• Corrosion Science and Technology
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• 제8권1호
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• pp.1-10
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• 2009

The influence of Schiff bases on the corrosion inhibition of mild steel in 1 M $H_2SO_4$ have been investigated by weight loss, gasometry, impedance and polarization techniques. The results obtained reveal that these compounds act as good inhibitors. The inhibition efficiency of Schiff bases increased with concentration and synergistically increased on addition of chromate, sulphate and halide ions. Potentiodynamic polarization measurements clearly reveal that the investigated inhibitors are of mixed type but they are more cathodic in nature. The adsorption of these compounds on mild steel surface for both the acids were found to obey Langmuir adsorption isotherm. The surface morphology was studied by SEM and UV reflectance spectra.

• 한국재료학회지
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• 제7권2호
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• pp.162-170
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• 1997

This study has evaluated the dissimialr weldability of Incoloy 825 Ni base alloy with a mild steel(SS41). Further a compatibility study of wrveral Ni base filler metals with the dissimilar joint between the two alloys was also included. The dissimilar weldability of Incoloy 825 with mild steel is strongly dependent upon the type of the filler metal used. Among the filler metals, ENiCrFe which has a chemical comosition similar to that of Incoloy 825 was found to be most compatible to the joint. In addition, a filler metal which showed a good cracing resistance in one dissimiar alloy combination was not necessarily graranteed to other combination. Microstructural examination with SEM, TEM and Auger revealed that the solidification cracking resestance of the dissimilar joint. between Incoloy 835 and SS41 was closely with the Ti+Nb content and with the content of a low melting eutectic phase of Laves relatibve to that of MC type phase.

• Journal of Welding and Joining
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• 제15권4호
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• pp.154-165
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• 1997

Abrasive wear characteristics of high Cr white cast iron-based hardfacing were investigated using the rubber wheel abrasion wear test method according with the ASTM G65-85. Mild steel was also tested for comparison with high Cr cast iron hardfacing. Wear experiments, where the applied force, wheel revolution rate and abrasive powder feed rate were selected as test valuables, were planned and analyzed by response surface method to evaluate wear statistically and quantitatively. Weight loss of high Cr cast iron hardfacing was mostly affected by the applied force and wheel revolution rate, and little by the powder feed rate. Weight loss of mild steel was greatly affected by the wheel revolution rate and powder feed rate, and slowly and steadily increased with the applied force. Abrasive wear mechanism of high Cr cast iron and mild steel was discussed in the light of the wear test results.

• Tribology and Lubricants
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• 제29권2호
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• pp.85-90
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• 2013

The effects of contact pressure on the sliding wear behavior of mild steel in a pin-on-disc type apparatus were investigated. Sliding wear tests were conducted with various combinations of the load and apparent area of contact. The wear behavior of mild steel as a function of sliding speed was independent of contact pressure. However, the wear rate at different sliding speeds was influenced by the load regardless of the apparent area of contact. This was attributed to the fact that there may be no difference in the real area of contact for any combination of the load and apparent area of contact.

• Smart Structures and Systems
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• 제16권3호
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• pp.537-554
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• 2015

Magneto-electro-elastic (MEE) materials under thermal environment exhibits pyroelectric and pyromagnetic coefficients resulting in pyroeffects such as pyroelectric and pyromagnetic. The pyroeffects on the behavior of multiphase MEE sensor bonded on top surface of a mild steel cylindrical shell under thermal environment is presented in this paper. The study aims to investigate how samples having different volume fractions of the multiphase MEE sensor behave due to pyroeffects using semi-analytical finite element method. This is studied at an optimal location on a mild steel cylindrical shell, where the maximum electric and magnetic potentials are induced due to these pyroeffects under different boundary conditions. It is assumed that sensor and shell is perfectively bonded to each other. The maximum pyroeffects on electric and magnetic potentials are observed when volume fraction is $v_f$ = 0.2. Additionally, the boundary conditions significantly influence the pyroeffects on electric and magnetic potentials.

• 대한화학회지
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• 제57권2호
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• pp.264-271
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• 2013

Corrosion inhibition of mild steel used in water station in 35 ppm aluminum sulfate and 10 ppm chloride solution by Camellia sinensis leaves extract was studied using weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy techniques at $30^{\circ}C$. Results show that the inhibition efficiency increases with increasing concentration of the extract and decreases with increasing temperature. Inhibitive effect was afforded by adsorption of the extract's components which was found to accord with Langmuir adsorption isotherm. Inhibition mechanism is deduced from the temperature dependence of the inhibition efficiency and was further corroborated by the values of activation parameters obtained from the experimental data.

