• Title/Summary/Keyword: maximum storage ratio

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Structural and Electrochemical Properties of Li2Mn0.5Fe0.5SiO4/C Cathode Nanocomposite

  • Chung, Young-Min;Yu, Seung-Ho;Song, Min-Seob;Kim, Sung-Soo;Cho, Won-Il
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4205-4209
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    • 2011
  • The $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ silicate was prepared by blending of $Li_2MnSiO_4$ and $Li_2FeSiO_4$ precursors with same molar ratio. The one of the silicates of $Li_2FeSiO_4$ is known as high capacitive up to ~330 mAh/g due to 2 mole electron exchange, and the other of $Li_2FeSiO_4$ has identical structure with $Li_2MnSiO_4$ and shows stable cycle with less capacity of ~170 mAh/g. The major drawback of silicate family is low electronic conductivity (3 orders of magnitude lower than $LiFePO_4$). To overcome this disadvantage, carbon composite of the silicate compound was prepared by sucrose mixing with silicate precursors and heat-treated in reducing atmosphere. The crystal structure and physical morphology of $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ was investigated by X-ray diffraction, scanning electron microscopy, and high resolution transmission electron microscopy. The $Li_2Mn_{0.5}Fe_{0.5}SiO_4$/C nanocomposite has a maximum discharge capacity of 200 mAh/g, and 63% of its discharge capacity is retained after the tenth cycles. We have realized that more than 1 mole of electrons are exchanged in $Li_2Mn_{0.5}Fe_{0.5}SiO_4$. We have observed that $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ is unstable structure upon first delithiation with structural collapse. High temperature cell performance result shows high capacity of discharge capacity (244 mAh/g) but it had poor capacity retention (50%) due to the accelerated structural degradation and related reaction.

Performance of the Electrode for All-vanadium Redox Flow Battery (바나듐 레독스 흐름 전지용 전극의 성능 평가)

  • IN, DAE-MIN;SONG, YOUNG-JOON;LEE, DAE-YEOP;RYU, CHEOL-HWI;HWANG, GAB-JIN
    • Journal of Hydrogen and New Energy
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    • v.28 no.2
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    • pp.200-205
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    • 2017
  • The three electrodes (carbon felt) were tested in all-vanadium redox flow battery (VRFB) to confirm the its usefulness. The electrode property was measured by the CV (cyclic voltammetry) method. The current ratio of maximum peak(IPA/IPC) in GF040BH5 and GF051BH3 had almost the same value compared to that in XF30A. The performances of VRFB using the each electrode were measured during 5 cycles of charge-discharge at the current density of $60mA/cm^2$. An average energy efficiency of the VRFB was 77.8%, 77.3%, and 79.2% for XF30A, GF040BH5 and GF051BH3, respectively. It was confirmed from the data that GF040BH5 and GF051BH3 is well suited for use in a VRFB as a electrode, like XF30A.

The Analysis of Critical Duration of uncontrolled single detention facility in Small Catchment (소규모 유역에서 자연방류형 단일저류지의 임계지속기간 분석)

  • Park, Jong-Young;Shin, Chang-Dong;Lee, Jung-Sik
    • Journal of the Korean Society of Hazard Mitigation
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    • v.5 no.2 s.17
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    • pp.17-28
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    • 2005
  • The objective of this study is to evaluate the critical duration between detention facility and flood control facility of small size catchment. 4 small size catchments are applied for hydrological analysis and rainfall excess is computed by using the NRCS Runoff Curve Number method. The critical duration of detention facility and flood control facility is evaluated using the concept of allowable release rate. The conclusions studied in this study are as follows; (1) The type of temporal pattern of design rainfall which causes maximum storage ratio has resulted in Huff's 2 quartile in case of the use of the concept of allowable release rate. (2) Based on (1) of conclusion, the critical durations of flood control facility are similar to those of detention facility, which is used for uncontrolled single detention pond.

Optimization of the Large Scale Magnetic Pulse Compression System of 100 ns-order (100 ns급 대용량 자기펄스 압축시스템의 최적화)

  • 이용우;이영우
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2003.10a
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    • pp.442-445
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    • 2003
  • In this study, we developed the 40 J-class MPC(magnetic pulse compression) system for exciting excimer laser and investigated the optimal conditions of each stage of MPC circuit. This system consists of a DC power supply, a pulse transformer and four saturable inductors. The number of turns of saturable inductors at each stage of MPC circuit are 140, 25, 5, 1 and the optimal storage capacitance of each stage are 34 nF, 28.9 nF, 22.1 nF, respectively. In the improvement MPC system, we have obtained an output voltage of 43 kV, a current of 8.25 kA and a pulse duration of 360 ns. Also, the maximum pulse compression ratio of 77.7 and the current gain of 71.7 were obtained.

