• Title/Summary/Keyword: micro-silica

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Sustainable self compacting acid and sulphate resistance RAC by two stage mixing approaches

  • Rajhans, Puja;Kisku, Nishikant;Nayak, Sanket;Panda, Sarat Kumar
    • Advances in concrete construction
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    • v.9 no.1
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    • pp.55-70
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    • 2020
  • In this research article, acid resistance, sulphate resistance and sorptivity of self compacted concrete (SCC) prepared from C&D waste have been discussed. To improve the above properties of self compacted recycled aggregate concrete (SCRAC) along with mechanical and durability properties, different two stage mixing approaches (TSMA and TSMAsfc) were followed. In the proposed two stage mixing approach (TSMAsfc), silica fume, a proportional amount of cement and a proportional amount of water were mixed in premix stage which fills the pores and cracks of recycled aggregate concrete (RAC). The concrete specimen prepared using above mixing approaches were immersed in 1% concentration of sulphuric acid (H2SO4) and magnesium sulphate (MgSO4) solution for 28, 90 and 180 days for evaluating the acid resistance of SCRAC. Experimental results concluded that the proposed two stage mixing approach (TSMAsfc) is most suitable for acid resistance and sulphate resistance in terms of weight loss and strength loss due to the elimination of pores and cracks in the interfacial transition zone (ITZ). In modified two stage mixing approach, the pores and cracks of recycled concrete aggregate (RCA) were filled up and make ITZs of SCRAC stronger. Microstructure analysis was carried out to justify the reason of improvement of ITZs by electron probe micro analyser (EPMA) analysis. X-ray mapping was also done to know the presence of strength contributing elements presents in the concrete sample. It was established that SCRAC with modified mixing approach have shown improved results in terms of acid resistance, sulphate resistance, sorptivity and mechanical properties.

Mechanical and durability properties of self-compacting concrete with blended binders

  • Xie, T.Y.;Elchalakani, M.;Mohamed Ali, M.S.;Dong, M.H.;Karrech, A.;Li, G.
    • Computers and Concrete
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    • v.22 no.4
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    • pp.407-417
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    • 2018
  • Over the past three decades, self-compacting concrete (SCC), which is characterized by its superior rheological properties, has been gradually used in construction industry. It is now recognized that the application of SCC using supplementary cementitious materials (SCM) is highly attractive and promising technology reducing the environmental impact of the construction industry and reducing the higher materials costs. This paper presents an experimental study that investigated the mechanical and durability properties of SCCs manufactured with blended binders including fly ash, slag, and micro-silica. A total of 8 batches of SCCs were manufactured. As series of tests were conducted to establish the rheological properties, compressive strength, and durability properties including the water absorption, water permeability, rapid chloride permeability and initial surface absorption of the SCCs. The influences of the SCC strength grade, blended types and content on the properties of the SCCs are investigated. Unified reactive indices are proposed based on the mix proportion and the chemical composition of the corresponding binders are used to assess the compressive strength and strength development of the SCCs. The results also indicate the differences in the underlying mechanisms to drive the durability properties of the SCC at the different strength grades.

Archeological Chemical analysis and Characteristic Investigation on Glass Beads Excavated in Sacheon Neukdo Island, Gyeongsangnam-do (경남 사천 늑도 유적 출토 유리구슬의 고고화학적 특성 고찰)

  • Kwon, Yoon-Mi;Kim, Gyu-Ho;Shin, Yong-Min
    • Journal of Conservation Science
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    • v.20
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    • pp.105-117
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    • 2007
  • This study is examined the beads excavated in the Sacheon Neukdo ruins to investigate the features of archaeological chemistry and to compare those of the same type of beads excavated within the Gyeongsang-do area by means of scientific analysis. The samples have been observed the micro-structures by an optical microscope and SEM and confirmed the physical property by density measurement. Chemical property have been analyzed main components such as flux, stabilizers, and colorants by SEM-EDS. Besides, XRD was used to identified the characteristic materials of beads. The white opaque beads, which was initially estimated as sea-shell beads, confirm as amorphous silica material. The glass beads, which are blue type as a result of compositional analysis, it is revealed potash glass group and LCA(Low-CaO, $Al_2O_3$) system. gB ones are revealed only in LCA-A(LCA-CaO<$Al_2O_3$), while purple blue ones in LCA-B(LCA-CaO>$Al_2O_3$).