• Journal of Electrochemical Science and Technology
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• 제10권1호
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• pp.37-54
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• 2019

A new organic Schiff base compound N-benzylidene-2,5-dichloroaniline (BDC) was synthesized and the structure of the Schiff base is illuminated by some spectroscopic techniques. In addition, whether it is an applicable inhibitor in the industrial field was examined by conventional methods such as linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization for different concentrations. The BDC concentration and temperature effects were surveyed for elucidating the inhibitive mechanism. The BDC molecules are adsorbed to surface of mild steel via the Langmuir isotherm. Atomic force (AFM) and scanning electron microscope (SEM) techniques were utilized to give insight into surface characterization.

• Corrosion Science and Technology
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• 제21권1호
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• pp.21-31
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• 2022

Potentiodynamic polarization, EIS measurements, quantum chemical calculations, and molecular dynamic simulations were used to investigate the corrosion behavior of mild steel in 0.5 M aqueous hydrochloric acid medium in the presence or absence of nystatin drug. Potentiodynamic tests suggested that this molecule could act as a mixed inhibitor due to its adsorption on the mild steel surface. The objective of this study was to exploit theoretical calculations to gain a better understanding mechanism of inhibition. Calculating the adsorption behavior of the investigated molecule on Fe (1 1 0) surface was accomplished using Monte Carlo simulation. Molecules were also investigated using Density Functional Theory (DFT), specifically PBE functional, in order to identify the link between molecular structure and corrosion inhibition behavior of the compound under investigation. Adsorption energies between nystatin and iron were estimated more accurately by utilizing Molecular Mechanics calculation with Periodic Boundary Conditions (PBC). Estimated theoretical parameters significantly assisted our understanding of the corrosion inhibition mechanism exhibited by this molecule. They were found to be in accord with experimental results.

• 한국산업보건학회지
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• 제10권1호
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• pp.45-57
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• 2000

Results of environmental monitoring for 35 steel industry welders exposed to manganese and chromium fume were evaluated. Efficiency of respiratory protectors, welding face shields and local exhaust ventilation were also evaluated to establish more efficient preventive measures that can protect welders from occupational disease as related to welding fume. The results are as follows; 1. Total fume from $CO_2$ arc welding with mild steel occurred 1.5 to 2.2 times more than that from shielded metal arc welding. Chromium and nickel fume from welding with stainless steel occurred 27 to 59 times and 18 to 30 times, respectively, than those with mild steel. 2. Proportions of water-soluble chromium(VI) and insoluble chromium(VI) Compare to total chromium occurring from $CO_2$ arc welding with stainless steel were 10.5% and 8.7%, respectively, while those with mild steel were 57.1 to 63.2% and 31.6 to 38.1%, respectively. 3. The efficiencies of 4 types of respiratory protectors to reduce welding fume exposure were evaluated as 54.4 to 64.4%. 4. The reducing effect of head type welding face shield was 67.6%, and that of hand type welding face shield was 58.5%. The highest reducing effect was shown in air supply welding face shield as 99.2%, although it is not convenient to wear. 5. When welding face shield and respiratory protectors were worn together, the reducing efficiency increased to 79.0 to 87.5%. 6. When local exhaust ventilation was installed in workplace, the reducing efficiencies varied from 31.5 to 73.1% according to the types of welding.

• Journal of Electrochemical Science and Technology
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• 제11권2호
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• pp.117-131
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• 2020

The adsorption of N-[(E)-Pyridin-2-ylmethylidene] aniline, a Schiff base, on to mild steel surface in 1M HCl and 0.5 M H₂SO₄ solutions and the consequent corrosion protection were studied employing weight loss method, electrochemical impedance spectroscopy and potentiodynamic polarization measurements. DFT calculations were performed to investigate its interaction with the metal surface at the atomic level to understand its inhibition mechanism. The adsorption process is well described by the Langmuir isotherm. The thermodynamic parameters indicated that the adsorption is spontaneous and the interaction of the inhibitor at the mild steel surface is mainly through physisorption. The R_a values obtained in AFM studies for the uninhibited and inhibited sample in HCl media respectively are 0.756 and 0.559 ㎛, and that in H₂SO₄ media are 0.411 and 0.406 ㎛. The lesser roughness values of the inhibited sample shows the adsorption of the molecules onto the mild surface. The inhibition efficiencies were found to improve with concentration of the inhibitor and the maximum efficiency was observed at 400ppm in all the investigation methods adopted. The inhibitor was found to exhibit a higher efficiency in HCl media (95.7%) than in H₂SO₄ (92.8%). The theoretical and experimental results are found to be in good agreement.