• Membrane Journal
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• v.9 no.4
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• pp.209-214
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• 1999

The purpose of this research was to investigate the permeation properties of each stage in three stage reverse osmosis system for cold-mill wastewater reuse. After construction of the three staged pilot plant which had 75% recovery and equipped with seven plate-and-frame modules, the change of each stage's penneate flow and quality were investigated in the process of membrane fouling. The order of average permeate flow was first, second, and third stage at the beginning. As the operation time passed, the permeate flow of first stage was decreased, the second stage was maintained steadily, and the third stage was increased. Accordingly, the fouling was initiated at the first stage and then progressed to the second and third stage. The first stage's permeate quality showed the best and the second and third stage was the next in that order. And the order of quality was maintained during the test periods. Therefore, the permeate quality was not affected by membrane fouling.

• Membrane Journal
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• v.17 no.4
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• pp.359-368
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• 2007

The copolymer membranes, poly(vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) were prepared by phase inversion method using as an additive with N,N-dimethylformamid as a solvent. The pores are generated during the solvent and non-solvent exchange process in the coagulation bath filled with non-solvent (distilled water). The highest porosity of the membrane was 60%. The surface and cross-section of the membranes was observed with a scanning electron microscopy (SEM). The mechanical property of the membrane was determined by using an universal testing machine (UTM). Tensile strength of measured membranes is presented the maximum 6.57 MPa at 30 wt% of PVdF-HFP.

• Membrane Journal
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• v.16 no.1
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• pp.9-15
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• 2006

PVA/SSA/HPA composite membranes were prepared by the addition of SSA as a crosslinking agent and HPA such as PWA or SiWA. The water uptake decreased and the IEC increased as the HPA contents increased in PVA/SSA/HPA composite membranes. XRD results showed that HPA distributed well into the composite membranes as the HPA concentration increased, and SiWA dispersed better than PWA in the composite membranes. TGA results showed that PVA/SSA composite membranes were more heat-resistant than PVA due to the crosslinking of PVA, and the heat stability of the composite membranes improved much more as the concentration of HPA increased. The methanol barrier property of PVA/SSA/HPA composite membranes was superior to Nafion, and the methanol permeability of the composite membranes decreased as the concentration of HPA increased.

• Membrane Journal
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• v.31 no.5
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• pp.363-370
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• 2021

Organic solvent resistant hollow fiber membranes were fabricated via a thermally induced phase separation (TIPS) method using Polyketone polymer, a material with excellent resistance to organic solvents. The PEG300, DMSO₂ and Glycerine called the "green solvents" were used as diluents for TIPS method. The spherulite structure was formed with DMSO₂ by S-L phase separation behavior whereas the bicontinuous structures were formed with PEG300 and Glycerine, respectively. The morphology of the PK hollow fiber membranes was investigated using SEM. The pure water permeability and the durability test were conducted to understand the permeation properties of PK hollow fiber membranes. The tensile strength test was conducted for the property of mechanical strength. In this study, the fabrication of PK hollow fiber membranes with various diluents was discussed to understand the correlation between diluent and polymer in detail.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.12
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• pp.1563-1571
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• 2011

In this study, we developed a finite element model of the human middle ear has been developed to calculate itsfor sound transfer characteristics calculation. We usedThe geometric data forof ossicles, obtained byfrom micro-CT scanning, was used in order to develop the middle- ear FE model. A right- side temporal bone of a Korean cadaver was used for the micro-CT scanning. The developed FE model includes three ossicles, the tympanic membrane, ligaments, and muscles. We calculated theA sound transfer function from the tympanic membrane to the stapes footplate was calculated. The sound transfer function calculated vias of the FE model shows good agreement with measured responses over the 10- kHz frequency band. To measureidentify the sensitivityies of the middle- ear function due to material property variation, we studied several parameters studies have been fulfilled using the middle ear FE model. TAs a result the stiffness property of the incudostapedial joint had the greatest influence onwas the most influential to the middle- ear sound transfer function among the parameters.

• Membrane Journal
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• v.29 no.6
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• pp.339-347
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• 2019

Forward osmosis (FO) is operated at a lower pressure than reverse osmosis (RO), which has great advantages in terms of fouling control, maintenance, membrane cleaning, and potential energy reduction. In particular, since the membrane fouling layer of the forward osmosis process has a relatively loose and dispersed property, it is possible to control the membrane fouling by physical cleaning, unlike the reverse osmosis process. However, existing studies do not apply the proper cleaning flow rate for forward osmosis physical cleaning, and thus there is a limit that the optimal operation can not be performed. Therefore, this study aims to evaluate the justification of proper flow rate that can show high efficiency cleaning with economical energy amount. The membrane fouling experiments of the forward osmosis process were maintained at a circulating flow rate of 8.54 cm/s and the recovery rates were compared with the three cleaning flow rates. As a result of this experiment, it was confirmed that the 2 × speed cleaning showed the same efficiency as the water permeability recovery rate of the 3 × speed cleaning, and it was confirmed that the 2 × speed cleaning was an appropriate flow rate with high cleaning efficiency and economical SEC.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.7
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• pp.753-761
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• 2005

