-Organic Electrolyte System (유기전해액에서 루테늄산화물 전극의 전기화학적 특성)

  • Doh, Chil-Hoon;Jin, Bong-Soo;Moon, Seong-In;Yun, Mun-Soo;Choi, Sang-Jin;Yug, Gyeong-Chang;Park, Jeong-Sik;Kim, Sang-Gil;Lee, Joo-Won
    • Journal of the Korean Electrochemical Society
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    • v.6 no.3
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    • pp.169-173
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    • 2003
  • Electrochemical capacitor made with metal oxide electrode uses rapid and reversible protonation/deprotonation of metal oxide material under the aqueous acidic solution, generally. Electrochemical stability window of aqueous electrolyte-type capacitor is narrow compared to that of organic electrolyte-type capacitor. Electrochemical characteristics of electrochemical capacitor made with metal oxide electrode and lithium or ammonium cation based organic electrolyte were evaluated. Electrochemical capacitor based on $RuO_2$ electrode material and 1M $LiPF_6$ in mixed solvents of EC, DEC, and EMC has anodic and cathodic specific capacitance of 145 and $142F/g-RuO_2{\cdot}nH_2O$, respectively, by using cyclic voltammetry with scan rate of 2mV/sec $g-RuO_2$ in potential range of $2.0\~4.2V(Li|Li^+))$.

Microcosm Study on BTEX and MTBE (Methyl Tert-Butyl Ether) Biodegradation under Aerobic-Anaerobic Conditions (호기/혐기성 조건에서의 BTEX 및 MTBE 동시 분해특성)

  • Oh, Inseok;Lee, Changyeol;Lee, Jongin;Kim, Jitae;Chang, Soonwoong
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.5
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    • pp.39-46
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    • 2014
  • The objectives of this study were to determine biodegradation and characteristics of BTEX and MTBE under aerovic-anaerobic conditions and evaluate the potential of natural attenuation method in denitrifying condition.. In the single-substrate experiments, all of the BTEX compounds were degraded under all the conditions. but, lower degradation of benzene and p-xylene were observed under aerobic condition due to the lack of oxygen initially supplied. In the mixed-substrate experiments, BTEX degradation was delayed compared to that in the single-substrate experiments due to a competition of the substrates. Biodegradation of MTBE was observed only under denitrifying conditions and we expected that MTBE mineralized to $CO_2$ without the accumulation of TBA. We also conducted to determine the effect of initial nitrate concentration on BTEX and MTBE degradation. At low nitrate concentration (<50 mg/L), BTEX degradations were limited by the lack of electron acceptor and BTEX degradation was inhibited at high nitrate concentration (>200 mg/L). The results in this study indicated that biotransformation could be applied to the gasoline-contaminated region under aerovic-anaerobic.

Antibacterial activity and sensory characteristic of sauce for raw fish with tea extract and garlic vinegar (차추출물과 마늘식초를 이용한 생선회용 소스의 항균활성 및 관능특성)

  • Han, Young Sun;Choi, Hye Jin;Lee, Seung Ri;Kwon, Mun-Ju;Heo, Myung Je;Jo, Nam-Gyu;Kim, Hye Young
    • Food Science and Preservation
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    • v.23 no.5
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    • pp.704-710
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    • 2016
  • This study was conducted to investigate the antibacterial activities and sensory properties of a sauce containing tea extract and garlic vineger against raw fish. The sauce was evaluated antibacterial activity against Vibrio parahaemolyticus and Vibrio vulnificus which is considered as one of the major food borne pathogens. As a result, the sauce inhibited the growth of V. parahaemolyticus and V. vulnificus distinctly. In addition, the sauce with soy sauce and Kochujang showed the restricted growth of Vibrio parahaemolyticus and Vibrio vulnificus in sliced raw flatfish. Sensory evaluations were measured by 7-point hedonic scale using sliced raw flatfish with the sauce mixed with Kochujang and soy sauce. The score of texture in the sauce with Kochujang was significantly higher than that of regular Chokochujang (p<0.05). Moreover, total preference including appearance, texture, aroma and taste were significantly higher in the sauce with soy sauce than those of regular soy sauce (p<0.05). Consequently, the soy sauce with tea extract and garlic vinegar may enhance the satisfaction of consumer and antimicrobial activity that against V. parahaemolyticus and V. vulnificus, resulting in potential reduction the outbreaks of food borne pathogens.

