• Journal of Magnetics
• /
• 제18권1호
• /
• pp.30-33
• /
• 2013

The magnetocaloric effect and magnetization behavior have been analyzed in the double-perovskite $La_{0.7}Ba_{0.3}Mn_{1-X}Fe_XO_3$ compound with the sintering temperature at 1273 K. Samples were fabricated by the conventional solid-state reaction method. X-ray diffraction measurement revealed that all the samples had a single phase in orthorhombic. Detailed investigations of the magnetic entropy behavior of the samples were discussed with the variation of $T_C$. The magnetic entropy changes, ${\Delta}S_M$ of approximately 0.36-1.14 J/kg K were obtained in the temperature range of 145-350 K for the $La_{0.7}Ba_{0.3}Mn_{1-X}Fe_XO_3$ compound. The enhancement of the magnetic entropy change is believed to be due to changes in the microstructure, which changes the magnetic part of the entropy of a solid around the magnetic ordering temperature.

• 한국자기학회:학술대회 개요집
• /
• 한국자기학회 2002년도 동계연구발표회 논문개요집
• /
• pp.121-121
• /
• 2002

A theoretical consideration for entropy changes in a magnetic solid is given in a general manner and has been taken into account for such La$\sub$0.7/Ca$\sub$0.3-x/Ba$\sub$x/MnO$_3$(x = 0.12, 0.24, 0.3) compounds. The total entropy changes, in which the total entropy is decomposed into the magnetic, lattice, and electron entropies, are discussed in detail. (omitted)

• 한국재료학회지
• /
• 제33권3호
• /
• pp.95-100
• /
• 2023

This research examines the effect of adding aluminum on the structural, phasic, and magnetic properties of CoCrFe NiMnAl_x high-entropy alloys. To this aim, the arc-melt process was used under an argon atmosphere for preparing cast samples. The phasic, structural, and magnetic properties of the samples were characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), and vibrational magnetometry (VSM) analyses. Based on the results, the addition of aluminum to the compound caused changes in the crystalline structure, from FCC solid solution in the CoCrFeNiMn sample to CoCrFeNiMnAl BBC solid solution. It was associated with changes in the magnetic property of CoCrFeNiMnAl_x high-entropy alloys, from paramagnetic to ferromagnetic. The maximum saturation magnetization for the CoCrFeNiMnAl casting sample was estimated to be around 79 emu/g. Despite the phase stability of the FCC solid solution with temperature, the solid solution phase formed in the CrCrFeNiMnAl high-entropy compound was not stable, and changed into FCC solid solution with temperature elevation, causing a reduction in saturation magnetization to about 7 emu/g.

• 한국재료학회지
• /
• 제26권11호
• /
• pp.623-627
• /
• 2016

$La_{1-x}Ba_xMnO_3$ (x = 0.30, 0.35 and 0.40) samples have been prepared by solid-state reaction method. The X-ray diffraction (XRD) study showed that all the samples crystallized in a rhombohedral structure with an R-3c space group. Variation of the magnetization as a function of the temperature and applied magnetic field was carried out. All the samples revealed ferromagnetic to paramagnetic (FM-PM) phase transition at the Curie temperature $T_C{\sim}342K$. The magnetic entropy change was also studied through examination of the measured magnetic isotherms M(H, T) near $T_C$. The magnetocaloric effect was calculated in terms of the isothermal magnetic entropy change. The maximum entropy change reaches a value of 1.192 J/kgK under a magnetic field change of 2.5T for the $La_{0.6}Ba_{0.4}MnO_3$ composition. The relative cooling power (RCP) is 79.31 J/kg for the same applied magnetic field.

• 한국자기학회지
• /
• 제10권4호
• /
• pp.149-153
• /
• 2000

변하는 자기장을 단결정 및 다결정 망간 산화물 La$_{0.7}$Ca$_{0.3}$MnO$_3$에 인가하였을 때 자기 엔트로피가 크게 변하는(거대 자기 엔트로피 변화)현상이 관측되었다. 이 거대 자기 엔트로피 변화는 Curie온도에서 유사 1차상전이에 의한 자화값의 급격한 변화에 의한 것으로 추측된다. 이 거대 자기 엔트로피 변화와 망간 산화물 Curie 온도의 100 K＜T＜400 K 내의 조절 용이성은 상온을 포함한 넓은 온도에서 망간 산화물을 이용한 자기 냉각 기관의 개발 가능성을 제시하고 있다. 있다.