In this study, pretreatment of organic matters with $MIEX^{(R)}$ was evaluated using bench-scale experimental procedures on four organic matters to determine its effect on subsequent UF membrane filtration. For comparison, coagulation process was also used as a pretreatment of UF membrane filtration. Moreover, the membrane fouling potential was identified using different fractions and molecular weights of organic matters. From the removal property of MW organic matters by coagulation process for the sample water NOM and AOM, the removal efficiency of high MW organic matters were much higher than those of low MW organic matters. It was shown that the removal efficiency of high MW organic matter more than 10 kDa was lower than that of low MW organic matter for $MIEX^{(R)}$ process. For the change of permeate flux by the pretreatment process, $MIEX^{(R)}$+UF process showed high removal efficiency of organic matter as compared with coagulation-UF processes, but high reduction rate of permeate flux was presented through the reduction of removal efficiency of high MW organic matter. From sequential filtration test results in order to examine the effect of MW of organic matter on membrane fouling, it was found that the membrane foulant was occurred by high MW organic matter, and the DOC of organic matter less than 0.5 mg/L was working as the membrane foulant. In the case of sample water composed of low MW organic matter less than 10 kDa, since the low MW organic matter less than 10 kDa has high removal efficiency by $MIEX^{(R)}$, low reduction rate of permeate flux is obtained as compared with coagulation-UF processes. In summary, it is required to conduct the research on physical/chemical characteristic of original water before pretreatment process of membrane process is selected, and a pertinent pre-treatment process should be employed based on the physical/chemical characteristic of original water.

• Membrane Journal
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• v.31 no.2
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• pp.101-119
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• 2021

The demand for clean water is virtually present in all modern human societies even as our society has developed increasingly more advanced and sophisticated technologies to improve human life. However, as global climate change begins to show more dramatic effects in many regions in the world, the demand for a cheap, effective way to treat wastewater or to remove harmful bacteria, microbes, viruses, and other solvents detrimental to human health has continued to remain present and remains as important as ever. Well-established synthetic membranes composed of polyaniline (PANI), polyvinylidene fluoride (PVDF), and others have been extensively studied to gather information regarding the characteristics and performance of the membrane, but recent studies have shown that making these synthetic membranes conductive to electrical current by doping the membrane with another material or incorporating conductive materials onto the surface of the membrane, such as allotropes of carbon, have shown to increase the performance of these membranes by allowing the adjustability of pore size, improving antifouling and making the antibacterial property better. In this review, modern electrically conductive membranes are compared to conventional membranes and their performance improvements under electric fields are discussed, as well as their potential in water filtration and wastewater treatment applications.

• Korean Journal of Materials Research
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• v.22 no.5
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• pp.227-236
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• 2012

Ionomer is a thermoplastic that is composed of covalent bonds and ionic bonds. It is possible to use this material in processes such as injection molding or extrusion molding due to the material's high oil resistance, weatherproof characteristics, and shock resistance. In this study, a new ionomer having a multifunctional group was prepared by a stepwise neutralization system with the addition of acidic and salt additives. In step I, to increase the contents of the multifunctional group and the acid degree in ethylene acrylic acid (EAA), MGA was added to the ionomer resin (EAA). A new ionomer was prepared via the traditional preparation method of the ionic cross-linking process. In step II, metal salt was added to the mixture of EAA and MGA. The extrusion process was performed using a twin extruder (L/D = 40, size : ${\varphi}30$). Ionomer film was prepared for evaluation of gas permeability by using the compression molding process. The degree of neutralized and ionic cross-linked new ionomer was confirmed by FT-IR and XRD analysis. In order to estimate the neutralization of the new ionomer film, various properties such as gas permeation and mechanical properties were measured. The physical strength and anti-scratch property of the new ionomer were improved with increase of the neutralization degree. The gas barrier property of the new ionomer was improved through the introduction of an ionic site. Also, the ionic degree of cross-linking and gas barrier property of the ionomer membrane prepared by stepwise neutralization were increased.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.9
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• pp.542-547
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• 2017

This paper was to analyze the membrane characterization of hydrophilicity, surface morphology and membrane chemical anlysis of three commercial microfiltration/ultrafiltration membranes, and evaluate the filtration performance of a seawater to assess the availability for pretreatment of desalination process. From the results of contact angle, Mem-3, fabricated with polyacrylonitrile, was highly hydrophilic. It find out that Mem-3 has more anti-biofouling property. In Field emission scanning electron microscope (FESEM), Mem-1 (polyethylene) and Mem-2 (Polyvinylidenefluoride) showed the sponge-like shape and Mem-3 showed finger-like shape. Membrane chemical analysis by energy dispersive spectrometer (EDS) presented that Mem-2 was mostly fluoride and Mem-3 had s high ratio of N (32.47%) due to the nitrile group. The permeation flowrate per time on suction pressures using deionized water (D.I. water) tends that permeation rate of Mem-3 more increased when the pressure was increased compared to other membranes. From the results of turbidity and total suspended solids (TSS) removal, turbidity of permeate was 0.191 NTU to 0.406 NTU and TSS was 2.2 mg/L to 3.0 mg/L in all membranes, indicating that it was not suitable for the pretreatment of seawater desalination by short-term experiments.