Influence of Paper Mill Sludge and Briquet Ash on the Growth of Zoysiagrass (제지(製紙)슬러지와 연탄재가 들잔디의 생육(生育)에 미치는 영향(影響))

  • Ku, Ja Hyeong;Kim, Tae Il;Ahn, Joo Won;Kim, Moon Kyu
    • Korean Journal of Agricultural Science
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    • v.19 no.2
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    • pp.153-160
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    • 1992
  • To investigate the potential of paper mill sludge and briquet ash as cultural media in turfgrass, zoysiagrass was grown in the mixtures prepared with paper mill sludge and briquet ash. The mixtures were consisted of sludge and briquet ash in the ratio by volume 3:1, 2:1, 1:1, 1:2, and 1:3 in the order. To compare the growth responses, some plants were grown in the medium containing sand(3), field soil(1) and peatmoss (1) by volume anti regarded as control. 1. Activated sludge mixed with sand increased plant height, fresh weight, and dry weight more than 1.5-2.0 times compared to those of the control. The highest plant growth was shown in mixtures containing 67% activated sludge. 2. Plant density per $100cm^2$ and chlorophyll content were higher in all mixtures containing activated sludge than control. 3. The growth of zoysiagrass was reduced along with the increase of non-activated sludge ratio, but no difference was found in chlorophyll content. 4. Plant height, fresh weight and dry weight were greater in activated sludge combined with sand compared to the briquet ash mixtures, but the difference of shoot density between two mixtures was not shown. 5. Even though non-activated sludge appeared not to be appropriate to the growth of seedlings, the number of tillers of plant propagated with rhizome was more increased compared to control when briquet ash content was less than 75%.

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A Clinical Study of Tonsillitis and Peritonsillar Abscess (구개편도염과 편도주위농양의 임상적 고찰)

  • 최창만;이병화;오대식;양철민;채규학
    • Korean Journal of Bronchoesophagology
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    • v.3 no.2
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    • pp.293-301
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    • 1997
  • The tonsillitis has long been one of the most common disease in the otolaryngologic field. Peritonsillar abscess occurs when bacterial infection of the tonsil spreads to the potential peritonsillar space deep behind the tonsil, and it usually occurs in patients with recurrent tonsillitis or in those with tonsillitis who have been inadequately treated. We studied retrospectively 71 patients who had been diagnosed as acute tonsillitis and 82 patients who had been diagnosed as peritonsillar abscess and had admitted in our department of the Ulsan Dong Kang Hospital from January, 1995 to September, 1997. Especially in the bacteriologic studies, we compared acute tonsillitis and peritonsillar abscess with chronic tonsillitis. The following results were obtained: 1) The sex distributions of acute tonsillitis were 47 males(66%) and 24 females(34%) cases, but 57 males(70%) and 25 females(30%) in cases of peritonsillar abscess. There were predominant in male and frequently affected in second and third decades in 53 cases(76%) of acute tonsillitis and 56 cases(68%) of peritonsillar abscess. 2) It was same found in each season. 3) The duration from onset of symptom to visit in our department was 3.92 days in cases of acute tonsillitis and 5.95 days in cases of peritonsillar abscess in average 4) The major symptoms were sore throat, swallowing difficult. And others were fever, fatigability, dysarthria, trismus, headache, otalgia. 5) Among the 71 cases of acute tonsillitis and 82 cases of peritonsillar abscess, most temperature of patients at visit were 36.6-37.5 $^{\circ}C$ in each 36 cases(51%), 57 cases(70%). 6) In each disease, 35 cases(47%), 45 cases(75%) consisted of single infection and 39 cases(53%), 15 cases(25%) consisted of mixed infection. In acute tonsillitis, 111 strains were isolated from 74 cases, the most common strain was 69 strains(62.2%) of $\alpha$-hemolytic streptococci. In the peritonsillar abscess, 77 strains were isolated from 60 cases, the most common strain was 49 strains(63.6%) of $\alpha$-hemolytic streptococci. In chronic tonsillitis, 563 strains were isolated from 382 cases, the most common strain was 334 strains(50.3%) of $\alpha$-hemolytic streptococci. 7) In acute tonsillitis and peritonsillar abscess, the most common leukocyte levels were reported with 10, 000-15, 000/$\mu$L in 23 cases(32%). The CRP levels were reported with abnormal findings in 61 cases(97%), 63 cases(95%) above 0.3 in each cases.

