• Title/Summary/Keyword: low-oxygen

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Corrosion of Titanium Alloys in High Temperature Seawater

  • Pang, J.J.;Blackwood, D.J.
    • Corrosion Science and Technology
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    • v.14 no.4
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    • pp.195-199
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    • 2015
  • Materials of choice for offshore structures and the marine industry have been increasingly favoring materials that offer high strength-to-weight ratios. One of the most promising families of light-weight materials is titanium alloys, but these do have two potential Achilles' heels: (i) the passive film may not form or may be unstable in low oxygen environments, leading to rapid corrosion; and (ii) titanium is a strong hydride former, making it vulnerable to hydrogen embrittlement (cracking) at high temperatures in low oxygen environments. Unfortunately, such environments exist at deep sea well-heads; temperatures can exceed $120^{\circ}C$, and oxygen levels can drop below 1 ppm. The present study demonstrates the results of investigations into the corrosion behavior of a range of titanium alloys, including newly developed alloys containing rare earth additions for refined microstructure and added strength, in artificial seawater over the temperature range of $25^{\circ}C$ to $200^{\circ}C$. Tests include potentiodynamic polarization, crevice corrosion, and U-bend stress corrosion cracking.

Imaging Hypoxic Myocardium (심근 저산소증 영상)

  • Bae, Sang-Kyun
    • The Korean Journal of Nuclear Medicine
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    • v.39 no.2
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    • pp.141-145
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    • 2005
  • Hypoxia (decreased tissue oxygen tension) is a component of many diseases such as tumors, cerebrovascular diseases and ischemic heart diseases. Although hypoxia can be secondary to a low inspired $pO_2$ or a variety of lung disorders, the most common cause is ischemia due to an oxygen demand greater than the local oxygen supply. In the heart tissue, hypoxia is often observed in persistent low-flow states, such as hibernating myocardium. Direct "hot spot" imaging of myocardial tissue hypoxia is potentially of great clinical importance because it may provide a means of identifying dysfunctional chronically ischemic but viable hibernating myocardium. A series of radiopharmaceuticals that incorporate nitroimidazole moieties have been synthesized to detect decreased local tissue pO2. In contrast to agents that localize in proportion to perfusion, these agents concentrate in hypoxic tissue. However, the ideal agents are not developed yet and the progress is very slow. Furthermore, the research focus is on tumor hypoxia nowadays. This review introduces the myocardial hypoxia imaging with summarizing the development of radiopharmaceuticals.

Hollow Fiber Dialysis Culture of E. coli (대장균의 실관투석배양)

  • 김인호;윤태호
    • KSBB Journal
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    • v.9 no.5
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    • pp.492-498
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    • 1994
  • A hollow fiber device was utilized to perform a dialysis culture for E. coli. Acetic acid inhibition on the growth of E. coli was relieved by dialyzing the acid from broth into a dialysate reservoir. The rate of acetic acid formation was very sensitive to the concentration of glucose and dissolved oxygen. Therefore it was found that the glucose permeation rate should be balanced with the oxygen supply rate. Specific growth rate of E. coli was determined by the glucose permeation rate through membrane. Under a low permeation rate, acetic acid formation was depressed in accordance with high dissolved oxygen concentration as well as low glucose concentration.

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Flame Stabilization and Control in Gas Turbine Combustor (가스터어빈 연소기의 화염 안정화와 제어)

  • Choi, G.M.
    • Journal of ILASS-Korea
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    • v.8 no.4
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    • pp.24-30
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    • 2003
  • This paper presents the characteristics of lifted height and flame length from non-premixed jet flames in highly preheated air to investigate the detail combustion mechanism in the gas turbine or HCCI engine, etc. Special attention was paid to the effect of preheated air temperature, oxygen concentration and fuel injection flow rate on flame length and lifted hight. By using highly preheated air, stable flames were formed even in low oxygen concentration condition. The lifted height increased with decreasing preheated air temperature, where the flame length showed opposed phenomena. The flamelet model, which is thought to have very thin flamelet, is difficult to applicable to the present flame conditions which is formed In low oxygen concentration in highly preheated air.

