• 대한전자공학회:학술대회논문집
• /
• 대한전자공학회 2004년도 학술대회지
• /
• pp.675-679
• /
• 2004

The existing conjugated blue emitting material polymer which has been used for the two-wavelength method white-emission has good stability and low operating voltage as merits, but the imbalanced carrier transport has been indicated as problem area. We have introduced a novel blue emitting material having perylene moiety unit with hole transporting ability and blue emitting property and triazine moiety unit with electron transporting ability into the same host chain. We have synthesized N-[p-(perylen-3-y1)pheny1]methacry1 amide (PPMA) monomer and [N-(2,4-dipheny1-1,3,5-triazine)pheny1 methacry1 amide] (DTPM) monomer having blue light-emitting unit and electron transport unit, respectively by three steps. A novel non-conjugated blue emitting material Poly[N -[p­(perylene-3-y1) pheny1] methacry1 amide-co-N-[P-(4,6-dipheny1-1,3,5-triazine-2-y1]pheny1]methacry1 amide] (PPPMA-co-DTPM) copolymer having electron transporting unit was synthesized by the solution polymerization of PPMA and DTPM monomers with an AIBN initiator and showed high yield of $75{\%}$. It was very soluble in common organic solvents, and the fabrication of the thin film using a spin coating method was very simple. The PPPMA exhibited a good thermal stability.

• 한국지반환경공학회 논문집
• /
• 제5권4호
• /
• pp.65-72
• /
• 2004

건설 골재 수급 문제 및 환경에 대한 관심이 높아지면서 국내에서 동슬래그와 같은 각종 산업폐기물의 재활용과 그에 따른 기술개발에 대한 연구가 활발히 진행되고 있다. 이에 본 연구는 동슬래그의 재료특성, 입도분포와 환경적 안정성의 검토를 통하여 동슬래그의 배수재로 적용성을 검토하였다. 실내시험결과를 통하여 일반적으로 쓰여지는 모래보다 우수한 연직배수효과가 있음을 알 수 있었다. 특히 분사현상에 대한 안정성 및 입자유실에 대한 내적안정성을 검토한 결과, 일반적인 사질토에 비해 한계동수경사가 크게 나타나고 내적안정성이 우수하게 평가되었다. 따라서 동슬래그는 지반조건에 따라 배수기능을 충분히 발휘할 수 있으며 내적으로도 안정한 배수재로서 사용이 가능한 것으로 판단된다.

• 보존과학연구
• /
• 통권29호
• /
• pp.5-18
• /
• 2008

Hanji among paper, which is material for support of the organic artifact such as painting and Thangkas, is given as much importance as the original material in the conservation treatment of artifacts. This lining paper can go through physical and chemical deterioration due to its organic nature, and inflict serious damage to the original materials of the artifact. There is a lot of difficulty in keeping continuous production of the paper mulberry fiber based on lining paper due to a short supply of raw material and discontinuation of traditional method. Also restoration and conservation treatment is done by relying only on the knowledge and skill of few experts without any recognized manual based on scientific analysis. In this study, we evaluated the stability of lining paper which is used to support organic artifact. As the result of experiments, this lining paper was made from mulberry tree in Korea and produced by means of oebal method, but was not treated by starch in its surface.

• 한국세라믹학회지
• /
• 제56권2호
• /
• pp.160-166
• /
• 2019

In this study, we investigated the long-term stability of Nd₂NiO₄ solid oxide fuel cell (SOFC) cathodes to evaluate their chromium poisoning tolerance. Symmetrical cells consisting of Nd2NiO4 electrodes and a yttria-stabilized zirconia electrolyte were fabricated and the cell potential and polarization resistance were measured at 850 ℃ in the presence of gaseous chromium species for 800 h. Up to 500 h of operation, the cell potential remained constant at 500 mA/㎠. However, it increased slightly over the operation duration of 550-800 h. No appreciable increase was observed in the polarization resistance of the Nd₂NiO₄ cathode during the entire operation of 800 h. Physicochemical examinations revealed that the gaseous chromium species did not form chromium-related contamination not only in the Nd₂NiO₄ cathode but also at the cathode/electrolyte interface. The results demonstrated that Nd₂NiO₄ is resistant to chromium poisoning, and hence is a potential alternative to standard perovskite cathodes.

• 한국응용과학기술학회지
• /
• 제25권3호
• /
• pp.341-346
• /
• 2008

Cellulose nanofibers from microfibril cellulose (MFC) was prepared by hydrobromic acid (HBr) treatment at different concentrations. Polyvinyl alcohol (PVA) composite films at various loading level of nanofibers were manufactured by a film casting method. The analysis of degree of polymerization (DP), crystallinity ($X_c$) and molecular weight ($M_w$) of cellulose after acid treatment was conducted. The mechanical and thermal properties of the cellulose nanofibers reinforced PVA films were characterized using tensile tests and thermogravimetric analysis (TGA). The DP and $M_w$ of MFC by HBr hydrolysis considerably decreased, but $X_c$ showed no significant change. After acid hydrolysis, the diameter of cellulose nanofibers was in the range of 100 to 200 nm. The thermal stability of the films was steadily improved with the increase of nanofiber loading. There was a significant increase in the tensile strength of PVA composite films with the increase in MFC loading. Finally, 5 wt.% nanofiber loading exhibited the highest tensile strength and thermal stability of PVA composite films.