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Effect of Addition of Dietary Fibers on Quality of Backsulgies (식이섬유 첨가에 의한 백설기의 특성변화에 관한 연구)

  • Choi, In-Ja;Kim, Young-A
    • Korean journal of food and cookery science
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    • v.8 no.3
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    • pp.281-289
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    • 1992
  • The physicochemical, rheological and sensory characteristics of Backsulgies added with dietary fibers-cellulose, pectin and wheat bran-were investigated. The maximum acceptable ratio of fibers was 10% for wheat bran or cellulose, 3% for pectin. As me results of physicochemical analysis, cellulose and pectin had larger water-binding capacity man wheat bran. Swelling power was increased with temperature increment. But the type of added dietary fiber did not make significant differences. The degree of gelatinization was measured by maltose content. The retrogradation of backsulgies was significantly delayed by the addition of dietary fibers. The retardation effect of dietary fibers for retrogradation of backsulgies was also proved by textural analysis and time constant determination of Avrami equation. Pectin had especially excellent delaying effect while me storage time extended. There were no significant differences in sensory characteristics between me backsulgi with no dietary fibers and backsulgies added with cellulose 3%, pectin 1% and wheat bran 3%. Therefore, we concluded mat cellulose 3%, pectin 1% and wheat bran 3% were me optimum addition ratios, which have the delaying effect of retrogradation, and which could be accepted as same as conventional backsulgies organoreptically.

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Application of an electroless copper coating in alkaline bath to preparation of the metal hydride electrode (금속 수소화물 전극제조에 있어서 알카리 무전해 구리 도금법의 응용)

  • CHOI, Jeon;PARK, Choong-Nyeon
    • Journal of Hydrogen and New Energy
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    • v.3 no.2
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    • pp.9-15
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    • 1992
  • Electroless copper plating method using an alkaline bath have been employed in copper coating of the (LM)Ni4.5Co0.1MnO.2A10.2 hydrogen storage alloy powders for electrode preparation. The plating were conducted without any pretreatment of alloy powders. For the preparation of the electrodes, about 0.12g of the copper coated alloy powder (copper to alloy ratio 1/3 by weight) was compacted with pressure of 6 tons/cm2 at room temperature. The disk-type compacts had a diameter of 10mm and thickness of about 0.24mm. The electrode characteristics were examined through SEM observations and electrochemical measurements in a half cell. The electrochemical measurement showed that the maximum discharge capacity of the electrodes prepared by using alkaline bath were 245mAh per gram of coated alloy (327mAh per gram of alloy) and appeared a considerable degradation with increasing number of cycles. The decrease of the discharge capacity after 100 cycles was about 30% It can be suggested that, with a slight of improvement, this electroless copper plating method could be applied to the preparation of the rare earth-nickel based alloy electrode.

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Emission Characteristics of Odorous Sulfur Gases from Food Types: A Case Study on Boiled Egg, Milk, Canned Meat, and Strawberry (음식물의 악취 황화합물 발생특성 조사: 계란, 우유, 고기통조림, 딸기에 대한 사례 연구)

  • Kim, Bo-Won;Ahn, Jeong-Hyeon;Kim, Ki-Hyun;Jo, Sang-Hee
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.5
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    • pp.615-624
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    • 2013
  • In this study, the emission patterns of reduced sulfur compounds (RSC) were investigated using four different types of food samples (boiled egg, milk, canned meat and strawberry) between fresh and decaying stages. To this end, the concentrations of RSCs were measured at storage days of 0, 1, 3, 6, and 9 under room temperature. Four sulfur compounds ($H_2S$, $CH_3SH$, DMS and DMDS) were selected as target compounds along with two reference compounds ($CS_2$ and $SO_2$). Their concentrations were quantified using GC-PFPD equipped with thermal desorption (TD) system. The boiled egg showed the highest concentration of $H_2S$ (3,655 ppb) at D-1, while $CH_3SH$ reached its maximum value of 64.4~78.5 ppb after 3 days. In milk samples, concentration of $CH_3SH$, DMS, and DMDS went up to 487, 16.3, and 578 ppb, respectively with the progress of decay (D-9). In case of canned meat, concentration of $H_2S$ and $CH_3SH$ peaked in the beginning (D-0) such as 345 and 66.6 ppb. In case of strawberry, $CH_3SH$ and DMDS showed the maximum concentrations 135 and 50.5 ppb at D-1, respectively. The olfactometry dilution-to-threshold (D/T) ratio by air dilution sensory (ADS) test showed similar patterns when sum of odor intensity (SOI) was derived via conversion of odorant concentration data. The results of this study confirm that the time of strong RSC emissions is distinguished for each food type between fresh (e.g., strawberries) and decaying conditions (e.g., milk).

