• 제목/요약/키워드: metal mobility

검색결과 342건 처리시간 0.03초

윤활액이 담지된 나노다공성 표면의 최신 응용분야 (Recent applications of lubricant-impregnated nanoporous surface : A Review)

  • 한경완;배기창;이정훈
    • 한국표면공학회지
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    • 제56권1호
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    • pp.1-11
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    • 2023
  • Lubricant-impregnated nanoporous surfaces (LIS), which is created by impregnating water-immiscible oil into nanoporous surface structure, have been explored considering wide range of application fields. Due to the lubricant impregnated in nanoporous structure, the surface shows extreme de-wetting with a high mobility of water droplets, so that various functionalities can be realized. The lubricant layer inhibits the contact of corrosive media to porous structure as well as metal substrate, thus the surface improves the corrosion resistance. The water on the surface freeze without any contact to solid porous structure, showing a low ice adhesion for de-icing an anti-icing. The extremely high mobility of water droplets on lubricant-impregnated porous surfaces also contributes the enhancement of condensation heat transfer as well as water harvesting from fog and moisture. Moreover, the bacteria adhesion on metal surface forming biofilms causing serious hygiene issues can be inhibited on the lubricantimpregnated surfaces. Despite of such superior functionalities, the lubricant-impregnated porous surface has a limitation of lubricant depletion by external flow of fluids. Therefore, extensive efforts to improve the durability of lubricant-impregnated surface are required for practical applications.

The Analysis of the Painting Work Clothes Clothing Comfort and Wearer Mobility Considering the Work Environment in the Machine and Shipbuilding Industries

  • Park, Gin-Ah;Park, Hye-Won;Bae, Hyun-Sook
    • 패션비즈니스
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    • 제16권3호
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    • pp.13-31
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    • 2012
  • The purpose of the study was to analyze the work clothes' clothing comfort and wearer mobility of painting workers with the consideration of the work environment features in the machine and shipbuilding industries in South Korea. A questionnaire survey was conducted for the study, which consisted of questions on the clothing comfort and wearer mobility aspects of painting work clothes by clothes types and body parts. The work clothes' clothing comfort and wearer mobility levels were scaled in 5 points i.e. 1(: very tight/very uncomfortable) to 5(: very slack/very comfortable). The painting work environmental hazardous features were considered as high impact levels of workplace temperature, oxygen deficiency, organic solvent, toxic gas factors while metal fragment factor only impacts 'low' in the painting processes with the findings throughout this study. Since the painting work consisted of surface washing and the spray and touch-up painting processes, which was carried out in an outdoor work place, the painting work clothes should meet high performance of waterproofing from the painting material and air permeability specially in summer as well as thermal performance in winter. The subjects painting workers' assessment of the existing work clothes' clothing oppression was in the levels between 3 (i.e. moderate) and 4 (i.e. comfortable) in a range of 1 to 5 points. The existing painting work clothes' wearer mobility was evaluated 'very uncomfortable' in all work clothes parts, especially, armhole length, biacromial breadth, sleeve length of the jumper; and body rise, waist, hip, thigh and knee circumferences of the pants.

Spectral and Thermal Studies of Transition Metal PSSA Ionomers

  • Shim, Il-Wun;Risen, William M. Jr.
    • Bulletin of the Korean Chemical Society
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    • 제9권6호
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    • pp.368-376
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    • 1988
  • Transition metal PSSA ionomers containing Co(II), Ni(II), Cr(III), Ru(III), and Rh(III) are investigated by IR, Far-IR, UV-Vis and DSC. Reliable IR Spectroscopic criteria are established for assessing the degree of ion-exchange of PSSA ionomers and the local structures around metal cations in them. In the hydrated transition metal PSSA ionomers, the ionic groups are solvated by water molecules and there is no significant interactions between sulfonate group and metal cations. The visible spectra indicated that metal cations are present as [M$(H_2O)_6$]$^{n+}$ with Oh symmetry. Their $T_g$ values increase as the extent of ionic site concentration increases, but there is no direct dependence of $T_g$ on the nature of metal cations or their oxidation states. Thus, the water content in PSSA ionomer is found to have dominant influence on $T_g$ of hydrated transition metal PSSA ionomers. Dehydration of the hydrated transition metal PSSA ionomers results in direct interaction between ionic groups and significant color changes of the ionomers due to the changes of the local structures around metal cations. On the base of spectral data, their local structures are discussed. In case of dehydrated 12.8 and 15.8 mol % transition metal PSSA ionomers, no glass transition is observed in 25-$250^{\circ}C$ region and this is believed to arise from the formation of highly crosslinked structures caused by direct coordination of sulfonate groups of metal cations. In the 6.9 mol % transition metal PSSA ionomers, the glass transition is always observed whether they are hydrated or dehydrated and this is though to be caused by the sufficient segmental mobility of the polymer backbone.