• Journal of Electrochemical Science and Technology
• /
• 제7권2호
• /
• pp.179-184
• /
• 2016

The interface between the surface of a cathode material and the electrolyte gives rise to surface reactions such as solid electrolyte interface (SEI) and chemical side reactions. These reactions lead to increased surface resistance and charge transfer resistance. It is consequently necessary to improve the electrochemical characteristics by suppressing these reactions. In order to suppress unnecessary surface reactions, we coated cathode material using polypropylene (PP). The PP coating layer effectively reduced the SEI film that is generated after a 4.3 V initial charging process. By mitigating the formation of the SEI film, the PP-coated Li[(Ni_0.6Co_0.1Mn_0.3)_0.36(Ni_0.80Co_0.15Al0.05)_0.64)]O₂(NCS) electrode provided enhanced transport of Li⁺ ions due to reduced SEI resistance (R_SEI) and charge transfer resistance (R_ct). The initial charge and discharge efficiency of the PP-coated NCS electrode was 96.2 % at a current density of 17 mA/g in a voltage range of 3.0 ~ 4.3 V, whereas the efficiency of the NCS electrode was only 94.7 %. The presence of the protective PP layer on the cathode improved the thermal stability by reducing the generated heat, and this was confirmed via DSC analysis by an increased exothermic peak.

• Geomechanics and Engineering
• /
• 제6권2호
• /
• pp.139-151
• /
• 2014

Mudstone is a very common rock that, when in contact with water, can exhibit considerable volume change and breakdown. This behavior of mudstone is frequently encountered in geotechnical engineering and has a considerable influence on infrastructure stability. This is particularly important in the present work, which focuses on mitigating the harmful properties of mudstone. The samples studied are of Permian Age mudstone from Shandong Province, China. Modification tests using organic silicone additive material were carried out. The mechanisms of physical properties modification of mudstone were comparatively studied using corresponding test methods, and the modification mechanism of organic silicone additive material acting on mudstone was analyzed. The following conclusions were drawn. The surface texture and characters of mudstone changed dramatically, surface character turns from hydrophilic to hydrophobic after organic silicone additive material modification. The changes in the surface character indicate a reduction in the water sensitivity of mudstone. After modification, the shape of porosity and fracture of mudstone changed unremarkable, and the total and free expansion ratios decreased obviously, whereas the strength increased markedly.

• Journal of Electrochemical Science and Technology
• /
• 제12권2호
• /
• pp.272-278
• /
• 2021

In this study, high nickel layered LiNi_0.8Co_0.1Mn_0.1O₂ cathode materials for lithium-ion batteries were modified by yttrium doping and poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) coating. The effects of yttrium doping and PEDOT:PSS coating on the structural and electrochemical properties of the LiNi_0.8Co_0.1Mn_0.1O₂ cathode material were investigated and compared. The substitution of nickel with an electrochemically inert yttrium was confirmed to be successful in stabilizing the layered structure framework. Moreover, coating the surfaces of the LiNi_0.8Co_0.1Mn_0.1O₂ particles with a conductive polymer, PEDOT:PSS, improved the capacity retention, thermal stability, and impedance of the cathode material by increasing its ionic and electric conductivities.

• Transactions on Electrical and Electronic Materials
• /
• 제16권6호
• /
• pp.293-302
• /
• 2015

Degraded data stability, weaker write ability, and increased leakage power consumption are the primary concerns in scaled static random-access memory (SRAM) circuits. Two new SRAM cells are proposed in this paper for achieving enhanced read data stability and lower leakage power consumption in memory circuits. The bitline access transistors are asymmetrically gate-underlapped in the proposed SRAM cells. The strengths of the asymmetric bitline access transistors are weakened during read operations and enhanced during write operations, as the direction of current flow is reversed. With the proposed hybrid asymmetric SRAM cells, the read data stability is enhanced by up to 71.6% and leakage power consumption is suppressed up to 15.5%, while displaying similar write voltage margin and maintaining identical silicon area as compared to the conventional memory cells in a 15 nm FinFET technology.

• Computers and Concrete
• /
• 제21권1호
• /
• pp.31-37
• /
• 2018

This paper deals with the stability analysis of concrete pipes mixed with nanoparticles conveying fluid. Instead of cement, the $Fe_2O_3$ nanoparticles are used in construction of the concrete pipe. The Navier-Stokes equations are used for obtaining the radial force of the fluid. Mori-Tanaka model is used for calculating the effective material properties of the concrete $pipe-Fe_2O_3$ nanoparticles considering the agglomeration of the nanoparticles. The first order shear deformation theory (FSDT) is used for mathematical modeling of the structure. The motion equations are derived based on energy method and Hamilton's principal. An exact solution is used for stability analysis of the structure. The effects of fluid, volume percent and agglomeration of $Fe_2O_3$ nanoparticles, magnetic field and geometrical parameters of pipe are shown on the stability behaviour of system. Results show that considering the agglomeration of $Fe_2O_3$ nanoparticles, the critical fluid velocity of the concrete pipe is decreased.