• Title/Summary/Keyword: material transport

Search Result 1,165, Processing Time 0.032 seconds

Model development for the estimation of specific degradation using classification and prediction of data mining (데이터 마이닝의 분류 및 예측 기법을 적용한 비유사량 추정 모델 개발)

  • Jang, Eun-kyung;Kang, Woochul
    • Journal of Korea Water Resources Association
    • /
    • v.53 no.3
    • /
    • pp.215-223
    • /
    • 2020
  • The objective of this study is to develop a prediction model of specific degradation using data mining classification especially for the rivers in South Korea river. A number of critical predictors such as erosion and sediment transport were extracted for the prediction model considering watershed morphometric characteristics, rainfall, land cover, land use, and bed material. The suggested model includes the elevations at the mid relative area of the hypsometric curve of watershed morphomeric characteristics, the urbanization ratio, and the wetland and water ratio of land cover factors as the condition factors. The proposed model describes well the measured specific degradation of the rivers in South Korea. In addition, the development model was compared with the existing models, since the existing models based on different conditions and purposes show low predictability, they have a limit about the application of Korean River. Therefore, this study is focusing on improving the applicability of the existing model

Synthesis of Sulfonated Polyethersulfone Membrane Material for Ultrafiltration by Heterogeneous Sulfonation and Fouling Reduction Effect (불균일계 술폰화에 의한 한외여과용 폴리에테르 술폰 막소재 합성과 fouling 감소효과)

  • 김인철;최중구;최남석;김종호;탁태문
    • Membrane Journal
    • /
    • v.8 no.4
    • /
    • pp.210-219
    • /
    • 1998
  • Sulfonated poly(ether sulfone)(SPES) of various ion exchange capacity (IEC) was prepared by heterogeneous sulfonation with chlorosulfonic acid (CSA) to make hydrophilic ultrafiltration membrane for reducing fouling. The effects of CSA concentration, reaction temperature and reaction time has been investigated. The reaction was effective when the temperature is above 10$\circ$C and the CSA concentration is over 0.05 mol, although polymer chain has been significantly degraded. The substitution of sulfonic acid groups was characterized by FTIR and $^1$H-NMR. Transport properties and fouling test have been conducted to the modified SPES ultrafiltration rnembranrs by heterogeneors method. Membranes were obtained using DCM and PVP as a non-solvent and pore forming agent, respectively. Flux reduced and rejection increased with ion exchange capacity. Finger-like structure was disappeared and the thickness of top layer was increased. Dense membrane by non-solvent DCM and porous membrane by pore forming agent PVP was prepared. Fouling was reduced with increasing ion exchange capacity because of hydrophilicity.

  • PDF

Design Approach of Concrete Structures Considering the Targeted CO2 Reduction (목표 탄소배출량 저감을 고려한 콘크리트 구조물의 설계 절차)

  • Jung, Yeon-Back;Yang, Keun-Hyeok
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.3 no.2
    • /
    • pp.115-121
    • /
    • 2015
  • The objective of this study is to present the design approach of low $CO_2$ concrete structures for reduction of $CO_2$ emissions. The design approach was implemented considering the system boundary for each processing presented in the ISO 13315-2. As for life-cycle inventory(LCI) for $CO_2$ assessment of concrete structures, data provided from domestic LCI DB was used. Based on the process presented in this study, case studies on the life-cycle $CO_2$ assessment of shear wall concrete structure was conducted. As substitution level of GGBS is 25%, the amount of $CO_2$ emissions and $CO_2$ uptake by concrete carbonation was decreased in the material, demolition and crushing, and transport phase. The amount of $CO_2$ emissions of column and total member was decreased by 26% and 22% respectively, compared to that of OPC.

Structural and electrical property studies dependent on the molding pressure in high-Tc superconductor $Y_1Ba_2Cu_3O_7-\delta$ (성형 압력변화에 따른 고온초전도체 $Y_1Ba_2Cu_3O_7-\delta$)

  • 김채옥;박정수;이교운
    • Electrical & Electronic Materials
    • /
    • v.9 no.1
    • /
    • pp.18-23
    • /
    • 1996
  • The molding pressure is also one of the important parameters in the preparation of HTSC materials by the solid state reaction method. In the present study, changes in structural, electrical and microstructural proper-ties with the molding pressure in YiB $a_{2}$C $u_{3}$ $O_{70{\delta}}$ superconductors have been performed. The investigated molding pressures were 0.5*10$^{3}$ N/c $m^{2}$, 1*10$^{3}$ N/c $m^{2}$, 2*10$^{3}$ n/c $m^{2}$ and 4*10$^{3}$ N/c $m^{2}$. As the molding pressure increased, the anisotropy of the crystal structure decreased and the grains have been grown preferentially in a c-axis direction. Since the size of the grain becomes larger with the decrease of the porosity, denser textures are formed. The results indicated that the critical current density is improved resulting from the enhanced densification due to higher molding pressure. When the molding pressure was between 1*10$^{3}$ N/c $m^{2}$ and 2*10$^{3}$ N/c $m^{2}$, while it did not affect the oxygen deficiency and Tc, the increase of the molding pressure affects remarkably on grain size and densification of the $Y_{1}$B $a_{2}$C $u_{3}$ $O_{7-{\delta}}$. When the molding pressure is larger than 2*10$^{3}$ N/c $m^{2}$, electrical proper-ties are independent on the molding pressure..

