• Title/Summary/Keyword: mineral powder

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Dispersion of Aqueous $Al_2O_3$Suspensions with Electrolytes; Influence of the Counter Ion

  • Cecile Pagnoux;Richard Laucournet;Thierry Chartier;Baumard, Jean-Francois
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.280-285
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    • 2000
  • The electrolyte, $(HO)_2C_6H_2(SO_3Na)_2H_2O $(Tiron), disperses efficiently alumina powder in aqueous media and stable suspensions with 60 vol% solid loading can be prepared. The strong adsorption of this additive is mainly due to the ability of the molecule to form chelate rings with the particle surface but electrostatic interactions between the surface charge and the anionic dispersant strongly influence the amount of Tiron adsorbed. By using a cationic exchange route to substitute the counter ion which neutralizes the sulfonate groups, new molecules of dispersant have been prepared, either with mineral cations as $Li^+,\; Na+^,\; NH_4^\;+$, or with organic cations as counter ion but organic counter ions lead to less to less viscous suspensions than $Na^+$ in particular when the number of carbon atoms of the aliphatic chain increases from 1 to 3.

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The Thermal Transformation of Tobermorite-Studies on The Thermal Transformation of Calcium Silicate Hydrates(II)- (Tobermorite의 가열변화 -규산칼슘 수화물의 가열성상에 관한 연구(II)-)

  • 이종근;최상흘;한상목
    • Journal of the Korean Ceramic Society
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    • v.11 no.4
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    • pp.25-30
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    • 1974
  • The mixture of quartz powder and slaked lime with plenty water was oscillated in an autoclave and treated hydrothermally under the pressure of 10 kg/$\textrm{cm}^2$ for 8 hours. The main mineral synthesized was confirmed 11$\AA$ tobermorite by the method of X-ray diffraction and selected area electron diffraction. Tobermorite was heat-treated at 40$0^{\circ}C$, 80$0^{\circ}C$ and 100$0^{\circ}C$ for investigation of transformation of morphology and structure. Electron micrographs showed the thin platy structure of synthetic tobermorite with a little of crumpled foil or fibrous semi-crystalline calcium silicate hydrates. No difference in structure was appeared under the temperature of 80$0^{\circ}C$ but tobermorite converted gradually into wollastonite at 800$^{\circ}$~85$0^{\circ}C$. On heating, moulded material from tobermorite hardly shrinks under 80$0^{\circ}C$.

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Analysis of Basic Constituents in Korean Earthworm About Lamnodrilus gotai Hatai (한국산 토룡의 기초성분 분석 -Lamnodrilus gotai Hatai를 대상으로-)

  • Chung, Yong;Lee, Yun-Sil;Lee, Hyo-Min
    • YAKHAK HOEJI
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    • v.31 no.4
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    • pp.224-229
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    • 1987
  • The earthworm(Annelid) is a herbicine which has traditionally been used in the treatment of infectious fever, jaundice, infection of middle ear, laryngitis, pharyngitis, nephritis, headache, toothache and certain urinary tract infections from the olden times. Before the isolation and purification of biologically active components we analyzed the basic constituents(proteins, amino acids, mineral, etc.) with lyophilized powder of Lamnodrilus gotai Hatai. The results were as follows: Minerals detected and quantitatively analyzed were $Ca^#$, $Mg^#$, Fe, Zn, Mn, Cu, Co, Cr, Ni, Ge and Se. Amino acids detected were alanine, phenylalanine, leucine, glutamic acid, tyrosine, threonine, arginine, aspartic acid, methionine, lysine, serine, histidine, isoleucine, glycine, proline and etc. The constituents of proteins, fat, fiber, ash and phosphorous were measured. These constituents were compared and discussed with those of other investigations.

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Comparison of National Standards for Blast Furnace Slag and Fly Ash between Korea and China (한국과 중국간의 고로슬래그 미분말 및 플라이 애시의 품질 규정 비교)

  • Hu, Yun-Yao;Lim, Gun-Su;kim, Jong;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.63-64
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    • 2022
  • In this study, the quality of mineral admixture, Comparison of blast-furnace slag(BS) and fly ash(FA)in Korea and China. In the case of BS, Korea is mainly classified into 1 type to 4 types according to the specific surface area, whereas China is classified into S105, 95, and 75 according to the activity index of 28 days of age. In the case of FA, Korea is like BS, is mainly classified into types 1 to 4 according to specific surface area, whereas China is classified into F, C (class F, class C) by ingredients and class I, II, and III according to powder and ignition loss.

