Browse > Article
http://dx.doi.org/10.9713/kcer.2019.57.4.539

Characteristic of Precipitated Metal Carbonate for Carbon Dioxide Conversion Using Various Concentrations of Simulated Seawater Solution  

Choi, Eunji (Department of Chemical and Biomolecular Engineering, Yonsei University)
Kang, Dongwoo (Department of Chemical and Biomolecular Engineering, Yonsei University)
Yoo, Yunsung (Department of Chemical and Biomolecular Engineering, Yonsei University)
Park, Jinwon (Department of Chemical and Biomolecular Engineering, Yonsei University)
Huh, Il-sang (Wooju Envitech, Inc. R&D Center)
Publication Information
Korean Chemical Engineering Research / v.57, no.4, 2019 , pp. 539-546 More about this Journal
Abstract
Global warming has mentioned as one of the international problems and these researches have conducted. Carbon Capture, Utilization and Storage (CCUS) technology has improved due to increasing importance of reducing emission of carbon dioxide. Among of various CCUS technologies, mineral carbonation can converted $CO_2$ into high-cost materials with low energy. Existing researches has been used ions extracted solid wastes for mineral carbonation but the procedure is complicated. However, the procedure using seawater is simple because it contained high concentration of metal cation. This research is a basic study using seawater-based wastewater for mineral carbonation. 3 M Monoethanolamine (MEA) was used as $CO_2$ absorbent. Making various concentrations of seawater solution, simulated seawater powder was used. Precipitated metal carbonate salts were produced by mixing seawater solutions and $rich-CO_2$ absorbent solution. They were analyzed by X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Thermogravimetric Analysis (TGA) and studied characteristic of producing precipitated metal carbonate and possibility of reusing absorbent.
Keywords
Precipitated Metal Carbonate; Carbon Capture and Utilization (CCU); Mineral carbonation; Brine; Carbon Capture and Storage (CCS);
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Basfar, A. A. and Bad, H. J., "Influence of Magnesium Hydroide and Huntite Hydromagnesite on Mechanical Properties of Ethylene Vinyl Acetate Compounds Cross-Linked by DiCumyl Peroxide and Ionizing Radiation," J. Fire Sci., 28(2), 161-180(2010).   DOI
2 Marion, G. M., "Carbonate Mineral Solubility at Low Temperatures in the $Na-K-Mg-Ca-H-Cl-SO_4-OH-HCO_3-CO_3-CO_2-H_2O$ System," Geochim. Cosmochim. Acta, 65(12), 1883-1896(2001).   DOI
3 Davies, P. J. and Bubela, B., "The Transformation of Nesquehonite into Hydromagnesite," Chem. Geol., 12(4), 289-300(1973).   DOI
4 Hollingbery, L. A. and Hull, T. R., "The Thermal Decomposition of Huntite and Hydromagnesite - a Review," Thermochim. Acta, 509(1-2), 1-11(2010).   DOI
5 Chaiwang, P., Chalermsinsuwan, B. and Piumsomboon, P., "Thermogravimetric Analysis and Chemical Kinetics for Regeneration of Sodium and Potassium Carbonate Solid Sorbents," Chem. Eng. Commun., 203(5), 581-588(2016).   DOI
6 Rosa, C. M. and Adisa, A., "Carbon Capture, Storage and Utilisation Technologies: A Critical Analysis and Comparison of their Life Cycle Environmental Impacts," J. of $CO_2$ Utilization, 9, 82-102(2015).   DOI
7 Kang, D. W., Lee, M. G., Jo, H. Y., Yoo, Y. S., Lee, S. M. and Park, J. W., "Carbon Capture and Utilization Using Industrial Wastewater under Ambient Conditions," Chem. Eng. J., 308, 1073-1080(2017).   DOI
8 Marco, M., Ronny, P. and Giuseppe, S., "Enhanced Coal Bed Methane Recovery," J. Supercrit. Fluids, 47(3), 619-627(2009).   DOI
9 Chen, J., Duan, L., Donat, F., Muller, C., Anthony, E. and Fan, M., "Self-activated, Nanostructured Composite for Improved CaL-CLC Technology," Chem. Eng. J., 351, 1038-1046(2018).   DOI
10 Lee, S., Kim, J. W., Chan, S., Bang, J. H. and Lee, S. W., "$CO_2$ Sequestration Technology Through Mineral Carbonation: An Extraction and Carbonation of Blast Slag," J. of $CO_2$ Utilization, 16, 336-345(2016).   DOI
11 Park, S. Y., Seo, J. S. and Kim, T. Y., "Environmental Impacts of Brine from the Seawater Desalination Plants," J. Environ. Impact Assess, 27(1), 17-32(2018).   DOI
12 Dash, S., Kamruddin, M., Ajikumar, K., Tyagi, A. K. and Raj, B., "Nanocrystalline and Metastable Phase Formation in Vaccum Thermal Decomposition of Calcium Carbonate," Thermochimi. Acta, 363(1-2), 129-135(2000).   DOI
13 Kang, D. W., Lee, M. G., Jo, H. Y. and Park, J. W., "Carbon Dioxide Utilization Using a Pretreated Brine Solution at Normal Temperature and Pressure," Chem. Eng. J., 286, 1270-1278(2016).
14 Kim, I. and Svendsen, H. F., "Heat of Absorption of Carbon Dioxide in Monoethanolamine (MEA) and 2-(Aminoethyl)ethanolamine (AEEA) Solutions," Ind. Eng. Chem. Res., 46(17), 5803-5809(2007).   DOI
15 David, T. W. and David, W., "Precipitation of Dolomite Using Sulphate-Reducing Bacteria from the Coorong Region, South Australia: Significance and Implications," Sedimentology, 52(5), 987-1008(2005).   DOI
16 Loste, E., Wilson, R. M., Sechadri, R. and Meldrum, F. C., "The Role of Magnesium in Stabilising Amorphous Calcium Carbonate and Controlling Calcite Morphologies," J. Cryst. Growth, 254(1-2), 206-218(2003).   DOI
17 De Chouden-Sa Nchez, V. and Gonzalez, L. A., "Calcite and Aragonite Precipitation Under Controlled Instantaneous Supersaturation: Elucidating the Role of $CaCO_3$ Saturation State and Mg/Ca Ratio on Calcium Carbonate Polymorphism," J. Sediment. Res., 79(6), 363-376(2009).   DOI
18 Mcintosh, R. M., Sharp, J. H. and Wilburn, F. W., "The Thermal Decomposition of Dolomite," Thermochimi. Acta, 165(2), 281- 296(1990).   DOI
19 Rodirguez-Blanco, J., Shaw, S., Bots, P., Roncal-Herrero, T. and Benning, L. G., "The Role of Mg in the Crystallization of Monohydrocalcite," Geochim. Cosmochim. Acta, 127, 204-220(2014).   DOI