Optical information storage using diffraction properties of volume hologram in Fe-LiNbO$_3$ crystal (Fe-LiNbO$_3$결정에서 부피형 홀로그램의 회절특성을 이용한 광정보 저장)

  • An, Jun-Won;Kim, Nam;Lee, Kwon-Yeon
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.6
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    • pp.63-71
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    • 1998
  • In this paper, we experiment the characteristics of coupling coefficient, gain, diffraction efficiency and dependence of time determined by TWM(Two-Wave Mixing), using Fe-LiNbO$_3$ crystal(doped with 0.015Wt.%). From these results, we proposed to apply for optical memory application. The highest coupling angle of 14。 and maximum coupling coefficient of 6.9$cm^{-1}$ / are obtained at 514.5nm wavelength. Also, maximum diffraction efficiency is 54.13% when intensity ratio and writing beam incident angle are 0.1 and 14o, respectively. After fixing process, diffraction efficiency is 21.4%. As an example, we demonstrated the writing and reconstruct optical data using spatial light modualtor and angular multiplexing in most optimal condition.

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The Topsoil Characteristics, and Estimation of Topsoil Organic Carbon Storage at Restoration Areas in Riparian Zones of the Han River (한강 수변구역 복원지의 표토 특성 및 유기탄소 저장량 추정)

  • Lee, Jong-Mun;Cho, Yong-Hyeon;Kim, Yoon-Ho;Park, Sung-Woo
    • Journal of the Korean Institute of Landscape Architecture
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    • v.47 no.4
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    • pp.12-23
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    • 2019
  • This study was carried out to investigate and analyze the environmental characteristics of restoration areas in the riparian zones of the Han River, and to quantify the amount of topsoil organic carbon storage. As a result of investigation and analysis of 21 survey sites, the total number of species planted was found to be 17, and the mean number of species was $2.86{\pm}0.13$ species per site. At least one species and a maximum of 7 species were planted at each site. The mean diameter at breast height was $9.1{\pm}0.6cm$, the mean height was $6.2{\pm}0.3m$ and the root content in soil was $0.13{\pm}0.18g/cm^2$. As a result of the analysis of the soil characteristics, 6 out of 21 items, such as the bulk density, solid ratio, gravel ratio, soil hardness, sand content, and pH increased as the soil layer deepened. The topsoil organic carbon storage by layer was $11.54{\pm}1.08ton/ha$ at 0-10cm, $8.69{\pm}0.81ton/ha$ at 10-20cm, $7.97{\pm}0.79ton/ha$ at 20-30cm, and the total from 0 to 30cm was $28.21{\pm}7.31ton/ha$. The highest amount of topsoil organic carbon storage by land use in the past was $35.17{\pm}5.31ton/ha$ in agricultural lands, followed by $28.16{\pm}8.31ton/ha$ in residential areas, $21.87{\pm}9.05ton/ha$ in commercial areas, $19.23{\pm}12.48ton/ha$ in industrial areas, and $17.07{\pm}11.33ton/ha$ in the barren areas. The highest amount of topsoil organic carbon storage in the restored areas was $38.46{\pm}3.14ton/ha$ in 2006, followed by $28.57{\pm}7.84ton/ha$ in 2016, and $16.78{\pm}6.06ton/ha$ in 2011. The results of this study are expected to provide a basic database and evaluation criteria for enhancing the carbon abatement effects of the restoration sites in riparian zones in the future.

Segmented Douglas-Peucker Algorithm Based on the Node Importance

  • Wang, Xiaofei;Yang, Wei;Liu, Yan;Sun, Rui;Hu, Jun;Yang, Longcheng;Hou, Boyang
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.14 no.4
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    • pp.1562-1578
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    • 2020
  • Vector data compression algorithm can meet requirements of different levels and scales by reducing the data amount of vector graphics, so as to reduce the transmission, processing time and storage overhead of data. In view of the fact that large threshold leading to comparatively large error in Douglas-Peucker vector data compression algorithm, which has difficulty in maintaining the uncertainty of shape features and threshold selection, a segmented Douglas-Peucker algorithm based on node importance is proposed. Firstly, the algorithm uses the vertical chord ratio as the main feature to detect and extract the critical points with large contribution to the shape of the curve, so as to ensure its basic shape. Then, combined with the radial distance constraint, it selects the maximum point as the critical point, and introduces the threshold related to the scale to merge and adjust the critical points, so as to realize local feature extraction between two critical points to meet the requirements in accuracy. Finally, through a large number of different vector data sets, the improved algorithm is analyzed and evaluated from qualitative and quantitative aspects. Experimental results indicate that the improved vector data compression algorithm is better than Douglas-Peucker algorithm in shape retention, compression error, results simplification and time efficiency.