PIII&D (Plasma immersion ion implantation & deposition)를 이용한 a-Ge (amorphous-Germanium) Thin Film의 결정성장

  • Jeon, Jun-Hong;Choi, Jin-Young;Park, Won-Woong;Lim, Sang-Ho;Han, Seung-Hee
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.153-153
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    • 2011
  • 유리나 폴리머를 기판으로 하는 TFT(Thin film transistor), solar cell에서는 낮은 공정 온도에서($200{\sim}500^{\circ}C$) amorphous semiconductor thin film을 poly-crystal semiconductor thin film으로 결정화 시키는 기술이 매우 중요하게 대두 되고 있다. Ge은 Si에 비해 높은 carrier mobility와 낮은 녹는점을 가지므로, 비 저항이 낮을 뿐만 아니라 더 낮은 온도에서 결정화 할 수 있다. 하지만 일반적으로 쓰이는 Ge의 결정화 방법은 비교적 높은 열처리 온도를 필요로 하거나, 결정화된 원소에 남아있는 metal이 불순물 역할을 한다는 문제점, 그리고 불균일한 결정크기를 만든다는 단점이 있었다. 그 중에서도 현재 가장 많이 쓰이고 있는 MIC, MILC는 metal과 a-Ge이 접촉되는 interface나, grain boundary diffusion에 의해 핵 생성이 일어나고, 결정이 성장하는 메커니즘을 가지고 있으므로 단순 증착과 열처리 만으로는 앞서 말한 단점을 극복하는데 한계를 가지고 있다. 이에 PIII&D 장비를 이용하면, 이온 주입된 원소들이 모재와 반응 할 수 있는 표면적이 커짐으로 핵 생성을 조절 할 수 있을 뿐만 아니라, 이온 주입 시 발생하는 self annealing effect로 결정 크기까지도 조절할 수 있다. 또한 이러한 모든 process가 한 진공 장비 내에서 이루어지므로 장비의 단순화와, 공정간 단계별로 발생하는 불순물과 표면산화를 막을 수 있으므로 절연체 위에 저항이 낮고, hall mobility가 높은 poly-crystalline Ge thin film을 만들 수 있다. 본 연구에서는, 주로 핵 생성과정에서 seed를 만드는 이온주입 조건과, 결정 성장이 일어나는 증착 조건에 따라서 Ge의 결정방향과 크기가 많은 차이를 보이는데, 이는 HR-XRD(High resolution X-ray Diffractometer)와 Raman spectroscopy를 이용하여 측정 하였으며, SEM과 AFM으로 결정의 크기와 표면 거칠기를 측정하였다. 또한 Hall effect measurement를 통해 poly-crystalline thin film 의 저항과 hall mobility를 측정하였다.

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주암댐 집수유역 내 하상퇴적물의 중금속 오염현황 및 거동 특성 (Contamination Level and Behavior of Heavy Metals in Stream Sediments Within the Watershed of Juam Reservoir)

  • 염승준;이평구;강민주;신성천;유연희
    • 자원환경지질
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    • 제37권3호
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    • pp.311-324
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    • 2004
  • 전라남도 보성강에 축조된 주암댐의 집수유역 내 하상퇴적물을 대상으로 중금속의 오염현황과 거동 특성을 알아보았다. 주암댐의 집수유역에는 많은 폐금속 및 탄광이 위치하고 있어 주암댐 호저퇴적물에 잠재적인 오염원으로 작용할 수 있다. 집수유역 내 하상퇴적물의 중금속 함량(Cr, Cu, Ni, Pb, Zn)은 매우 낮기 때문에 주암댐의 호저퇴적물에 영향을 줄 것으로 판단되지 않는다. 하지만 폐금속광산지역 내 하상퇴적물의 Pb 함량은 하류로 갈수록 증가하는 경향을 보여, Pb의 오염 확산이 우려된다. 폐금속광산의 환경을 고려한 강산성 조건의 용출실험결과, 하상퇴적물의 용출비로부터 결정된 중금속의 상대적 이동도는 Pb>Zn=Cu>Ni>Cr으로서, Pb이 주암댐 호저퇴적물에 영향을 미치는 원소가 될 수 있음을 지시해준다. 한편 댐으로 유입한 퇴적물이 호저에 놓이게 되면(즉, 환원환경), Pb의 이동도가 비교적 높게 나타나 물-퇴적물 경계에서 Pb의 수중으로 재용출될 수 있다.

