• Title/Summary/Keyword: melt-electrospun fiber

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Effects of Melt-viscosity of Polyethylene Mixtures on the Electrospun-fiber Diameter Using a Oil-circulating Melt-electrospinning Device (열매유형 용융전기방사장치를 이용한 폴리에틸렌 혼합물의 용융점도와 섬유직경의 상관관계 연구)

  • Yang, Hee-Sung;Kim, Hyo-Sun;Na, Jong-Sung;Seo, Young-Soo
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.518-524
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    • 2014
  • Electrospinning has gained interests as a polymer processing technique for nanofiber fabrications. It is well known that both polymer solutions and polymer melts can be electrospun. Among them, melt electrospinning is environmentally friendly technique due to the absence of solvent. However, the diameter of melt-electrospun fibers is typically thicker than solution-electrospun fibers. By using a home-made melt-electrospinning device, micron-sized fibers with smooth and even surfaces were electrospun successfully. We demonstrate that low-density polyethylene fibers can be reduced in diameter with a viscosity-reducing additive such as low molecular weight polyethylene monoalcohol and polyethylene wax. The diameter was further reduced by blending it with oxidized polyethylene wax due to polarity increment. Additionally, parameters affecting the diameter were analyzed such as an applied voltage and a spinning distance.

Fabrication of Polycarbonate Nano Fibers Using Electrospinning (전기방사법을 이용한 Polycarbonate 나노 섬유 제조)

  • Kim Giltae;Park Sangkyoung;Lee Jaekeun;Ahn Youngchull
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.4 s.235
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    • pp.512-518
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    • 2005
  • Polymeric fibers with nanometer-scale diameters are produced by electrospinning. When the electrical forces at the surface of a polymer solution or melt overcome the surface tension then electrospinning occurs. Polycarbonate has been electrospun. Electrospun fibers are observed by scanning electron microscopy and transmission electron microscopy. The surface morphology of e-spun fiber has been studied by many variables that are involved in different polymer concentrations, solvent mixing ratios and ambient parameters. The average diameters of the electrospun fibers range from 200 nm to 4,570 nm when the PC concentration is decreasing from 15.5\;wt{\%}\;to\;25\;wt{\%}.$ The higher concentration of the polymer solution makes the fibers thicker due to preventing the fiber stretching. With respect evaporation effects, the solvent mixing ratios cause significant changes of the fiber size distribution. As a matter of fact the fiber diameter steadily increases with increasing amount of DMF until the solvent mixture is at THF:DMF ratio of 60:40.

Fabrication of Polymer Nanofibers using Electrospinning (전기방사법을 이용한 고분자 나노섬유 제조)

  • Kim, Gil-Tae;Ahn, Young-Chull;Lee, Ju-Young;Choi, Jae-Won;Shin, Hee-Soo;Lee, Jae-Keun;Sung, Chang-Mo
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1869-1874
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    • 2003
  • Polymeric fibers with nanometer-scale diameters are produced by electrospinning. When the electrical forces at the surface of a polymer solution or melt overcome the surface tension then electrospinning occurs. Polyethylene oxide (PEO), Polycarbonate have been electrospun in our laboratory. Electrospun fibers are observed by optical microscopy or scanning electron microscopy. The average diameters of the electrospun fibers range from 300 nm to 30 nm when the electric field strength increasing from 1 kV/cm to 3 kV/cm. The average diameters of the electrospun fibers range from 200 nm to 30 nm when the concentration decreasing from 10 wt% to 4 wt%.

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Effects of Molecular Weight and Temperature on Fiber Diameter of Poly(ε-caprolactone) Melt Electrospun Fiber

  • Ko, Junghyuk;Jun, Seungwon;Lee, Jason Keonhag;Lee, Patrick C.;Jun, Martin B.G.
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.24 no.2
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    • pp.160-165
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    • 2015
  • The 14k, 45k, and 70k Mw PCL have different crystallization temperatures and therefore have slightly different characteristics affecting the fiber diameter. To observe these behaviors, the fiber was produced at every step of $10^{\circ}C$ for each molecular weights and the diameter was measured. Moreover, the fiber was fabricated over the cooled ground plate to observe the change in fiber diameter in comparison to the normal ground plate. In case of molecular Mw 14k PCL, the diameter increased as the temperature increased. For Mw 45k PCL, the fiber diameter decreased as the temperature increased. As of Mw 70k PCL, the fiber diameter decreased with increasing temperature as well. When the experiment was conducted over the cooled collector plate, the data did not change significantly from the previous lexperiments.