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Microstructure and Mechanical Properties of Oxygen Free Copper Processed by ARB at Low Strain Rate (저변형률속도에서 ARB가공된 무산소동의 미세조직 및 기계적 성질)

  • Lee, Seong-Hee;Han, Seung-Zeon;Lim, Cha-Yong
    • Korean Journal of Materials Research
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    • v.17 no.10
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    • pp.521-525
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    • 2007
  • The microstructure and mechanical properties of an oxygen free copper processed by accumulative roll bonding(ARB) at low strain rate were studied. The copper sheets were highly strained up to an equivalent strain of ${\sim}6.4$ by ARB process at ambient temperature. The strain rate of the copper during the ARB was $2.6sec^{-1}$. The microstructure and mechanical properties of the ARB-processed copper were compared to those of the specimens processed by ARB at relatively high strain rate ($37sec^{-1}$). The microstructure and mechanical properties of the copper with ARB process was very similar to each other despite of some differences in recovery.

Oxygen Evolution Reaction at Electrodes of Single Phase Ruthenium Oxides with Perovskite and Pyrochlore Structures$^{**}$

  • 최은옥;권영욱;모선일
    • Bulletin of the Korean Chemical Society
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    • v.18 no.9
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    • pp.972-976
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    • 1997
  • Single phase ruthenium oxides with perovskite (ATi1-xRuxO3 (A=Ca, Sr)) and pyrochlore structure (Bi2Ru2O7, Pb2Ru2O6.5) have been prepared reproducibly by solid state reaction methods and their electrocatalytic activities for oxygen evolution have been examined by Tafel plots. Tafel slopes vary from a low value of 42 mV/decade up to 222 mV/decade at room temperature. The high exchange current densities and high Tafel slopes compared with those obtained from the RuO2 DSA electrode at the crystalline single phase metal oxide electrodes suggest that they are better electrocatalysts at low overpotentials. A favorable change in the Tafel slope for the oxygen evolution reaction occurs as the ruthenium content increases. Substitution of Ti for Ru in the perovskite solid solutions enhanced their chemical stability by losing marginal electrochemical activity.

In-situ Monitoring of Anodic Oxidation of p-type Si(100) by Electrochemical Impedance Techniques in Nonaqueous and Aqueous Solutions

  • 김민수;김경구;김상열;김영태;원영희;최연익;모선일
    • Bulletin of the Korean Chemical Society
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    • v.20 no.9
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    • pp.1049-1055
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    • 1999
  • Electrochemical oxidation of silicon (p-type Si(100)) at room temperature in ethylene glycol and in aqueous solutions has been performed by applying constant low current densities for the preparation of thin SiO2 layers. In-situ ac impedance spectroscopic methods have been employed to characterize the interfaces of electrolyte/oxide/semiconductor and to estimate the thickness of the oxide layer. The thicknesses of SiO2 layers calculated from the capacitive impedance were in the range of 25-100Å depending on the experimental conditions. The anodic polarization resistance parallel with the oxide layer capacitance increased continuously to a very large value in ethylene glycol solution. However, it decreased above 4 V in aqueous solutions, where oxygen evolved through the oxidation of water. Interstitially dissolved oxygen molecules in SiO2 layer at above the oxygen evolution potential were expected to facilitate the formation of SiO2 at the interfaces. Thin SiO2 films grew efficiently at a controlled rate during the application of low anodization currents in aqueous solutions.