ZnO 스퍼터링에서 기판전압의 변화에 의한 성장 조절 (Control of ZnO Sputtering Growth by Changing Substrate Bias Voltage)

  • ;최재원;전원진;조중열
    • 반도체디스플레이기술학회지
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    • 제16권2호
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    • pp.94-97
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    • 2017
  • Amorphous Si has been used for data processing circuits in flat panel displays. However, low mobility of the amorphous Si is a limiting factor for the data transmission speed. Metal oxides such as ZnO have been studied to replace the amorphous Si. ZnO is a wide bandgap (3.3 eV) semiconductor with high mobility and good optical transparency. When ZnO is grown by sputtering with $O_2$ as an oxidizer, there can be many ion species arising from $O_2$ decomposition. $O^+$, $O_2{^+}$, and $O^-$ ions are expected to be the most abundant species, and it is not clear which one contributes to the ZnO growth. We applied alternating substrate voltage (0 V and -70 V) during sputtering growth. We studied changes in transistor characteristics induced by the voltage switching. We also compared ZnO grown by dc and rf sputtering. ZnO film was grown at $450^{\circ}C$ substrate temperature. ZnO thin-film transistor grown with these methods showed $7.5cm^2/Vsec$ mobility, $10^6$ on-off ratio, and -2 V threshold voltage.

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저분자 유기산을 이용한 폐금속광산 주변토양 정화 (Remediation of Soil Surrounding Abandoned Metal Mine By Using Low Molecular Weight Organic Acid)

  • 이동호;박옥현
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 1998년도 공동 심포지엄 및 추계학술발표회
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    • pp.183-188
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    • 1998
  • The efficiency of removing cadmium, copper, and lead from a contaminated soil of abandoned metal mine was studied in a laboratory investigation where citric acid were used to extract the metal from the soil. The contamination level of Pb, Cu in the soil A were 875.5, 667.5mg/kg respectively. The mobility and bioavailability of the metals in soil were also estimated by Sequential Chemical Extractions. Citric acid were examined for its potential extractive capabilities. Concentrations of the acid examined in this study ranged from 0.025 to 0.15M. The pH of the suspensions and S/S ratio in which the extractions were performed ranged from 2.4 to 8.1, and from 2.1:1 to 20:1. Results showed that the removal of contaminant using citric acid was pH and S/S raton dependent.

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회로 레벨의 신뢰성 시뮬레이션 및 그 응용 (Circuit-Level Reliability Simulation and Its Applications)

  • 천병식;최창훈;김경호
    • 전자공학회논문지A
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    • 제31A권1호
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    • pp.93-102
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    • 1994
  • This paper, presents SECRET(SEC REliability Tool), which predicts reliability problems related to the hot-carrier and electromigration effects on the submicron MOSFETs and interconnections. To simulate DC and AC lifetime for hot-carrier damaged devices, we have developed an accurate substrate current model with the geometric sensitivity, which has been verified over the wide ranges of transistor geometries. A guideline can be provided to design hot-carrier resistant circuits by the analysis of HOREL(HOT-carrier RFsistant Logic) effect, and circuit degradation with respect to physical parameter degradation such as the threshold voltage and the mobility can also be expected. In SECRET, DC and AC MTTF values of metal lines are calculated based on lossy transmission line analysis, and parasitic resistances, inductances and capacitances of metal lines are accurately considered when they operate in the condition of high speed. Also, circuit-level reliability simulation can be applied to the determination of metal line width and-that of optimal capacitor size in substrate bias generation circuit. Experimental results obtained from the several real circuits show that SECERT is very useful to estimate and analyze reliability problems.

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Development of 2 inch LTPS-TFT AMOLED on Flexible Metal Foil

  • Park, Dong-Jin;Moon, Jae-Hyun;Kim, Yong-Hae;Chung, Choong-Heui;Lee, Myung-Hee;Lee, Jin-Ho;Song, Yoon-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.1111-1114
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    • 2006
  • We have developed a 2 inch LTPS-TFT AMOLED display with a top emission structure on a $50-{\mu}m-thick$ metal foil. The Active matrix back planes were fabricated with the p-channel LTPS TFT with a conventional pixel circuit consisting of 2 transistors and 1 capacitance. The p-channel TFTs on the metal foil exhibited the field-effect mobility of $22cm^2/Vs$. Finally, a images from prototype monochrome AMOLED displays are successfully presented, with $64{\times}88$ pixels and 56-ppi resolution.

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OTFT용 용액공정의 에틸렌-브리지드 실세스퀴옥산 게이트 절연체 (Solution-Processed Gate Insulator of Ethylene-Bridged Silsesquioxnae for Organic Field-Effect Transistor)

  • 이덕희;정현담
    • 통합자연과학논문집
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    • 제3권1호
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    • pp.7-18
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    • 2010
  • Ethylene-bridged silsesquioxane resins were synthesized from two monomers: 1,2-bis(trimethoxysilyl)ethane and methyltrimethoxysilane. The silsesquioxane thin films were spin-coated from the copolymerized resins on silicon wafer. Metal insulator metal (MIM), metal insulator semiconductor (MIS) devices were utilized to investigate the electrical properties of the copolymerized thin films. As the films were inserted as gate insulator in the OTFT devices, the field effect mobilitites were evaluated by employing Poly(3-hexylthiophene) (P3HT) as organic semiconductor, which shows that their dielectric properties and mobility values are dependent on the molecular structures and Si-OH concentration involving in the films.