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Fabrication and Characterization of Porous TiO2 Powder by Aerosol Process (에어로졸공정에 의한 다공성 TiO2분말의 제조 및 공극특성)

  • Chang, Han Kwon;Jang, Hee Dong;Park, Jin Ho;Cho, Kuk;Kil, Dae Sup
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.479-485
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    • 2008
  • Porous $TiO_2$ nanostructured particles containing both mesopores and macropores were fabricated by utilizing an aerosol templating method from two kinds of starting materials (colloidal mixture of $TiO_2$ nanoparticles and PS particles, and that of TTIP solution and PS particles). The effects of mixing ratio of PS to $TiO_2$ and reactor temperature on the particle properties were investigated. When $TiO_2$ nanoparticles were used as starting materials, the increase of macropores number was observed by SEM and the specific surface area and total pore volume were increased from $31.6m^2/g$ to $39.1m^2/g$ and $0.068cm^3/g$ to $0.089cm^3/g$, respectively, by increasing the weight mixing ratio of $PS/TiO_2$ from 0.79 to 1.31. When TTIP was used as precursor, the specific surface area and mesopore volume of particles prepared at same condition decreased by 67% and 75%, respectively.

Physicochemical Characteristics of Zeolite Mineral by Alkali Solution Treatment (알칼리 처리에 의한 Zeolite 광물의 물리화학적 특성)

  • Yim, Going
    • The Journal of Natural Sciences
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    • v.8 no.2
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    • pp.119-127
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    • 1996
  • The effect of sodium hydroxide treatment on some physicochemical properties of zeolite mordenite mineral was studied with chemical analyses, powder X-ray diffraction, thermal analyses, infrared analysis, measurement of carbon dioxide adsorption and gas chromatography. Mordenite mineral from tuffaceous rocks in Yeongil and Wolsung area was used as a starting material and treated with 0.1-5N NaOH aqueous solution at about $95^{\circ}C$ in the water bath for three hours.At the concentration of sodium hydroxide below 0.5N, all chemical compositions in the tuff were virtually insoluble and the mordenite structure did not change. At the concentration above 1N, the chemical compositions such as silica, alumina, etc., were dissolved. The dissolution ratio of silica was lager than that of alumina, and the ratio of silica to alumina in the tuff decreased sharply in the concentration range of 2 to 3N. Intensity of X-ray diffraction peak of mordenite (202) plane and the adsorbed amount of carbon dioxide also decreased with the increasing concentration of sodium hydroxide above 1N. These decreases corresponded to the degree of mordenite structure collapsed.The separation of gas chromatography of nitrogen, oxygen and carbon monoxide was not affected by the sodium hydroxide treatment, but elution peaks of methane and krypton tended to be broadened and their retention time was shortened. The elution peaks of both methane and krypton tended to be overlapped with those of nitrogen and oxygen.

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Mineralogy of Cu-Co Ores from Democratic Republic of Congo (콩고민주공화국 동-코발트 광석의 광물학적 특정)

  • Cho, Hyen-Goo;Seo, Hye-Min;Kim, Soon-Oh;Kim, Young-Ho;Kim, Sang-Bae
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.4
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    • pp.305-313
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    • 2010
  • Mineralogical characteristics of Cu-Co ores from the Central African Copperbelt in the Democratic Repblic of Congo are studied using powder X-ray diffractometer, general area detector X-ray diffractometer, and electron proble microanalyzer. Black ores are mainly composed of heterogenite (cobalt oxide/hydroxide mineral) and malachite (copper carbonate mineral), whereas green ores are only composed of malachite. Heterogenite shows very bright white color under the reflected microscope, and belongs to 3R polytype, because it has d-spacings at $4.39{\AA}$ and $2.316{\AA}$. Since NiO and $Fe_20_3$ content of heterogenite are lower than those of 3R polytype from other localities, it cannot completely exclude the presence of 2H polytype in heterogenite from this study. Malachite is light grey color under the reflected microscope with approximate chemical formula of $Cu_{1.97}Co_{0.02}Fe^{2+}{_{0.01}}CO_3(OH)_2$. Heterogenite and malachite were probably formed at the supergene emichment stage, the last mineralization stage in the Central African Copperbelt. Cobalt seems to be much more emiched in the black supergene (oxy)hydroxide ore than those in the primary sulfide ore.

