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Fabrication of Polycarbonate Nano Fibers Using Electrospinning

전기방사법을 이용한 Polycarbonate 나노 섬유 제조

  • Published : 2005.04.01

Abstract

Polymeric fibers with nanometer-scale diameters are produced by electrospinning. When the electrical forces at the surface of a polymer solution or melt overcome the surface tension then electrospinning occurs. Polycarbonate has been electrospun. Electrospun fibers are observed by scanning electron microscopy and transmission electron microscopy. The surface morphology of e-spun fiber has been studied by many variables that are involved in different polymer concentrations, solvent mixing ratios and ambient parameters. The average diameters of the electrospun fibers range from 200 nm to 4,570 nm when the PC concentration is decreasing from 15.5\;wt{\%}\;to\;25\;wt{\%}.$ The higher concentration of the polymer solution makes the fibers thicker due to preventing the fiber stretching. With respect evaporation effects, the solvent mixing ratios cause significant changes of the fiber size distribution. As a matter of fact the fiber diameter steadily increases with increasing amount of DMF until the solvent mixture is at THF:DMF ratio of 60:40.

Keywords

References

  1. Lee, S. G., Choi, S. S. and Joo, C. W., 2002, 'Nanofiber Formation of Poly(etherimide) under Various Electrospinning Conditions,' Journal of the Korean Fiber Society, Vol. 39
  2. Jo, S. M., Lee, W. S. and Chun, S. W., 2002, 'Nanofiber Technology and Applications,' Fiber Technology and Industry, Vol. 6
  3. Kim, G. T. and Lee, J. K., 2002, 'Electrospinning Process of Polyethylene Oxide Nanofibers,' Proceedings of the 4th Cross Straits Symposium, pp. 176-177
  4. Ku, B. K. and Kim, S. S., 2002, 'An Experimental Study on Characteristics of Droplet Generation by Electrospraying for Highly Viscous Liquids,' Trans. of the KSME (B), Vol. 26, No. 4, pp. 603-613
  5. Buchko, C. J., Chen, L. C., Shen, Y. and Martin, 1999, 'Processing and Microstructural Characterization of Porous Bipcompatible Protein Polymer Thin Films,' Polymer, Vol. 49, pp. 7397-7407 https://doi.org/10.1016/S0032-3861(98)00866-0
  6. Deitzel, J. M., Kleinmeyer, J., Harris, D. and Beck Tan, N. C., 2001, 'The Effect of Processing Variables on Morphology of Electrospun Nanofibers and Textiles,' Polymer, Vol. 42, pp. 261-272 https://doi.org/10.1016/S0032-3861(00)00250-0
  7. Shin, Y. M., Holman, M. M., Brenner, M. P. and Rutledge, G. C., 2001, 'Electrospinning: A Whipping Fluid Jet Generates Submicron Polymer Fibers,' Applied physics letters, Vol. 78, No. 8, pp. 1149-1151 https://doi.org/10.1063/1.1345798
  8. Shin, Y. M., Holman, M. M., Brenner, M. P. and Rutledge, G. C., 2001, 'Experimental Characterization of Electrospinning: the Electrically Forced Jet and Instabilities,' Polymer, Vol. 42, pp. 9955-9967 https://doi.org/10.1016/S0032-3861(01)00540-7
  9. Fong, H., Chun, I. and Reneker, D. H., 1999, 'Beaded Nanofibers Formed During Electrospinning,' Polymer, Vol. 40, pp. 4585-4592 https://doi.org/10.1016/S0032-3861(99)00068-3
  10. Doshi, J. and Reneker, D. H., 1995, 'Electrospinning Process and Applications of Electrospun Fibers,' Journal of Electrostatics, Vol. 35, pp. 151-160 https://doi.org/10.1016/0304-3886(95)00041-8
  11. Kenawy, E., Layman, J. M., Watkins, J. R., Bowlin, G. L., Mattews, J. A., Simpson, D. G. and Wenk, G. E., 2003, 'Electrospinning of Poly (ethylene-co-vinyl alcohol) Fibers,' Biomaterials, Vol. 24, pp. 907-913 https://doi.org/10.1016/S0142-9612(02)00422-2

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