  • PDF

Computational and experimental forensics characterization of weapons-grade plutonium produced in a thermal neutron environment

  • Osborn, Jeremy M.;Glennon, Kevin J.;Kitcher, Evans D.;Burns, Jonathan D.;Folden, Charles M.III;Chirayath, Sunil S.
    • Nuclear Engineering and Technology
    • /
    • v.50 no.6
    • /
    • pp.820-828
    • /
    • 2018
  • The growing nuclear threat has amplified the need for developing diverse and accurate nuclear forensics analysis techniques to strengthen nuclear security measures. The work presented here is part of a research effort focused on developing a methodology for reactor-type discrimination of weapons-grade plutonium. To verify the developed methodology, natural $UO_2$ fuel samples were irradiated in a thermal neutron spectrum at the University of Missouri Research Reactor (MURR) and produced approximately $20{\mu}g$ of weapons-grade plutonium test material. Radiation transport simulations of common thermal reactor types that can produce weapons-grade plutonium were performed, and the results are presented here. These simulations were needed to verify whether the plutonium produced in the natural $UO_2$ fuel samples during the experimental irradiation at MURR was a suitable representative to plutonium produced in common thermal reactor types. Also presented are comparisons of fission product and plutonium concentrations obtained from computational simulations of the experimental irradiation at MURR to the nondestructive and destructive measurements of the irradiated natural $UO_2$ fuel samples. Gamma spectroscopy measurements of radioactive fission products were mostly within 10%, mass spectroscopy measurements of the total plutonium mass were within 4%, and mass spectroscopy measurements of stable fission products were mostly within 5%.

Detection and Manipulation of Spin state of Single Molecule Magnet: Kondo resonance and ESR-STM

  • Komeda, T.;Isshiki, H.;Zhang, Y.F.;Katoh, K.;Yoshida, Y.;Yamashita, M.;Miyasaka, H.;Breedlove, B.K.
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.02a
    • /
    • pp.16-17
    • /
    • 2010
  • Molecular spintronics has attracted attentions, which combines molecular electronics with the spin degree of freedom in electron transport. Among various molecules as candidates of the molecular spintronics, single molecule magnet (SMM) is one of the most promising material. SMM molecules show a ferromagnetic behavior even as a single molecule and hold the spin information even after the magnetic field is turned off. Here in this report, we show the spin behavior of SMM molecules adsorbed on the Au surface by combining the observation of Kondo peak in the STS and ESR-STM measurement. Kondo resonance state is formed near the Fermi level when degenerated spin state interacts with conduction electrons. ESR-STM detects the Larmor frequency of the spin in the presence of a magnet field. The sample include $MPc_2$ and $M_2Pc_3$ molecules ($M\;=\;Tb^{3+}$, $Dy^{3+}$, and $Y^{3+}$ Pc=phthalocyanine) whose critical temperature as a ferromagnet reaches 40 K. A clear Kondo peak was observed which is originated from an unpaired electron in the ligand of the molecule, which is the first demonstration of the Kondo peak originated from electron observed in the STS measurement. We also observed corresponding peaks in ESR-STM spectra. [1] In addition we found that the Kondo peak intensity shows a clear variation with the conformational change of the molecule; namely the azimuthal rotational angle of the Pc planes. This indicates that the Kondo resonance is correlated with the molecule electronic state. We examined this phenomena by using STM manipulation technique, where pulse bias application can rotate the relative azimuthal angle of the Pc planes. The result indicates that an application of ~1V pulse to the bias voltage can rotate the Pc plane and the Kondo peaks shows a clear variation in intensity by the molecule's conformational change.