Extraction of Pyrophyllite Mineralized Zone using Characteristics of Spectral Reflectance of Rock Samples (암석분광반사율 특성을 이용한 납석 광화대 추출)

  • Chi, Kwang-Hoon;Lee, Hong-Jin
    • Korean Journal of Remote Sensing
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    • v.23 no.6
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    • pp.493-500
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    • 2007
  • In general, it accomplished a spectral reflectance analysis to be, the measurement results appear differently by targets, methods and condition. This paper presents a standard methodology for preprocessing mineral/rock samples and setting the distance from a target to the sensor, and then examines closely the spectral features for pyrophyllite. The size of mineral/rock samples is various according to the condition and scale of outcrop, so it is important to maintain the distance between the sensor and the sample. Before standardization for preprocessing samples and the sensor and sample distance, we prepare various rock samples (Quartz Porphyry) such as natural rock, pebble, powder and cutting rock. For a qualitative analysis to minimize the effect of surface condition of the sample and shadow, we maintains the distance from the sample to the sensor at 30cm and measures three times repeatedly for cutting the sample at $1{\sim}2cm$ thickness. To illustrate the proposed methodology, a case study for pyrophyllite was carried out. In this study, pyrophyllite showed an absorption pattern at wave length of 1.406nm, 1,868nm, 2.180nm and 2.309nm, and a higher grade represented strong absorption at 1.406nm and 2.180 nm. These absorption feature corresponds the band 7 of LANDSAT TM and band 8 of ASTER imageries. So, using these results, pyrophyllite deposits were extracted from other features (such as barren area, concrete area, bed of river, stone pit area etc.).

Characteristic of Precipitated Metal Carbonate for Carbon Dioxide Conversion Using Various Concentrations of Simulated Seawater Solution (해수 농축수 내 금속 이온 농도에 따른 이산화탄소 전환 생성물의 특성연구)

  • Choi, Eunji;Kang, Dongwoo;Yoo, Yunsung;Park, Jinwon;Huh, Il-sang
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.539-546
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    • 2019
  • Global warming has mentioned as one of the international problems and these researches have conducted. Carbon Capture, Utilization and Storage (CCUS) technology has improved due to increasing importance of reducing emission of carbon dioxide. Among of various CCUS technologies, mineral carbonation can converted $CO_2$ into high-cost materials with low energy. Existing researches has been used ions extracted solid wastes for mineral carbonation but the procedure is complicated. However, the procedure using seawater is simple because it contained high concentration of metal cation. This research is a basic study using seawater-based wastewater for mineral carbonation. 3 M Monoethanolamine (MEA) was used as $CO_2$ absorbent. Making various concentrations of seawater solution, simulated seawater powder was used. Precipitated metal carbonate salts were produced by mixing seawater solutions and $rich-CO_2$ absorbent solution. They were analyzed by X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Thermogravimetric Analysis (TGA) and studied characteristic of producing precipitated metal carbonate and possibility of reusing absorbent.

Breakage and Surface Oxidation Characteristics of Waste NdFeB Magnet for Recycling (NdFeB 자석 재활용을 위한 파분쇄 및 그에 따른 표면 산화 특성 연구)

  • Kim, Kwanho;Kim, Gahee;Lee, Hoon;Kang, Jungshin
    • Resources Recycling
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    • v.28 no.3
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    • pp.26-34
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    • 2019
  • Due to the increasing demand of rare earth magnet for various application, it is predicted that the amount of waste rare earth magnet will increase sharply. The process of waste rare earth magnet recycling is mainly consisted of leaching and separation of rare earth element contained in the magnet. However, there is no study on the breakage characteristics of the waste rare earth magnet for production of magnet powder. Therefore, in this study, effective crushing/grinding process and breakage characteristics were investigated for waste rare earth magnet. In the case of jaw crusher, the particle size of magnet was effectively reduced without rapid oxidation. In ball mill grinding test, it was found that the grinding process was not performed properly at the early stage of grinding. Moreover, waste rare earth magnet showed very low specific rate of breakage(S) and high fraction of fine particle breakage distribution(B) compared to ordinary minerals. These results can be used as a basic data for developing crushing/grinding circuit of waste rare earth magnet.