• 제목/요약/키워드: mild solution

검색결과 257건 처리시간 0.023초

Corrosion Protection Effectiveness and Adsorption Performance of Schiff Base-Quinazoline on Mild Steel in HCl Environment

  • Sayyid, Firas F.;Mustafa, Ali M.;Hanoon, Mahdi M.;Shaker, Lina M.;Alamiery, Ahmed A.
    • Corrosion Science and Technology
    • /
    • 제21권2호
    • /
    • pp.77-88
    • /
    • 2022
  • Schiff base quinazoline derivative viz., 3-((2-hydroxy-3-methoxybenzylidene)amino)-2-methylquinazolin-4(3H)-one (SB-Q), was synthesized in this study. Its corrosion protection impact on mild steel (MS) in 1 M hydrochloric acid solution was examined by performing weight loss measurements. The protective efficacy of SB-Q on MS in 1 M HCl was investigated based on its concentrations, immersion period, and immersion temperature. SB-Q was found to be an efficient inhibitor for the corrosion of MS. Its inhibition efficiency was improved by increasing the concentration of SB-Q to an optimal concentration of 500 ppm. Its inhibition efficacy was 96.3% at 303K. Experimental findings revealed that its inhibition efficiency was increased with increasing immersion time, but decreased with an increase in temperature. The adsorption of SB-Q molecules was followed the Langmuir adsorption isotherm model. The adsorption of the examined inhibitor molecules on the surface of mild steel was studied by density functional theory (DFT). DFT investigation confirmed weight loss findings.

Gravimetric Measurements and Theoretical Calculations of 4-Aminoantipyrine Derivatives as Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution: Comparative Studies

  • Firas F. Sayyid;Ali M. Mustafa;Slafa I. Ibrahim;Mustafa K. Mohsin;Mahdi M. Hanoon;Mohammed H. H. Al-Kaabi;A. A. H. Kadhum;Wan Nor Roslam Wan Isahak;A. A. Al-Amiery
    • Corrosion Science and Technology
    • /
    • 제22권2호
    • /
    • pp.73-89
    • /
    • 2023
  • Due to continuous promotion of green alternatives to toxic petrochemicals by government policies, research efforts towards the development of green corrosion inhibitors have intensified recently. The objective of the current work was to develop novel green and sustainable corrosion inhibitors derived from 4-aminoantipyrine to effectively prevent corrosion of mild steel in corrosive environments. Gravimetric methods were used to investigate corrosion inhibition of 4-((furan-2-ylmethylene)amino)antipyrine (FAP) and 4-((pyridin-2-ylmethylene)amino)antipyrine (PAP) for mild steel in 1 M HCl. FAP and PAP were subjected to quantum chemical calculations using density functional theory (DFT). DFT was used to determine the mechanism of mild steel corrosion inhibition using inhibitors tested in HCl. Results demonstrated that these tested inhibitors could effectively inhibit mild steel corrosion in 1.0 M HCl. At 0.0005 M, these inhibitors' efficiencies for FAP and PAP were 93.3% and 96.5%, respectively. The Langmuir adsorption isotherm was obeyed by these inhibitors on the mild steel surface. Values of adsorption free energies, ΔGoads, revealed that FAP followed chemical and physical adsorptions.

레진 배양액의 세포독성에 관한 연구 (A STUDY ON THE CYTOTOXICITY OF THE INCUBATED RESIN SOLUTION)

  • 임미경;김은철;유수경;김강주
    • Restorative Dentistry and Endodontics
    • /
    • 제18권2호
    • /
    • pp.369-376
    • /
    • 1993
  • To know the in vitro and the in vivo cytotoicity of resin solution, resin solution was applied to cultured fibroblast and was injected into the mouse. The cytotoxic effect of resin solution was measured by MIT assay and in vivo cytotoxicity was examined after Hematoxylin and Eosin staining. The cell activity of resin solution in the concentration of 50% was significantly decreased compared to control group and 5 % group. In histopathologic study of resin solution, there were severe inflammatory cell infiltration, mild interstitial edema, trace hemorrhage, and moderate or severe muscle destruction in resin injected group. These results suggested that there might be some differences between the cell viability of fibroblast and in vivo cell cytotoxicity. Further study is needed to clarify the cytotoxicity by direct implanting of resin mass.

  • PDF

NONLINEAR ALGORITHMS FOR A COMMON SOLUTION OF A SYSTEM OF VARIATIONAL INEQUALITIES, A SPLIT EQUILIBRIUM PROBLEM AND FIXED POINT PROBLEMS

  • Jeong, Jae Ug
    • Korean Journal of Mathematics
    • /
    • 제24권3호
    • /
    • pp.495-524
    • /
    • 2016
  • In this paper, we propose an iterative algorithm for finding a common solution of a system of generalized equilibrium problems, a split equilibrium problem and a hierarchical fixed point problem over the common fixed points set of a finite family of nonexpansive mappings in Hilbert spaces. Furthermore, we prove that the proposed iterative method has strong convergence under some mild conditions imposed on algorithm parameters. The results presented in this paper improve and extend the corresponding results reported by some authors recently.

APPROXIMATE REACHABLE SETS FOR RETARDED SEMILINEAR CONTROL SYSTEMS

  • KIM, DAEWOOK;JEONG, JIN-MUN
    • Journal of applied mathematics & informatics
    • /
    • 제38권5_6호
    • /
    • pp.469-481
    • /
    • 2020
  • In this paper, we consider a control system for semilinear differential equations in Hilbert spaces with Lipschitz continuous nonlinear term. Our method is to find the equivalence of approximate controllability for the given semilinear system and the linear system excluded the nonlinear term, which is based on results on regularity for the mild solution and estimates of the fundamental solution.

IMPULSIVE FUZZY SOLUTIONS FOR ABSTRACT SECOND ORDER PARTIAL NEUTRAL FUNCTIONAL DIFFERENTIAL EQUATIONS

  • CHALISHAJAR, DIMPLEKUMAR N.;RAMESH, R.
    • Journal of Applied and Pure Mathematics
    • /
    • 제4권1_2호
    • /
    • pp.71-77
    • /
    • 2022
  • This work considers the existence and uniqueness of fuzzy solutions for impulsive abstract partial neutral functional differential systems. To establish the existence and uniqueness, we apply the concept of impulse, semi group theory and suitable fixed point theorem.

CONTROLLABILITY OF STOCHASTIC FUNCTIONAL INTEGRODIFFERENTIAL EVOLUTION SYSTEMS

  • Kokila, J.;Balachandran, K.
    • Journal of applied mathematics & informatics
    • /
    • 제29권3_4호
    • /
    • pp.587-601
    • /
    • 2011
  • In this paper, we prove the existence and uniqueness of mild solution for stochastic functional integrodifferential evolution equations and derive sufficient conditions for the controllability results. As an illustration we consider the controllability for a system governed by a random motion of a string.

EXISTENCE, UNIQUENESS AND STABILITY OF IMPULSIVE STOCHASTIC PARTIAL NEUTRAL FUNCTIONAL DIFFERENTIAL EQUATIONS WITH INFINITE DELAYS

  • Anguraj, A.;Vinodkumar, A.
    • Journal of applied mathematics & informatics
    • /
    • 제28권3_4호
    • /
    • pp.739-751
    • /
    • 2010
  • This article presents the result on existence, uniqueness and stability of mild solution of impulsive stochastic partial neutral functional differential equations under sufficient condition. The results are obtained by using the method of successive approximation.