  • PDF

An Analysis on Traffic Networks of Local Metropolitan area Based on Express Bus and Car O/D (고속버스, 승용차 O/D를 활용한 지방도시권의 교통네트워크 분석)

  • Jang, Hwan-Young;Kim, Nam-Gon
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.17 no.9
    • /
    • pp.559-569
    • /
    • 2016
  • This study examined flow between regions based on the spatial structure of the territory and characterized the flow patterns by analyzing regional networks via transportation connectivity. To accomplish this, transportation connectivity of the entire nation was examined using 2010 national express bus OD data from the Korea Transport Database. After the initial analysis, 2010 car OD data describing networks in seven regions (125 cities and districts), Gangwon-do, Gyeongsangnam-do, Gyeongsangbuk-do, Jeollanam-do, Jeollabuk-do, Chungcheong-do and Seoul, were analyzed to identify transportation connectivity. The results revealed that Korea has strong triangular-belt-shaped transportation connectivity that connects among metropolitan areas in the Jeolla and Gyeongsang areas. Particular zones are set by regional characteristics and functional connectivity for each zone. The results of this study will be useful as a basic material to establish development strategies and customized regional policy development, as well as balanced development.

A Study on Analytical Approach for Performance Evaluation of Pyrotechnically Actuated Device (파이로작동기구 성능평가를 위한 해석모델 연구)

  • Choi, Joo-Ho;Sung, Hong-Gye;Kim, Jun-Sik
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2012.05a
    • /
    • pp.63-64
    • /
    • 2012
  • A pyrotechnic actuated device (PAD) is a component that delivers high power in remote environments by combustion of a self-contained energy source. Historically, the design of these devices has been largely empirical and considered to be an art. In this study, an overview for developing an analytical model is introduced that efficiently evaluates performance of PAD. The model is integrated by three parts of different disciplines that are coupled in sequence with each other. First is the solid explosive burning to form product gas within an actuator and transport to an expansion chamber. Second is the insertion of initially tapered piston into a small hole by gas pressure in the chamber. Third is the shear cutting of the diaphragm from the piston to enable gas flow into the conduit. Some results of preliminary study for each of three parts are introduced in the presentation.

  • PDF

Evaluation of Methane Emissions with Water Regime before the Cultivation Period in Paddy Fields

  • Park, Jun-Hong;Park, Sang-Jo;Kim, Jong-Su;Seo, Dong-Hwan;Park, So-Deuk;Kim, Jin-Ho
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.48 no.4
    • /
    • pp.271-277
    • /
    • 2015
  • Anaerobic decomposition of organic material in flooded rice fields produces methane, which escapes to the atmosphere primarily by transport through the rice plants. The annual amount of $CH_4$ emitted from a given area of rice is a function of the number and duration of crops grown, water regimes before and during cultivation period, and organic and inorganic soil amendments. Soil type, temperature, and rice cultivar also affect $CH_4$ emissions. The field experiment was conducted for three years to develop methane emission factor for water regime before the cultivation period from the rice fields. It was treated with three different water regimes prior to rice cultivation, namely: non-flooded pre-season < 180 days, non-flooded pre-season > 180 days, flooded per-season in which the minimum flooding interval is set to 30 days. Methane emission increased with days after transplanting and soil redox potential (Eh) decreased rapidly after flooding during the rice cultivation. The average methane emission fluxes were $5.47kg\;CH_4\;ha^{-1}day^{-1}$in flooded pre-season > 30 days, 5.04 in non-flooded pre-season < 180 days and 4.62 in non-flooded pre-season > 180. Methane emission flux was highly correlated with soil temperature and soil Eh. Rice yields showed no difference among treatments with water regime before the cultivation period.

Hydroxide ion Conduction Mechanism in Mg-Al CO32- Layered Double Hydroxide

  • Kubo, Daiju;Tadanaga, Kiyoharu;Hayashi, Akitoshi;Tatsumisago, Masahiro
    • Journal of Electrochemical Science and Technology
    • /
    • v.12 no.2
    • /
    • pp.230-236
    • /
    • 2021
  • Ionic conduction mechanism of Mg-Al layered double hydroxides (LDHs) intercalated with CO32- (Mg-Al CO32- LDH) was studied. The electromotive force for the water vapor concentration cell using Mg-Al CO32- LDH as electrolyte showed water vapor partial pressure dependence and obeyed the Nernst equation, indicating that the hydroxide ion transport number of Mg-Al CO32- LDH is almost unity. The ionic conductivity of Mg(OH)2, MgCO3 and Al2(CO3)3 was also examined. Only Al2(CO3)3 showed high hydroxide ion conductivity of the order of 10-4 S cm-1 under 80% relative humidity, suggesting that Al2(CO3)3 is an ion conducting material and related to the generation of carrier by interaction with water. To discuss the ionic conduction mechanism, Mg-Al CO32- LDH having deuterium water as interlayer water (Mg-Al CO32- LDH(D2O)) was prepared. After the adsorbed water molecules on the surface of Mg-Al CO32- LDH(D2O) were removed by drying, DC polarization test for dried Mg-Al CO32- LDH(D2O) was examined. The absorbance attributed to O-D-stretching band for Mg-Al CO32- LDH(D2O) powder at around the positively charged electrode is larger than that before polarization, indicating that the interlayer in Mg-Al CO32- LDH is a hydroxide ion conduction channel.