Characterization of Electrospun Nylon 66 Fiberwebs (전기방사 나일론 66 섬유웹의 특성화)

  • Lee, Young-Soo;Park, Sung-Shin;Lee, Chung-Jung;Joo, Chang-Whan
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.165-168
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    • 2003
  • Nylon was the first commercialized synthetic fiber. It is a polyamide, derived from a diamine and dicarboxylic acid. The nylon fiber has outstanding durability and excellent physical properties such as stiffness, wear and abrasion resistance, friction coefficient and chemical resistance. Due to these properties of nylon 66, nano-sized fibers are produced by electrospinning method in this study. During the past years the nylon 66 fibers have been prepared by conventional melt spining. (omitted)

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Preparation of Electrospun PI-based ACF Web for Electrode of Electric Double Layer Capacitior(EDLC) (정전기 방사에 의한 EDLC 전극용 폴리이미드계 활성탄소섬유 웹의 제조)

  • Choi, Young-Ok;Kim, Chan;Yang, Gab-Seung
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.134-137
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    • 2003
  • 탄소섬유나 활성탄소섬유(activated carbon fiber, ACF)는 일반적으로 출발물질에 따라 polyacrylonitrile(PAN)계, 아크릴(acryl)계, 피치(pitch)계, 페놀(phenol)계 등으로 분류할 수 있다. 보통 습식, 용융 혹은 용융분사(melt-blown) 방사 방법에 의해 섬유 형태로 형성한 다음 산화성 가스 분위기에서 불융화 과정을 거쳐 열에 대한 안정성을 부여하여 불활성 분위기에서 탄소화하여 탄소섬유를 제조하거나, 수증기나 이산화 탄소와 같은 산화성 분위기에서 활성화하여 활성탄소섬유를 제조한다. (중략)

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Development of Electrospun Cellulose Acetate Membranes using Carbon Nanotubes for Filtration of Particulate Matter in the Air (전기방사를 이용한 탄소나노튜브 폴리머 공기정화 멤브레인 개발)

  • Park, Soyeon;Kim, Jaehyuk;Han, Sangil
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.68-73
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    • 2017
  • The removal of particulate matter ranging from $0.01{\mu}m{\sim}10{\mu}m$ can be performed by using membrane filters composed of fibers. Electrospinning techniques offer the production of very thin fibers with a uniform fiber diameter over conventional techniques including template synthesis, melt-blown, phase separation, etc. Air filtration will be improved with electrospun membranes due to the open pore structures, high porosity, and large surface area of the membranes. In the present study, filtration efficiency increased with pore size decrease and fiber density increase induced by carbon nanotube and the increased CA (cellulose acetate) concentration during electrospinning process.

Development Trend of Nanofiber Filter (나노섬유 필터의 개발 동향)

  • Kang Inn-Kyu;Kim Young-Jin;Byun Hong-Sik
    • Membrane Journal
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    • v.16 no.1
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    • pp.1-8
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    • 2006
  • Nanofiber is a broad phrase generally referring to a fiber with diameter less than 1 micron. Various polymers have been successfully electrospun into nanofibers in recent years. These nanofibers, due to their high surface area and porosity, have a great potential for use as filter medium, adsorption layers in protective clothing, etc. Nanofiber filters will enable new levels of filtration performance in the field of air filtration. In particular, nanofibers provide marked increases in filtration efficiency at relatively small pressure drop in permeability. Therefore, nanofiber filters could be substituted for conventional filter market due to the easy application of process and the possibility of coating to micron-sized non-woven sheets. This review is discussed on the trend of researche and development related to nanofiber filter including future marketability.