A Study on Perpendicular Flame Retardant Characteristic Improvement of Halogen-free Flame Retardant Compounds by Nanoclay Addition (나노클레이 첨가에 따른 할로겐프리 난연컴파운드의 수직난연 특성 향상에 관한 연구)

  • Hwang, Chan-Yun;Yang, Jong-Seok;Seong, Baeg-Yong;Kim, Ji-Yeon;Park, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.1
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    • pp.51-56
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    • 2015
  • The object of this study is to obtain the optimum mix proportion of halogen free compound with flame resistance and, for the purpose, thermal/electrical characteristics test are conducted using compatibilizing agents, flame resistance agents, hydroxide aluminum, sunscreen, antioxidant and silicon oil on the base resin of linear low density polyethylene (LLDPE), Ethylene vinyl acetate copolymer (EVA). Existing compound method accompanies many requirements to be satisfied including a lot of addition of flame resistance agents, prohibition of impact on mixing capability with base and property and etc. In this study, different from the existing method, the optimum mix proportion is determined and experimented by adding nano clay. Oxygen index test shows no difference between specimens while T-6, T-9 shows oxygen index of 29[%] and 26[%], respectively. This is concluded that hydroxide aluminum, which is a flame resistance agent, leads low oxygen index. From UL94-V vertical flame resistance test, the combustion behavior is determined as V-0, Fail based on UL94-V decision criteria. Viscometry shows low measurements in specimens with separate addition of compatibilizing agents or nano clay. Volume resistivity test shows low measurement mainly in specimens without compatibilizing agents. Therefore, with the flame resistance compound shows better performance for thermal/electrical property and the optimum mix proportion are achieved among many existing materials.

Low-Pressure Plasma Inactivation of Escherichia coli (감압 플라즈마를 이용한 Escherichia coli 살균)

  • Mok, Chulkyoon;Song, Dong-Myung
    • Food Engineering Progress
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    • v.14 no.3
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    • pp.202-207
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    • 2010
  • Low-pressure plasmas (LPPs) were generated with different gases such as air, oxygen and nitrogen, and their inactivation effects against Escherichia coli were compared in order to evaluate the potential as a non-thermal microbial disinfection technology. Homogeneous plasmas were generated under low pressure below 1 Torr at gas flow rate of 350 mL/min regardless the types of gases. Temperature increases by LPPs were not detrimental showing less than ${10^{\circ}C}$ and ${25^{\circ}C}$ increases after 5 and 10 min treatments, respectively. The smallest temperature increase was observed with air LPP, and followed by oxygen and nitrogen LPPs. More than 5 log reduction in E. coli was achieved by 5 min LPP treatment but the destruction effect was retarded afterward. The LPP inactivation was represented by a iphasic first order reaction kinetics. The highest inactivation rate constant was achieved in air LPP and followed by oxygen and nitrogen LPPs. The small D-values of the LPP also supported its potentialities as a non-thermal food surface disinfection technology in addition to the substantial microbial reduction of more than 5 logs.

A Study on the Effect of Low-Temperature Activity on Vanadium Catalysts (Vanadium계 촉매의 NH3-SCR 저온 활성 영향 연구)

  • Yeo, Jonghyeon;Hong, Sungchang
    • Clean Technology
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    • v.26 no.4
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    • pp.321-328
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    • 2020
  • This experiment compared V/W/TiO2 and V/Mo/TiO2 catalysts that were used for commercial catalysts. The effects of SCR reactions on low-temperature activity were studied. NH3-TPD, DRIFT, and H2-TPR analysis, alongside O2-on/off experiments, were conducted to identify the effects of NH3 acid sites and oxygen participating in the SCR reaction, which had a significant impact on the NH3-SCR reaction. The effect on activity was analyzed at 250 ℃, a high temperature of reaction activity, and 180 ℃, which showed significant activity degradation. In NH3 involved in the SCR reaction at 250 ℃, B and L acid sites contributed to the reaction. In particular, the B acid site was found to have significantly participated in the reaction and affected the NH3-SCR activity, which was reduced at 180 ℃ to affect the activity degradation. Also, atmospheric oxygen contributed to the SCR reaction, causing the active property to facilitate reaction activity at 250 ℃. However, oxygen did not comprise the reaction at 180 ℃, indicating a drop inactivity. Therefore, the B acid site was reduced, and the activity was judged to be degraded due to failure to share in the reaction and low effects by atmospheric oxygen.