• Journal of the Korean Physical Society
• /
• 제73권9호
• /
• pp.1303-1309
• /
• 2018

In the present paper, we study the entropy analysis of boundary layer flow over a slender stretching sheet under the action of a non uniform magnetic field that is acting perpendicular to the flow direction. The effects of viscous dissipation and Joule heating are included in the energy equation. Using similarity transformation technique the momentum and thermal boundary layer equations to a system of nonlinear differential equations. Numerical solutions are obtained using the shooting and fourth-order Runge-Kutta method. The expressions for the entropy generation number and Bejan number are also obtained using a suggested similarity transformation. The main objective of this article is to investigate the effects of different governing parameters such as the magnetic parameter ($M^2$), Prandtl number (Pr), Eckert number (Ec), velocity index parameter (m), wall thickness parameter (${\alpha}$), temperature difference parameter (${\Omega}$), entropy generation number (Ns) and Bejan number (Be). All these effects are portrayed graphically and discussed in detail. The analysis reveals that entropy generation reduces with decreasing wall thickness parameter and increasing temperature difference between the stretching sheet and the fluid outside the boundary layer. The viscous and magnetic irreversibilities are dominant in the vicinity of the stretching surface.

• 한국자기공명학회논문지
• /
• 제8권1호
• /
• pp.1-18
• /
• 2004

A thioredoxin from hyperthermophile, Methanococcus jannashii (MjTRX) was characterized by use of the differential scanning calorimetry to understand the mechanisms of thermodynamic stability. MjTRX has an unfolding transition temperature of 116.5$^{\circ}C$, although the maximum free energy of the unfolding (9.9 Kcal/mol) is similar to that of E. coli thioredoxin (ETRX, 9.0 Kcal/mol). However, the temperature of maximum stability is higher than ETRX by 20$^{\circ}C$, indicating that the unfolding transition temperature increased by shifting the temperature of maximum stability. MjTRX has lower enthalpy and entropy of the unfolding compared to ETRX maintaining a similar free energy of the unfolding. From the structure and the thermodynamic parameters of MjTRX, we showed that the unfolding transition temperature of MjTRX is increased due to the decreased entropy of the unfolding. Decreasing the unfolded state entropy and increasing the folded state entropy can decrease the entropy of the unfolding. In the case of MjTRX, the increased number of proline residues decreased the unfolded state entropy and the increased enthalpy in the folded state increased the folded state entropy.

• Journal of Magnetics
• /
• 제21권3호
• /
• pp.468-475
• /
• 2016

In this article, entropy generation on MHD Williamson nanofluid over a porous shrinking sheet has been analyzed. Nonlinear thermal radiation and chemical reaction effects are also taken into account with the help of energy and concentration equation. The fluid is electrically conducting by an external applied magnetic field while the induced magnetic field is assumed to be negligible due to small magnetic Reynolds number. The governing equations are first converted into the dimensionless expression with the help of similarity transformation variables. The solution of the highly nonlinear coupled ordinary differential equation has been obtained with the combination of Successive linearization method (SLM) and Chebyshev spectral collocation method. Influence of all the emerging parameters on entropy profile, temperature profile and concentration profile are plotted and discussed. Nusselt number and Sherwood number are also computed and analyzed. It is observed that entropy profile increases for all the physical parameters. Moreover, it is found that when the fluid depicts non-Newtonian (Williamson fluid) behavior then it causes reduction in the velocity of fluid, however, non-Newtonian behavior enhances the temperature and nanoparticle concentration profile.

• 한국자기학회지
• /
• 제18권2호
• /
• pp.63-66
• /
• 2008

초상자성 코발트 페라이트 나노입자를 제조하여 자화 및 자기엔트로피 변화를 조사하였다. 제조된 시료는 전형적인 입방 스피넬 구조를 띠고 있었다. 5K와 300K에서의 최대 자화는 덩어리 상태에서의 최대 자화보다 작은 값을 가졌다. 시료의 초상자성적 거동은 M vs. H/T 곡선의 겹침에 의해 확인되었다. 열역학적 이론을 바탕으로 자기엔트로피의 변화에 대한 온도 의존성을 도출한 결과, 온도가 높을수록 자기엔트로피의 변화는 더 크게 감소하는 것으로 나타났다.

• Journal of Magnetics
• /
• 제18권4호
• /
• pp.405-411
• /
• 2013

The structural, magnetic and magnetocaloric properties of $CoMn_{1-x}Cr_xGe$ (x=0.05-0.125) have been investigated by using electron microscopy, x-ray diffraction, calorimetric and magnetic measurements. In this study, our aim is to justify the magnetocaloric effect by tuning the structural and magnetic transition temperature with Cr doping on CoMnGe pure system. The substitution of Cr for Mn leads to a decrease of both structural and magnetic transition temperatures. However, structural and magnetic transition temperatures do not close to each other. From magnetization measurement, we calculate that isothermal entropy change associated with magnetic transition can be as high as 3.82 J $kg^{-1}K^{-1}$ at 302 K in a field of 7 T. Meanwhile, structural phase transition contribution to isothermal entropy change is calculated as 5.85 J $kg^{-1}K^{-1}$ at 322 K for 7 T.