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A-team Based Approach for Reactive Power/Voltage Control Considering Steady State Security Assessment (정태 안전성 평가를 고려한 무효전력 전압제어를 위한 A-team기반 접근법)

  • Kim, Doo-Hyun
    • Journal of the Korean Society of Safety
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    • v.11 no.2
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    • pp.150-159
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    • 1996
  • In this paper, an A-team(Asynchronous Team ) based approach for Reactive power and volage control considering static security assessment in a power system with infrastructural deficiencies is proposed. Reactive power and voltage control problem is the one of optimally establishing voltage level given several constraints such as reactive generation, voltage magnitude, line flow, and other switchable reactive power sources. It can be formulated as a mixed-integer linear programming(MILP) problem without deteriorating of solution accuracy to a certain extent. The security assessment is to estimate the relative robustness of the system in Its present state through the evaluation of data provided by security monitoring. Deterministic approach based on AC load flow calculations is adopted to assess the system security, especially voltage security. A security metric, as a standard of measurement for power system security, producting a set of discrete values rather than binary values, is employed. In order to analyze the above two problems, reactive power/voltage control problem and static security assessment problem, in an integrated fashion for real-time operations, a new organizational structure, called an A-team, is adopted. An A-team is an organization for agents which ale all autonomeus, work in parallel and communicate asynchronously, which is well-suited to the development of computer-based, multi-agent systems for operations. This A-team based approach, although it is still in the beginning stage, also has potential for handling other difficult power system problems.

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Disruption of Sex Differentiation by Exogenous Sex Steroid Hormones in Korean Rockfish, Sebastes schlegeli (외인성 성스테로이드 호르몬에 의한 조피볼락, Sebastes schlegeli의 성분화 교란)

  • Kwon, Joon-Yeong;Lee, Chan-Hee;Kim, Ju-Yeong;Kim, Sang-Hun;Kim, Dae-Jung;Han, Hyoung-Kyun;Lim, Han-Kyu;Byun, Sun-Gyu
    • Development and Reproduction
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    • v.10 no.4
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    • pp.247-254
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    • 2006
  • It is well publicized that the existence of various endocrine disrupting chemicals threatens normal sexual development of many sedentary marine fishes in the coastal areas. However, a suitable marine fish species for efficient monitoring of this threatening has yet to be identified. One of the difficulties in estimating the effect of endocrine disruption in marine fish is the absence of clear distinction between testicular and ovarian structures at the early stages of sex differentiation. In search of a potential test species, we have investigated the microscopic structures of sexually undifferentiated and differentiated gonads and the susceptibility of gonadal differentiation to exogenous sex steroids during the sex differentiation period in a sedentary marine rockfish, Sebastes schlegeli. Male gonads in this species contained dark pigmentation that made them distinct from female gonads. Treatment either with $estradiol-17\;{\beta}(E_2)$ or $17\;{\alpha}-methyltestosterone$ (MT) significantly altered the sex ratios with the complete sex changes or the occurrence of ovotestis that was easily identified by the mixed structure of dimorphic gonads (coexistence of ovarian cavity/primary oocytes and dark pigmentation/seminiferous tubules). Results in this study suggest that S. schlegeli can be developed as a monitoring/test fish species for endocrine disruption in marine fish in the coastal areas.

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Biodiesel Production and Nutrients Removal from Piggery Manure Using Microalgal Small Scale Raceway Pond (SSRP) (미세조류 옥외배양 시스템을 이용한 돈분 액체 비료의 영양염류 제거 및 바이오디젤 생산)