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Micro In-situ Tests on Overconsolidated Clay Prepared in Chambers (토조내에 준비된 과압밀 점토에 대한 모형 원위치 시험)

  • Cho Nam Jun
    • Journal of the Korean Geotechnical Society
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    • v.21 no.2
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    • pp.5-16
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    • 2005
  • Tn this study, model soil deposits are prepared in large test chambers to minimize the scale effects. Also, slurry of mixture containing 50 percent kaolin clay and 50 percent silica has been consolidated to simulate the process of natural soil deposit formation and to reduce the consolidation time. To provide a more detailed description of varying soil properties along the soil profile of model clay deposits and to compare the in-situ test results with those from prototype tests, miniature in-situ tests, including vane shear, piezoprobe, and cone penetration tests were conducted in each of the clay deposits. The current results indicate that consistent soil deposits were prepared for the current and previous test programs. Also, reasonable predicting methods of prototype behavior based on model in-situ test results were suggested in this study by examining differences between the test results from both the model and prototype tests.

A Study on the Improvement of Dry Bag Filter Treatment System Regarding harmful gas of Glass Recuperator (유리용해로 가스처리 건식 Bag Filter의 개선에 관한 연구)

  • Lee, Sung-Jin;Seo, Man-Chul
    • Journal of environmental and Sanitary engineering
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    • v.23 no.3
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    • pp.9-22
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    • 2008
  • This study was conducted to develop a system that processes harmful gases and dust, which being generated in the production of micro-inorganic fabric. This can be obtained by melt spinning raw materials such as agalmatolite, fluorspar, limestone, silica under high temperature at $1500-1600^{\circ}C$ in a glass recuperator using a dry method by Cyclone Reactor or Envelope Type (ET) type Bag Filter. If the number of the members of Korea Glass Industry Association reaches up to 45, the damage of the harmful gas being generated in recuperator should not be small. In addition, research of existing facilities showed the most of harmful gas treatment facilities which adopt wet treatment or semi-dry treatment process. This was caused the problems for wastewater and the second pollutive materials. Moreover, in the dust collecting facility behind recuperator, it is also problematic that electric dust collector requires enormous initial investment. We have researched various methods to show both economic and efficient new processes for the preventive facilities of recuperator. As the result of the experiments, the removal efficiencies of HF and SOx were 99% and 87%, respectively. Although it was insignificant reaction, a pretty much interesting result that NOx showed an absorption reaction with $Ca(OH)_2$(removal efficiency was more than 25%) was obtained.

Li2O and Li2CO3 Thin Film Growth by LPMOCVD (LPMOCVD에 의한 Li2O 및 Li2CO3 박막의 증착)

  • Jung, Sang-Chul;Ahn, Ho-Geun;Imaishi, Nobuyuki
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.225-230
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    • 1999
  • Low pressure metal organic chemical vapor deposition (LPMOCVD) of $Li_2O$ solid thin films from Li(DPM) in nitrogen-oxygen or argon-oxygen atmosphere was experimentally investigated by using a small hot wall tubular type reactor. XRD and ESCA analysis revealed that $Li_2CO_3$ film grew in nitrogen-oxygen atmosphere and $Li_2O$ grew in argon-oxygen atmosphere. The grown lithium oxide or carbonate reacted with silicon or silica base materials to produce silicates. The CVD model analysis by means of the well-known micro trench method and Monte Carlo simulation was not fully successful, but a set of data on gas phase reaction rate constant and surface reaction constant was obtained.

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EFFECT OF RESIN AND FILLER TYPE ON THE FRACTURE TOUGHNESS OF UTMA-BASED LIGHT-CURED COMPOSITES (기질레진 필러가 UTMA계 광중합형 복합레진의 파괴인성에 미친는 영향)

  • Ahn, Yun-Sil;Hwang, Su-Jin;Bae, Tae-Sung;Lee, Kwang-Won
    • Restorative Dentistry and Endodontics
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    • v.24 no.4
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    • pp.604-613
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    • 1999
  • This study was performed to evaluate the effect of resin and filler type on the fracture toughness of light-activated composites. Experimental composites were prepared using urethane tetramethacrylate(UTMA) and bisphenol glycidylmethacrylate(Bis-GMA) monomers and five different types of silica fillers. Fracture toughness was measured by a single edge V-notched beam(SEVNB) method, which was discussed from ASTM E399-78. Rectangular bars of $2.5{\times}5{\times}26mm$ were prepared with experimental composites and a notch about 2.25mm deep was carved at the center of the long axis of the specimen using a dental diamond disk driven by a dental micro engine. The flexural test was carried out at a crosshead speed of 0.05mm/min and fracture surfaces were observed under scanning electron microscope. The results obtained were summarized as follows: 1. The fracture toughness values of UTMA-based composites were relatively higher than those of Bis-GMA-based composites. 2. The highest fracture toughness value was observed in the UTMA-based composite containing the $1.5{\mu}m$-spherical fillers. 3 Aging in the distilled water at $37^{\circ}C$ for 10 days showed the increase of fracture toughness, which was severer in the Bis-GMA-based composites than those of UTMA-based composites. 4. The AE amplitude occurring during the fracture toughness tests was the highest at the point of macroscopic fracture.

