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http://dx.doi.org/10.5229/JECST.2019.10.1.37

A Newly Synthesized Schiff Base Derived from Condensation Reaction of 2,5-dichloroaniline and benzaldehyde: Its Applicability through Molecular Interaction on Mild Steel as an Acidic Corrosion Inhibitor by Using Electrochemical Techniques  

Ozkir, Demet (Nigde Omer Halisdemir University, Faculty of Arts and Sciences, Department of Chemistry)
Publication Information
Journal of Electrochemical Science and Technology / v.10, no.1, 2019 , pp. 37-54 More about this Journal
Abstract
A new organic Schiff base compound N-benzylidene-2,5-dichloroaniline (BDC) was synthesized and the structure of the Schiff base is illuminated by some spectroscopic techniques. In addition, whether it is an applicable inhibitor in the industrial field was examined by conventional methods such as linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization for different concentrations. The BDC concentration and temperature effects were surveyed for elucidating the inhibitive mechanism. The BDC molecules are adsorbed to surface of mild steel via the Langmuir isotherm. Atomic force (AFM) and scanning electron microscope (SEM) techniques were utilized to give insight into surface characterization.
Keywords
Schiff base; Mild steel; Interaction; EIS; Acid corrosion;
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