  • Choi, Jong-Eun;Kim, Byung-Hyuk;Kang, Zion;Oh, Hee-Mock;Kim, Hee-Sik
    • Korean Journal of Environmental Biology
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    • v.32 no.1
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    • pp.26-34
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    • 2014
  • Due to the rapid energy consumption and fossil fuel abundance reduction, the world is progressively in need of alternative and renewable energy sources such as biodiesel. Biodiesel from microalgae offers high hopes to the scientific world for its potential as well as its non-competition with arable lands. Taking consideration to reduce the cost of production as well as to attain twin environmental goals of treatment and use of animal waste material the microalgal cultivation using piggery manure has been tested in this study. Unialgal strains such as Chlorella sp. JK2, Scenedesmus sp. JK10, and an indigenous mixed microalgal culture CSS were cultured for 20 days in diluted piggery manure using Small Scale Raceway Pond (SSRP). Biomass production and lipid productivity of CSS were $1.19{\pm}0.09gL^{-1}$, $12.44{\pm}0.38mgL^{-1}day^{-1}$, respectively and almost twice that of unialgal strains. Also, total nitrogen and total phosphorus removal efficiencies of CSS was 93.6% and 98.5% respectively and 30% higher removal efficiency compared to the use of unialgal strains. These results indicate that the piggery manure can provide microalgae necessary nitrogen and phosphorus for growth thereby effectively treating the manure. In addition, overall cost of microalgal cultivation and subsequently biodiesel production would be significantly reduced.

A Study on Correlation Between Cyclic Drying-Wetting Accelerated Corrosion Test and Long-term Exposure Test (건습반복 부식촉진시험 및 장기폭로시험의 상관성에 대한 연구)

  • Park, Sang-Soon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.4
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    • pp.136-143
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    • 2016
  • There are various method for evaluating the durability life of concrete structures due to salt damage. The best way is to perform a corrosion test for a rebar embedded in concrete specimen was exposure to marine environment. However, this method has the disadvantage that it takes a long period of time. Also, accelerated corrosion test which was complemented complements the time-consuming weakness is limited to apply because it could not reveal a correlation between long-term exposure test. Accordingly, the purpose of this study is to derive a correlation coefficient between cycle drying-wetting accelerated corrosion test and long-term exposure test. Corrosion initiation time was measured in four types of concrete samples, i.e., two samples mixed with fly ash(FA) and blast furnace slag(BS), and the other two samples having two water/cement ratio(W/C = 0.6, 0.35) without admixture(OPC 60 and OPC 35). The accelerated corrosion test was carried out by two case, i.e., one is a cyclic drying-wetting method(case 1), and the other is a artificial seawater ponding test method(case 2). Whether corrosion occurs, it was measures using half-cell potential method. The results indicated that case 1 is to accelerated the corrosion of rebar about 24~36% as compared with case 2, then the corrosion of rebar embedded in concrete occurred according to the order of OPC60, FA, BS, OPC35. Correlation coefficient between accelerated corrosion test and long-term exposure test, case 1 is 4.23 to 5.42, and case 2 is 6.54 to 7.82.

The Allelopathic Effect of Alfalfa residues on Crops and Weeds (잡초와 작물에 대한 알팔파 잔유물의 Allelopathy 효과)

  • Yu, C.Y.;Jeon, I.S.;Chung, I.M.;Hur, J.H.;Kim, E.H.
    • Korean Journal of Weed Science
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    • v.15 no.2
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    • pp.131-140
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    • 1995
  • This experiment was conducted to test the effect on germination and seedling growth of major industrial crops and weed control potential using alfalfa plant. When dried alfalfa residues were mixed into vermiculite, germination, length of shoot and root of crops, such as Perilla frutescens, Sorghum nevosum, Platycodon grandiflorum and weeds, Digitaria saguinalis, Setaria viridis, Siegesbechia pubescens, Ammaranthus lividus, and Solanum nigrum, were significantly inhibited as the dried residue concentration increased. More than 10% concentration of the dired residue caused 80% germination and growth inhibition. The fresh alfalfa exudation also inhibited the germination and seedling growth of crop, barley, rye, alfalfa, and sesame, and weeds, Echinochloa crus-galli, Siegesbechia viridis, and Portulaca oleracea. The degree of inhibition showed the different response according to the fresh exudation concentration, types of crops and weeds. Generally, as the exudation concentration increased, the germination and seedling growth of crops and weeds inhibited. The exudation of dried residue also exhibited the strong inhibition effect on germination and seedling growth of crops, alfalfa, Platycodon grandiflorum, barley, sesame, rye and weeds, D. sanguinalis, S. pubescens, S. viridis, P. oleracea, E. crus-galli, At the 10% concentrations, S. pubescens, and P. oleracea were not germinated and showed only 15% germination in the S. viridis. From this study, would conclude that alfalfa plant contained water soluble phytotoxic substances which were inhibitory to weeds and crops. This results suggest that alfalfa had some possibility to control some weed species using toxic compounds like natural herbicide.

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