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Compositional and microstructural analyses of grayish-blue-powdered celadon in Yeongseo Region in Gangwon-do:by Wonju Beopcheon-temple site (강원도 영서지역 출토 분청사기의 조성 및 미세구조 분석: 원주(原州) 법천사지(法泉寺址)를 중심으로)

  • Lee, Byoung-Hoon;So, Myoung-Gi
    • Analytical Science and Technology
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    • v.26 no.3
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    • pp.211-221
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    • 2013
  • This research aims to examine compositional and microstructural properties of grayish-blue-powdered celadon in Wonju Beopcheon-temple site. X-ray fluorescence sequential spectroscopy (XRF) with micro-point analysis, scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) were applied to determine the chemical composition, microstructure and crystallinity of samples, respectively. As a result, the average compositions of bodies were low silica ($RO_2$) and high flux (RO+$R_2O$). Owing to the high content of calcium oxide the glaze is considered lime type between limealkali type. The body of celdon sheard was found quarts, mullite, microcline, albite. Especially, the body's chemical compositions were compared to the results of previous studies by using a Seger formula. The compositional properties of Grayish-blue-powdered celadon in Wonju Beopcheon-temple site showed diffrently from the the other grayish-blue-powdered celadon.

Design, fabrication and characterization of a flap valve mircopump using an ionic polymer-metal composite actuator (이온성 폴리머-금속 복합재료 작동층을 사용한 플랩 밸브 마이크로 펌프의 설계, 개발 및 특성 규명)

  • Nguyen, Thanh Tung;Nguyen, Vinh Khanh;Yoo, Young-Tai;Goo, Nam-Seo
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.4
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    • pp.302-307
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    • 2007
  • In this paper, a flap valve micropump with an ionic polymer-metal composite (IPMC) actuator was designed, fabricated, and experimentally characterized. A multilayered IPMC based on Nafion/layered silicate and Nafion/silica nanocomposites was fabricated for the actuation section of the micropump. The IPMC diaphragm, a key element of the mircopump, was designed so that the IPMC actuator was supported by a flexible polydimethylsiloxane (PDMS) structure at its perimeter. This design feature enabled a significantly high displacement of the IPMC diaphragm. The overall size of the micropump is $20{\times}20{\times}5$ ${mm}^3$. Water flow rates of up to 760 ${\mu}l$/min and a maximum backpressure of 1.5 kPa were recorded. A significant advantage of the proposed micropump is its low driven voltage from only 1-3 V. In addition, a simple and effective design, and an ease of manufacturing are other advantages of the present micropump.

The effect of wollastonite powder with pozzolan micro silica in conventional concrete containing recycled aggregate

  • Dinh-Cong, Du;Keykhosravi, Mohammad. H.;Alyousef, Rayed;Salih, Musab N.A.;Nguyen, Hoang;Alabduljabbar, Hisham;Alaskar, Abdulaziz;Alrshoudi, Fahed;Poi-Ngian, Shek
    • Smart Structures and Systems
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    • v.24 no.4
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    • pp.541-552
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    • 2019
  • Construction development and greenhouse gas emissions have globally required a strategic management to take some steps to stain and maintain the environment. Nowadays, recycled aggregates, in particular ceramic waste, have been widely used in concrete structures due to the economic and environmentally friendly solution, requiring the knowledge of recycled concrete. Also, one of the materials used as a substitute for concrete cement is wollastonite mineral to decrease carbon dioxide (CO2) from the cement production process by reducing the concrete consumption in concrete. The purpose of this study is to investigate the effect of wollastonite on the mechanical properties and durability of conventional composite concrete, containing recycled aggregates such as compressive strength, tensile strength (Brazilian test), and durability to acidic environment. On the other hand, in order to determine the strength and durability of the concrete, 5 mixing designs including different wollastonite values and recovered aggregates including constant values have been compared to the water - cement ratio (w/c) constant in all designs. The experimental results have shown that design 5 (containing 40% wollastonite) shows only 6.1% decrease in compressive strength and 4.9% decrease in tensile strength compared to the control plane. Consequently, the use of wollastonite powder to the manufacturing of conventional structural concrete containing recycled ceramic aggregates, in addition to improving some of the properties of concrete are environmentally friendly solutions, providing natural recycling of materials.